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	~~{{About\|anharmonic oscillators\|the anharmonic ratio\|Cross-ratio}}~~		Jayson Berryhill is how I'm known as and my wife doesn't like it at all. Alaska is exactly where he's usually been residing. To climb is something she would never give up. Distributing production is where my main earnings arrives from and it's something I truly appreciate.<br><br>Take a look at my web-site: psychic phone readings ([http://www.herandkingscounty.com/content/information-and-facts-you-must-know-about-hobbies website link])
	~~In [[classical mechanics]], '~~'~~'anharmonicity''' is the deviation of a system from being a [[harmonic oscillator]]. An oscillator that is not oscillating in [[simple harmonic motion]] is~~ known as ~~an anharmonic oscillator where the system can be approximated to a harmonic oscillator~~ and ~~the anharmonicity can be calculated using [[perturbation theory]]~~. ~~If the anharmonicity~~ is ~~large then other [[numerical analysis\|numerical techniques]] have to be used.~~

	~~As a result, oscillations with frequencies <math>2\omega</math> and <math>3\omega</math> etc.,~~ where <math>\omega</math> is the fundamental frequency of the oscillator, appear. Furthermore, the frequency <math>\omega</math> deviates from the frequency <math>\omega_0</math> of the harmonic oscillations. As a first approximation, the frequency shift <math>\Delta \omega=\omega-\omega_0</math> is proportional to the square of the oscillation amplitude <math>A</math>:

	~~:<math>\Delta \omega\propto A^2</math>~~

	In a system of oscillators with [[normal mode\|natural frequencies]] <math>\omega_\alpha</math>, <math>\omega_\beta</math>, ... anharmonicity results in additional oscillations with frequencies <math>\omega_\alpha\pm \omega_\beta</math>.

	~~Anharmonicity also modifies the profile of the resonance curve, leading to interesting phenomena such as the [[nonlinear resonance\|foldover effect]] and superharmonic resonance.~~

	~~== General principle ==~~

	A generalized version of harmonic oscillator in which the relationship between force and displacement is linear. The harmonic oscillator is a highly idealized system that oscillates with a single frequency, irrespective of the amount of pumping or energy injected into the system. Consequently, the harmonic oscillator's ~~fundamental frequency of vibration is independent of the amplitude of the vibrations~~. ~~Applications of the harmonic oscillator model abound in various fields, but perhaps the most commonly studied system~~ is ~~the Hooke's law mass-spring system~~. ~~In the Hooke's law system the restoring force exerted on the mass~~ is ~~proportional to the displacement of the mass~~ from ~~its equilibrium position. This linear relationship between force~~ and ~~displacement mandates that the oscillation frequency of the mass will be independent of the amplitude of the displacement.~~

	In a mechanical anharmonic oscillator, the relationship between force and displacement is not linear but depends upon the amplitude of the displacement. The nonlinearity arises from the fact that the spring is not capable of exerting a restoring force that is proportional to its displacement because of, for example, stretching in the material comprising the spring. As a result of the nonlinearity, the vibration frequency can change, depending upon the system's ~~displacement~~. ~~These changes in the vibration frequency result in energy being coupled from the fundamental vibration frequency to other frequencies through a process known as parametric coupling.~~

	~~== Examples in physics ==~~

	There are many systems throughout the physical world that can be modeled as anharmonic oscillators in addition to the nonlinear mass-spring system. For example, an atom, which consists of a positively charged nucleus surrounded by a negatively charged electronic cloud, experiences a displacement between the center of mass of the nucleus and the electronic cloud when an electric field is present. The amount of that displacement, called the electric dipole moment, is related linearly to the applied field for small fields, but as the magnitude of the field is increased, the field-dipole moment relationship becomes nonlinear, just as in the mechanical system.

	Further examples of anharmonic oscillators include the large-angle pendulum, which exhibits chaotic behavior as a result of its anharmonicity; nonequilibrium semiconductors that possess a large hot carrier population, which exhibit nonlinear behaviors of various types related to the effective mass of the carriers; and ionospheric plasmas, which also exhibit nonlinear behavior based on the anharmonicity of the plasma. In fact, virtually all oscillators become anharmonic when their pump amplitude increases beyond some threshold, and as a result it is necessary to use nonlinear equations of motion to describe their behavior.

	Anharmonicity plays a role in lattice and molecular vibrations, in quantum oscillations (see {{citation\|url=http://jchemed.chem.wisc.edu/Journal/issues/2005/Aug/abs1263_2.html\|title=The Effect of Anharmonicity on Diatomic Vibration: A Spreadsheet Simulation \|date=August 2005\|volume= 82 \|number= 8\|page= 1263\|author=Lim, Kieran F. ; Coleman, William F. \|journal=J. Chem. Educ.\|bibcode = 2005JChEd..82.1263F \|doi = 10.1021/ed082p1263.1 }}), and in [[acoustics]]. The atoms in a molecule or a solid vibrate about their equilibrium positions. When these vibrations have small amplitudes they can be described by [[harmonic oscillators]]. However, when the vibrational amplitudes are large, for example at ~~high temperatures, anharmonicity becomes important. An example of the effects of anharmonicity is the thermal expansion of solids, which is usually studied within the [[quasi~~-harmonic approximation]]. Studying vibrating anharmonic systems using quantum mechanics is a computationally demanding task because anharmonicity not only makes the potential experienced by each oscillator more complicated, but also introduces coupling between the oscillators. It is possible to use first-principles methods such as [[density-functional theory]] to map the anharmonic potential experienced by the atoms in both molecules<ref>{{citation\|url=http:~~//dx.doi.org/10.1063/1.472960\|title=Vibrational wave functions and spectroscopy of~~ (H<sub>2</sub>O)<sub>''n''</sub>, ''n''=2,3,4,5: Vibrational self‐consistent field with correlation corrections \|year=1996\|volume= 105 \|page= 10332\|author=Jung, J. O.;Benny Gerber, R. \|journal=J. Chem. Phys.\|doi = 10.1063/1.472960 \|bibcode = 1996JChPh.10510332J }}</ref> and solids.<ref>{{citation\|url=http://~~link~~.~~aps~~.~~org/doi~~/~~10.1103~~/~~PhysRevB.87.144302\|title=Anharmonic vibrational properties in periodic systems: energy, electron~~-~~phonon coupling,~~ and stress \|year=2013\|volume= 87 \|page= 144302\|author=Monserrat, B.; Drummond, N.D.; Needs, R.J. \|journal=Phys. Rev. B\|doi = 10.1103/PhysRevB.87.144302 \|arxiv = 1303.0745 \|bibcode = 2013PhRvB..87n4302M }}</ref> Accurate anharmonic vibrational energies can then be obtained by solving the anharmonic vibrational equations for the atoms within a [[mean-~~field theory]]. Finally, it is possible to use [[Møller~~-~~Plesset perturbation theory]] to go beyond the mean~~-~~field formalism.~~

	~~== Potential energy from period of oscillations ==~~

	~~Let us consider a potential well <math>U(x)</math>.~~
	~~Assuming that the curve <math>U=U(x)</math> is symmetric about the <math>U</math>~~-~~axis, the shape of the curve can be implicitly determined from the period <math>T(E)</math> of the oscillations of particles with energy <math>E</math> according to the formula:~~

	~~:<math>x(U)=\frac{1}{2\pi \sqrt{2m}}\int_0^U\frac{T(E)\,dE}{\sqrt{U~~-~~E}}</math>~~

	~~== See also ==~~
	*[[Inharmonicity]]
	*[[Harmonic oscillator]]
	*[[Quantum harmonic oscillator]]
	*[[Musical acoustics]]
	*[[Nonlinear resonance]]

	~~== References ==~~
	* {{Citation \| last1=Landau \| first1=L. D. \| authorlink1=Lev Landau \| last2=Lifshitz \| first2=E. M. \| authorlink2=Evgeny Lifshitz \| year=1976 \| title=Mechanics \| edition=3rd \| publisher=Pergamon Press \| isbn=0-~~08-021022-8 }}~~
	* {{Citation \| last1=Filipponi \| first1=A. \| last2=Cavicchia \| first2=D. R. \| year=2011 \| title=Anharmonic dynamics of a mass O-spring oscillator
	~~\| publisher=American Journal of Physics, Volume 79, Issue 7, pp. 730 \| url=http://dx.doi.org/10.1119/1.3579129}}~~

	~~{{reflist}}~~

	~~== External links ==~~
	* {{Citation \| last=Elmer \| first=Franz-Josef \| url=http://monet.physik.unibas.ch/~elmer/pendulum/nonres.htm \| title=Nonlinear Resonance \| publisher=[[University of Basel]] \| date=July 20, 1998 \| accessdate=October 28, 2010 }}

	~~[[Category:Classical mechanics]~~]

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← Older revision		Revision as of 10:11, 14 February 2013
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	~~Alyson~~ is the ~~name individuals use~~ to ~~call me~~ and ~~I think it seems fairly good when you say it~~. ~~Her family members life~~ in ~~Ohio~~. He is ~~an purchase clerk~~ and it's some ~~thing he truly enjoy~~. ~~Playing badminton~~ is a ~~factor that he~~ is ~~completely addicted~~ to.<br><br>~~My blog~~; ~~tarot readings; [~~http://~~www~~.~~weddingwall~~.~~com~~.au/~~groups~~/~~easy~~-~~advice~~-~~for~~-~~successful~~-~~personal~~-~~development~~-~~today~~/ ~~watch this video~~],		{{About\|anharmonic oscillators\|the anharmonic ratio\|Cross-ratio}}
			In [[classical mechanics]], '''anharmonicity''' is the deviation of a system from being a [[harmonic oscillator]]. An oscillator that is not oscillating in [[simple harmonic motion]] is known as an anharmonic oscillator where the system can be approximated to a harmonic oscillator and the anharmonicity can be calculated using [[perturbation theory]]. If the anharmonicity is large then other [[numerical analysis\|numerical techniques]] have to be used.

			As a result, oscillations with frequencies <math>2\omega</math> and <math>3\omega</math> etc., where <math>\omega</math> is the fundamental frequency of the oscillator, appear. Furthermore, the frequency <math>\omega</math> deviates from the frequency <math>\omega_0</math> of the harmonic oscillations. As a first approximation, the frequency shift <math>\Delta \omega=\omega-\omega_0</math> is proportional to the square of the oscillation amplitude <math>A</math>:

			:<math>\Delta \omega\propto A^2</math>

			In a system of oscillators with [[normal mode\|natural frequencies]] <math>\omega_\alpha</math>, <math>\omega_\beta</math>, ... anharmonicity results in additional oscillations with frequencies <math>\omega_\alpha\pm \omega_\beta</math>.

			Anharmonicity also modifies the profile of the resonance curve, leading to interesting phenomena such as the [[nonlinear resonance\|foldover effect]] and superharmonic resonance.

			== General principle ==

			A generalized version of harmonic oscillator in which the relationship between force and displacement is linear. The harmonic oscillator is a highly idealized system that oscillates with a single frequency, irrespective of the amount of pumping or energy injected into the system. Consequently, the harmonic oscillator's fundamental frequency of vibration is independent of the amplitude of the vibrations. Applications of the harmonic oscillator model abound in various fields, but perhaps the most commonly studied system is the Hooke's law mass-spring system. In the Hooke's law system the restoring force exerted on the mass is proportional to the displacement of the mass from its equilibrium position. This linear relationship between force and displacement mandates that the oscillation frequency of the mass will be independent of the amplitude of the displacement.

			In a mechanical anharmonic oscillator, the relationship between force and displacement is not linear but depends upon the amplitude of the displacement. The nonlinearity arises from the fact that the spring is not capable of exerting a restoring force that is proportional to its displacement because of, for example, stretching in the material comprising the spring. As a result of the nonlinearity, the vibration frequency can change, depending upon the system's displacement. These changes in the vibration frequency result in energy being coupled from the fundamental vibration frequency to other frequencies through a process known as parametric coupling.

			== Examples in physics ==

			There are many systems throughout the physical world that can be modeled as anharmonic oscillators in addition to the nonlinear mass-spring system. For example, an atom, which consists of a positively charged nucleus surrounded by a negatively charged electronic cloud, experiences a displacement between the center of mass of the nucleus and the electronic cloud when an electric field is present. The amount of that displacement, called the electric dipole moment, is related linearly to the applied field for small fields, but as the magnitude of the field is increased, the field-dipole moment relationship becomes nonlinear, just as in the mechanical system.

			Further examples of anharmonic oscillators include the large-angle pendulum, which exhibits chaotic behavior as a result of its anharmonicity; nonequilibrium semiconductors that possess a large hot carrier population, which exhibit nonlinear behaviors of various types related to the effective mass of the carriers; and ionospheric plasmas, which also exhibit nonlinear behavior based on the anharmonicity of the plasma. In fact, virtually all oscillators become anharmonic when their pump amplitude increases beyond some threshold, and as a result it is necessary to use nonlinear equations of motion to describe their behavior.

			Anharmonicity plays a role in lattice and molecular vibrations, in quantum oscillations (see {{citation\|url=http://jchemed.chem.wisc.edu/Journal/issues/2005/Aug/abs1263_2.html\|title=The Effect of Anharmonicity on Diatomic Vibration: A Spreadsheet Simulation \|date=August 2005\|volume= 82 \|number= 8\|page= 1263\|author=Lim, Kieran F. ; Coleman, William F. \|journal=J. Chem. Educ.\|bibcode = 2005JChEd..82.1263F \|doi = 10.1021/ed082p1263.1 }}), and in [[acoustics]]. The atoms in a molecule or a solid vibrate about their equilibrium positions. When these vibrations have small amplitudes they can be described by [[harmonic oscillators]]. However, when the vibrational amplitudes are large, for example at high temperatures, anharmonicity becomes important. An example of the effects of anharmonicity is the thermal expansion of solids, which is usually studied within the [[quasi-harmonic approximation]]. Studying vibrating anharmonic systems using quantum mechanics is a computationally demanding task because anharmonicity not only makes the potential experienced by each oscillator more complicated, but also introduces coupling between the oscillators. It is possible to use first-principles methods such as [[density-functional theory]] to map the anharmonic potential experienced by the atoms in both molecules<ref>{{citation\|url=http://dx.doi.org/10.1063/1.472960\|title=Vibrational wave functions and spectroscopy of (H<sub>2</sub>O)<sub>''n''</sub>, ''n''=2,3,4,5: Vibrational self‐consistent field with correlation corrections \|year=1996\|volume= 105 \|page= 10332\|author=Jung, J. O.;Benny Gerber, R. \|journal=J. Chem. Phys.\|doi = 10.1063/1.472960 \|bibcode = 1996JChPh.10510332J }}</ref> and solids.<ref>{{citation\|url=http://link.aps.org/doi/10.1103/PhysRevB.87.144302\|title=Anharmonic vibrational properties in periodic systems: energy, electron-phonon coupling, and stress \|year=2013\|volume= 87 \|page= 144302\|author=Monserrat, B.; Drummond, N.D.; Needs, R.J. \|journal=Phys. Rev. B\|doi = 10.1103/PhysRevB.87.144302 \|arxiv = 1303.0745 \|bibcode = 2013PhRvB..87n4302M }}</ref> Accurate anharmonic vibrational energies can then be obtained by solving the anharmonic vibrational equations for the atoms within a [[mean-field theory]]. Finally, it is possible to use [[Møller-Plesset perturbation theory]] to go beyond the mean-field formalism.

			== Potential energy from period of oscillations ==

			Let us consider a potential well <math>U(x)</math>.
			Assuming that the curve <math>U=U(x)</math> is symmetric about the <math>U</math>-axis, the shape of the curve can be implicitly determined from the period <math>T(E)</math> of the oscillations of particles with energy <math>E</math> according to the formula:

			:<math>x(U)=\frac{1}{2\pi \sqrt{2m}}\int_0^U\frac{T(E)\,dE}{\sqrt{U-E}}</math>

			== See also ==
			*[[Inharmonicity]]
			*[[Harmonic oscillator]]
			*[[Quantum harmonic oscillator]]
			*[[Musical acoustics]]
			*[[Nonlinear resonance]]

			== References ==
			* {{Citation \| last1=Landau \| first1=L. D. \| authorlink1=Lev Landau \| last2=Lifshitz \| first2=E. M. \| authorlink2=Evgeny Lifshitz \| year=1976 \| title=Mechanics \| edition=3rd \| publisher=Pergamon Press \| isbn=0-08-021022-8 }}
			* {{Citation \| last1=Filipponi \| first1=A. \| last2=Cavicchia \| first2=D. R. \| year=2011 \| title=Anharmonic dynamics of a mass O-spring oscillator
			\| publisher=American Journal of Physics, Volume 79, Issue 7, pp. 730 \| url=http://dx.doi.org/10.1119/1.3579129}}

			{{reflist}}

			== External links ==
			* {{Citation \| last=Elmer \| first=Franz-Josef \| url=http://monet.physik.unibas.ch/~elmer/pendulum/nonres.htm \| title=Nonlinear Resonance \| publisher=[[University of Basel]] \| date=July 20, 1998 \| accessdate=October 28, 2010 }}

			[[Category:Classical mechanics]]

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2012-05-02T22:50:49Z

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