Capacity of a set - Revision history

41.58.78.235: /* See also */

2014-02-16T23:19:42Z

See also

← Older revision		Revision as of 01:19, 17 February 2014
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	~~In [[chemistry]], the '''Effective Molarity''~~' (~~denoted ''EM''~~)~~<ref name=Kirby>{{cite book\|last=Kirby~~, ~~AJ in\|title=Advances in Physical Organic Chemistry\|year=1980\|publisher=Academic Press\|location=London\|isbn=9780120335176\|pages=183–278}}~~<~~/ref~~> ~~is defined as the ratio between the first-order rate constant of an [[intramolecular reaction]]~~ and ~~the second-order rate constant of the corresponding intermolecular reaction (~~'~~'Kinetic Effective Molarity'')~~<~~ref name=Kirby /~~><~~ref~~>~~{{cite book\|last=Dougherty\|first=Eric V. Anslyn ; Dennis A.\|title=Modern physical organic chemistry\|year=2006\|publisher=University Science Books\|location=Sausalito~~, ~~Calif.\|isbn=9781891389313\|pages=496\|edition=Dodr.}}<~~/ref> or the ratio between the [[equilibrium constant]] of an [[intramolecular reaction]] and the [[equilibrium constant]] of the corresponding intermolecular reaction (''Thermodynamic Effective Molarity'').<ref name=Kirby /><ref>{{cite journal\|last=Hunter\|first=Christopher A.\|coauthors=Anderson, Harry L.\|title=What is Cooperativity?\|journal=Angewandte Chemie International Edition\|date=28 September 2009\|volume=48\|issue=41\|pages=7488–7499\|doi=10.~~1002~~/~~anie.200902490}}~~<~~/ref~~>		I'm Merissa (22) from Zevenbergen, Netherlands. <br>I'm learning Spanish literature at a local college and I'm just about to graduate.<br>I have a part time job in a university.<br>, https://twitter.com/playdohvideos<br><br>My weblog: [https://twitter.com/playdohvideos Surprise Eggs unboxing toys]

	<~~math~~>~~EM_{kinetic} = {k_{intramolecular} \over k_{intermolecular}}<~~/~~math>~~

	~~<math>EM_{thermo} = {K_{intramolecular} \over K_{intermolecular}}<~~/~~math>~~

	EM has the dimension of concentration. High EM values always indicate greater ease of intramolecular processes over the corresponding intermolecular ones. Effective molarities can be used to get a deeper understanding of the effects of intramolecularity on reaction courses.<ref>{{cite journal\|last=Krishnamurthy\|first=Vijay M.\|coauthors=Semetey, Vincent; Bracher, Paul J.; Shen, Nan; Whitesides, George M.\|title=Dependence of Effective Molarity on Linker Length for an Intramolecular Protein−Ligand System\|journal=Journal of the American Chemical Society\|date=1 February 2007\|volume=129\|issue=5\|pages=1312–1320\|doi=10.1021/ja066780e}}</ref> In last decades, the frequency of use of effective molarity in scientific literature has shown a marked decrease, because this formalism is being progressively replaced by more important [[physical quantities]].

	~~==See also==~~
	*[[Cyclic compound]]
	*[[Macrocycle]]
	*[[Intramolecular reaction]]
	*[[Polymerization]]

	~~==References==~~

	~~{{Reflist}}~~

	~~[[Category:Physical organic chemistry]~~]

en>Spectral sequence: /* References */ Ransford (1995)

2013-07-22T18:12:19Z

References: Ransford (1995)

← Older revision		Revision as of 20:12, 22 July 2013
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	~~Genoveva Reck~~ is ~~what is penned on my beginning~~ [~~http://Photo.net/gallery/tag~~-~~search~~/~~search?query_string~~=~~certificate certificate] but you can get in touch with me nearly anything you like~~. ~~As a female what I seriously like is curling but I cannot make it my [https://www~~.~~Vocabulary~~.~~com~~/~~dictionary/occupation occupation~~] ~~actually. Given that I was 18 I have been doing work as a output~~ and ~~planning officer but I~~'~~ve often needed my individual business enterprise~~. ~~I have generally liked dwelling in Alaska~~. ~~I'm not excellent at webdesign but you may want to check out my web page: http://www~~.~~qrm~~.~~nl/aspnet_client~~/~~nike-air-max-dames~~.~~html~~<br><br>~~Here is my blog post: [http:~~//~~www~~.~~qrm~~.nl/~~aspnet_client~~/~~nike-air-max-dames~~.~~html Nike air max dames~~]		In [[chemistry]], the '''Effective Molarity''' (denoted ''EM'')<ref name=Kirby>{{cite book\|last=Kirby, AJ in\|title=Advances in Physical Organic Chemistry\|year=1980\|publisher=Academic Press\|location=London\|isbn=9780120335176\|pages=183–278}}</ref> is defined as the ratio between the first-order rate constant of an [[intramolecular reaction]] and the second-order rate constant of the corresponding intermolecular reaction (''Kinetic Effective Molarity'')<ref name=Kirby /><ref>{{cite book\|last=Dougherty\|first=Eric V. Anslyn ; Dennis A.\|title=Modern physical organic chemistry\|year=2006\|publisher=University Science Books\|location=Sausalito, Calif.\|isbn=9781891389313\|pages=496\|edition=Dodr.}}</ref> or the ratio between the [[equilibrium constant]] of an [[intramolecular reaction]] and the [[equilibrium constant]] of the corresponding intermolecular reaction (''Thermodynamic Effective Molarity'').<ref name=Kirby /><ref>{{cite journal\|last=Hunter\|first=Christopher A.\|coauthors=Anderson, Harry L.\|title=What is Cooperativity?\|journal=Angewandte Chemie International Edition\|date=28 September 2009\|volume=48\|issue=41\|pages=7488–7499\|doi=10.1002/anie.200902490}}</ref>

			<math>EM_{kinetic} = {k_{intramolecular} \over k_{intermolecular}}</math>

			<math>EM_{thermo} = {K_{intramolecular} \over K_{intermolecular}}</math>

			EM has the dimension of concentration. High EM values always indicate greater ease of intramolecular processes over the corresponding intermolecular ones. Effective molarities can be used to get a deeper understanding of the effects of intramolecularity on reaction courses.<ref>{{cite journal\|last=Krishnamurthy\|first=Vijay M.\|coauthors=Semetey, Vincent; Bracher, Paul J.; Shen, Nan; Whitesides, George M.\|title=Dependence of Effective Molarity on Linker Length for an Intramolecular Protein−Ligand System\|journal=Journal of the American Chemical Society\|date=1 February 2007\|volume=129\|issue=5\|pages=1312–1320\|doi=10.1021/ja066780e}}</ref> In last decades, the frequency of use of effective molarity in scientific literature has shown a marked decrease, because this formalism is being progressively replaced by more important [[physical quantities]].

			==See also==
			*[[Cyclic compound]]
			*[[Macrocycle]]
			*[[Intramolecular reaction]]
			*[[Polymerization]]

			==References==

			{{Reflist}}

			[[Category:Physical organic chemistry]]

109.100.67.93: /* References */ - Rephrased a sentence in a more natural way

2012-03-27T14:28:35Z

References: - Rephrased a sentence in a more natural way

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