Stoichiometry: Difference between revisions

From formulasearchengine
Jump to navigation Jump to search
en>Slazenger
m Reverted edits by 111.93.178.202 (talk) to last revision by Vsmith (HG)
en>ClueBot NG
m Reverting possible vandalism by 70.114.144.64 to version by Signalizing. False positive? Report it. Thanks, ClueBot NG. (2081945) (Bot)
 
(One intermediate revision by one other user not shown)
Line 1: Line 1:
'''Superconducting Magnetic Energy Storage (SMES)''' systems store energy in the [[magnetic field]] created by the flow of [[direct current]] in a  [[Superconductivity|superconducting]] coil which has been [[Cryogenics|cryogenically]] cooled to a temperature below its [[Superconductivity#Superconducting phase transition|superconducting critical temperature]].
== 「徐Pingqiuは、本格的な歯痛 ==


A typical SMES system includes three parts: superconducting [[coil]], power conditioning system and cryogenically cooled refrigerator. Once the superconducting coil is charged, the current will not decay and the magnetic energy can be stored indefinitely.  
行? [http://www.dmwai.com/webalizer/kate-spade-0.html ハンドバッグ ケイトスペード] 「徐Pingqiuは、本格的な歯痛。<br>のみならず、<br>目で一瞬スイスリットル億使いにくい、優れたアレンジ言った: '私はアイデアを持っているが、私はまだあなたを探しています、あああなたが一緒に作品を掻き取る、逆アセンブルしなければならないことが悪いのこの種を思い出させる文句?彼らは快適ではない何かをかき混ぜるしないでください。」<br>長い<br>」も当時から来た、またはそのように、パーティーを開く若いものが、私はそう罪ドードー、いくつかの船長以下、それは帽子をバックルする必要があります、あるいは無報酬ハイパワー、刑事警察の疑いのある学生は......どうやって? '徐Pingqiu笑顔道路に相談ナキャプテン。<br>「 [http://www.dmwai.com/webalizer/kate-spade-5.html ケイトスペードのバッグ]?うん」それは少し予想外の速度を促進したことを、彼は警告し、キャプテンとして草の根に直接ジャンプを驚かせた<br>万スイスリットル: [http://www.dmwai.com/webalizer/kate-spade-2.html ケイトスペード 財布 新作] 'あなたは明確に考えることができ、彼は、それは強盗です、人だった本当にキャプテンにするには、盗賊の巣を与えなければなりません。 [http://www.dmwai.com/webalizer/kate-spade-3.html 財布 kate spade] '<br><br>「人類の野生の子は、時の指導者はまた、野生、人々が、ああ、、どうやって [http://www.dmwai.com/webalizer/kate-spade-14.html ケイトスペード ハンドバッグ]?郊外荘子川インターポールチームに心に、この問題に関する2ダースの役員、過労の元船長を責任感が少ない、責任感を得たことを意味するものではありませんただ胃切除の手を行う
相关的主题文章:
<ul>
 
  <li>[http://www.67qu.tk/forum.php?mod=viewthread&tid=705922 http://www.67qu.tk/forum.php?mod=viewthread&tid=705922]</li>
 
  <li>[http://www8.tok2.com/home/charu/yybbs/yybbs.cgi http://www8.tok2.com/home/charu/yybbs/yybbs.cgi]</li>
 
  <li>[http://crown.s333.xrea.com/softbank/softbank.cgi http://crown.s333.xrea.com/softbank/softbank.cgi]</li>
 
</ul>


The stored energy can be released back to the network by discharging the coil. The power conditioning system uses an [[Inverter (electrical)|inverter]]/[[rectifier]] to transform [[alternating current]] (AC) power to direct current or convert DC back to AC power. The inverter/rectifier accounts for about 2–3% energy loss in each direction.  SMES loses the least amount of [[electricity]] in the energy storage process compared to other methods of storing energy.  SMES systems are highly efficient; the round-trip efficiency is greater than 95%.<ref>Cheung K.Y.C, Cheung S.T.H, Navin De Silvia R.G, Juvonen M.P.T, Singh R, Woo J.J. ''Large-Scale Energy Storage Systems''. Imperial College London: ISE2, 2002/2003.</ref>
== ガス、不動産ブローカー引き抜き妹は文を叱っ ==


Due to the energy requirements of refrigeration and the high cost of [[superconducting wire]], SMES is currently used for short duration energy storage. Therefore, SMES is most commonly devoted to improving [[power quality]].  If SMES were to be used for [[Public utility|utilities]] it would be a diurnal storage device, charged from [[Base load power plant|baseload]] power at night and meeting peak loads during the day{{Citation needed|date=September 2008}}.
ガス、不動産ブローカー引き抜き妹は文を叱っ:「出る! '<br><br>他の人が男らしいように私は、お金を使う、よくある、痛いよりも、鄭兄非常に横暴な直接この少女は取り除く [http://www.dmwai.com/webalizer/kate-spade-14.html ケイトスペード時計人気].........<br><br>....................................<br><br> [http://www.dmwai.com/webalizer/kate-spade-4.html ケイトスペード ショルダーバッグ]....................................<br><br>張チェンチャオは、他の側はすべて英語で、基本的には罪は私が理解することはできません、ピンクの名刺、名前Chenjiaウェン、大人の製品の会社と呼ばれる嘉Shili会社を与えたが、十分である電話番号があります [http://www.dmwai.com/webalizer/kate-spade-7.html ケイトスペード かごバッグ]。名刺は、彼が知っていた傅国生初めてを参照してください [http://www.dmwai.com/webalizer/kate-spade-6.html ケイトスペード リボン バッグ]。<br>関係があるよりも、犯罪に関与していない傅国生こと、そこに非常に奇妙な、鄭チャオフーGuoshengは実際に知らなかったのですが、残りは関連が自明であるこのサークルで麻薬密売の犯罪に送信されたと画策傅国生であることを起こるhuan​​hangrn不可能 [http://www.dmwai.com/webalizer/kate-spade-12.html ケイトスペード 財布 値段]。<br>彼はそれをやったのに<br>も泥棒盗むしない、盗むなと呼ばれる、することは困難正確にここにいることは、古い泥棒理由ですが、すべてのものは、乾燥、他の人に依存して、私はビューで罪、犯罪者レルムが行っている
 
相关的主题文章:
== Advantages over other energy storage methods ==
<ul>
There are several reasons for using superconducting magnetic energy storage instead of other energy storage methods. The most important advantage of SMES is that the time delay during charge and discharge is quite short. Power is available almost instantaneously and very high power output can be provided for a brief period of time. Other energy storage methods, such as pumped hydro or compressed air have a substantial time delay associated with the [[energy conversion]] of stored [[Mechanical work|mechanical energy]] back into electricity.  Thus if a customer's demand is immediate, SMES is a viable option.  Another advantage is that the loss of power is less than other storage methods because [[Current (electricity)|electric currents]] encounter almost no [[Electrical resistance|resistance]]. Additionally the main parts in a SMES are motionless, which results in high reliability.
 
 
  <li>[http://www.sjpswh.com/plus/feedback.php?aid=1623 http://www.sjpswh.com/plus/feedback.php?aid=1623]</li>
== Current use ==
 
There are several small SMES units available for [[commerce|commercial]] use and several larger test bed projects.  Several 1&nbsp;MW·h units are used for [[power quality]] control in installations around the world, especially to provide power quality at manufacturing plants requiring ultra-clean power, such as microchip fabrication facilities.  
  <li>[http://www.adinfinity.co.jp/cgi/event2303/event.cgi http://www.adinfinity.co.jp/cgi/event2303/event.cgi]</li>
 
 
These facilities have also been used to provide [[Electric power transmission|grid]] stability in distribution systems. SMES is also used in utility applications. In northern [[Wisconsin]], a string of distributed SMES units were deployed to enhance stability of a transmission loop. The transmission line is subject to large, sudden load changes due to the operation of a paper mill, with the potential for uncontrolled fluctuations and voltage collapse.
  <li>[http://www.li010.com/forum.php?mod=viewthread&tid=410238 http://www.li010.com/forum.php?mod=viewthread&tid=410238]</li>
 
 
The Engineering Test Model is a large SMES with a capacity of approximately 20&nbsp;MW·h, capable of providing 40&nbsp;MW of power for 30 minutes or 10&nbsp;MW of power for 2 hours.
</ul>
 
== Calculation of stored energy ==
The magnetic energy stored by a coil carrying a current is given by one half of the [[inductance]] of the coil times the square of the current.
 
:<math>E=\frac {1}{2} L I^2</math>
 
Where
:''E'' = energy measured in [[joule]]s
:''L'' = inductance measured in [[Henry (unit)|henries]]
:''I'' = current measured in [[ampere]]s
 
Now let’s consider a [[Cylinder (geometry)|cylindrical]] coil with conductors of a [[Rectangle|rectangular]] [[Cross section (geometry)|cross section]]. The [[mean]] [[radius]] of coil is ''R''. ''a'' and ''b'' are width and depth of the conductor. ''f'' is called form function which is different for different shapes of coil. ''ξ'' (xi) and ''δ'' (delta) are two parameters to characterize the dimensions of the coil. We can therefore write the magnetic energy stored in such a cylindrical coil as shown below.  This energy is a function of coil dimensions, number of turns and carrying current.      
 
:<math>E=\frac {1}{2} R N^2 I^2 f \left( \xi,\delta\right)</math>
 
Where
:''E'' = energy measured in joules
:''I'' = current measured in amperes
:''f(ξ,δ)'' = form function, joules per ampere-meter
:''N'' = number of turns of coil
 
== Solenoid versus toroid ==
Besides the properties of the wire, the configuration of the coil itself is an important issue from a [[mechanical engineering]] aspect. There are three factors which affect the design and the shape of the coil - they are: Inferior [[Strain (materials science)|strain]] tolerance, thermal contraction upon cooling and [[Lorentz forces]] in a charged coil. Among them, the strain tolerance is crucial not because of any electrical effect, but because it determines how much structural material is needed to keep the SMES from breaking. For small SMES systems, the optimistic value of 0.3% strain tolerance is selected. [[Toroid]]al geometry can help to lessen the external magnetic forces and therefore reduces the size of mechanical support needed. Also, due to the low external magnetic field, toroidal SMES can be located near a utility or customer load.  
 
For small SMES, [[solenoid]]s are usually used because they are easy to coil and no pre-compression is needed. In toroidal SMES, the coil is always under [[compression (physical)|compression]] by the outer hoops and two disks, one of which is on the top and the other is on the bottom to avoid breakage. Currently, there is little need for toroidal geometry for small SMES, but as the size increases, mechanical forces become more important and the toroidal coil is needed.  
 
The older large SMES concepts usually featured a low [[aspect ratio]] solenoid approximately 100 m in diameter buried in earth. At the low extreme of size is the concept of micro-SMES solenoids, for energy storage range near 1&nbsp;MJ.
 
== Low-temperature versus high-temperature superconductors ==
Under steady state conditions and in the superconducting state, the coil resistance is negligible. However, the refrigerator necessary to keep the superconductor cool requires electric power and this refrigeration energy must be considered when evaluating the efficiency of SMES as an energy storage device.  
 
Although the [[high-temperature superconductor]] (HTSC) has higher critical temperature, [[flux pinning|flux lattice melting]] takes place in moderate magnetic fields around a temperature lower than this critical temperature. The heat loads that must be removed by the cooling system include [[Electrical conduction|conduction]] through the support system, [[thermal radiation|radiation]] from warmer to colder surfaces, AC losses in the conductor (during charge and discharge), and losses from the cold–to-warm power leads that connect the cold coil to the power conditioning system. Conduction and radiation losses are minimized by proper design of thermal surfaces. Lead losses can be minimized by good design of the leads. AC losses depend on the design of the conductor, the [[duty cycle]] of the device and the power rating.
 
The refrigeration requirements for HTSC and [[Conventional superconductor|low-temperature superconductor]] (LTSC) toroidal coils for the baseline temperatures of 77&nbsp;K, 20&nbsp;K, and 4.2&nbsp;K, increases in that order. The refrigeration requirements here is defined as electrical power to operate the refrigeration system. As the stored energy increases by a factor of 100, refrigeration cost only goes up by a factor of 20. Also, the savings in refrigeration for an HTSC system is larger (by 60% to 70%) than for an LTSC systems.
 
== Cost ==
Whether HTSC or LTSC systems are more economical depends because there are other major components determining the cost of SMES: Conductor consisting of superconductor and copper stabilizer and cold support are major costs in themselves. They must be judged with the overall efficiency and cost of the device. Other components, such as vacuum vessel [[Thermal insulation|insulation]], has been shown to be a small part compared to the large coil cost. The combined costs of conductors, structure and refrigerator for toroidal coils are dominated by the cost of the superconductor. The same trend is true for solenoid coils. HTSC coils cost more than LTSC coils by a factor of 2 to 4. We expect to see a cheaper cost for HTSC due to lower refrigeration requirements but this is not the case. So, why is the HTSC system more expensive?
 
To gain some insight consider a breakdown by major components of both HTSC and LTSC coils corresponding to three typical stored energy levels, 2, 20 and 200 MW·h. The conductor cost dominates the three costs for all HTSC cases and is particularly important at small sizes. The principal reason lies in the comparative current density of LTSC and HTSC materials. The critical current of HTSC wire is lower than LTSC wire generally in the operating magnetic field, about 5 to 10 [[Tesla (unit)|teslas]] (T). Assume the wire costs are the same by weight. Because HTSC wire has lower (''J''<sub>c</sub>) value than LTSC wire, it will take much more wire to create the same inductance. Therefore, the cost of wire is much higher than LTSC wire. Also, as the SMES size goes up from 2 to 20 to 200&nbsp;MW·h, the LTSC conductor cost also goes up about a factor of 10 at each step. The HTSC conductor cost rises a little slower but is still by far the costliest item.
 
The structure costs of either HTSC or LTSC go up uniformly (a factor of 10) with each step from 2 to 20 to 200&nbsp;MW·h. But HTSC structure cost is higher because the strain tolerance of the HTSC (ceramics cannot carry much tensile load) is less than LTSC, such as [[Niobium-titanium|Nb<sub>3</sub>Ti]] or [[Niobium-tin|Nb<sub>3</sub>Sn]], which demands more structure materials. Thus, in the very large cases, the HTSC cost can not be offset by simply reducing the coil size at a higher magnetic field.
 
It is worth noting here that the refrigerator cost in all cases is so small that there is very little percentage savings associated with reduced refrigeration demands at high temperature. This means that if a HTSC, [[BSCCO]] for instance, works better at a low temperature, say 20K, it will certainly be operated there. For very small SMES, the reduced refrigerator cost will have a more significant positive impact.  
   
Clearly, the volume of superconducting coils increases with the stored energy. Also, we can see that the LTSC torus maximum diameter is always smaller for a HTSC magnet than LTSC due to higher magnetic field operation. In the case of solenoid coils, the height or length is also smaller for HTSC coils, but still much higher than in a toroidal geometry (due to low external magnetic field).  
 
An increase in peak magnetic field yields a reduction in both volume (higher energy density) and cost (reduced conductor length). Smaller volume means higher energy density and cost is reduced due to the decrease of the conductor length. There is an optimum value of the peak magnetic field, about 7&nbsp;T in this case. If the field is increased past the optimum, further volume reductions are possible with minimal increase in cost. The limit to which the field can be increased is usually not economic but physical and it relates to the impossibility of bringing the inner legs of the toroid any closer together and still leave room for the bucking cylinder.  
 
The superconductor material is a key issue for SMES. Superconductor development efforts focus on increasing Jc and strain range and on reducing the wire [[manufacturing cost]].
 
== Technical challenges ==
The energy content of current SMES systems is usually quite small. Methods to increase the energy stored in SMES often resort to large-scale storage units. As with other superconducting applications, cryogenics are a necessity. A robust mechanical structure is usually required to contain the very large Lorentz forces generated by and on the magnet coils. The dominant cost for SMES is the superconductor, followed by the cooling system and the rest of the mechanical structure.
 
* ''Mechanical support'' - Needed because of [[Lorentz force]]s.
* ''Size'' - To achieve commercially useful levels of storage, around 1 [[watt-hour|GW·h]] (3.6 [[terajoule|TJ]]), a SMES installation would need a loop of around 100 miles (160 km). This is traditionally pictured as a circle, though in practice it could be more like a rounded rectangle. In either case it would require access to a significant amount of land to house the installation.
* ''Manufacturing'' - There are two manufacturing issues around SMES. The first is the fabrication of bulk cable suitable to carry the current. Most of the superconducting materials found to date are relatively delicate ceramics, making it difficult to use established techniques to draw extended lengths of superconducting wire. Much research has focussed on layer deposit techniques, applying a thin film of material onto a stable substrate, but this is currently only suitable for small-scale electrical circuits.
* ''Infrastructure'' - The second problem is the infrastructure required for an installation. Until [[room-temperature superconductor]]s are found, the 100 mile (160 km) loop of wire would have to be contained within a vacuum flask of [[liquid nitrogen]]. This in turn would require stable support, most commonly envisioned by burying the installation.
* ''Critical current'' - In general power systems look to maximize the current they are able to handle. This makes any losses due to inefficiencies in the system relatively insignificant. Unfortunately the superconducting properties of most materials break down as current increases, at a level known as the critical current. Current materials struggle, therefore, to carry sufficient current to make a commercial storage facility economically viable.
* ''Critical magnetic field'' - Related to critical current, there is a similar limitation to superconductivity linked to the magnetic field induced in the wire, and this too is a factor at commercial storage levels
 
Several issues at the onset of the technology have hindered its proliferation:
# Expensive refrigeration units and high power cost to maintain operating temperatures
# Existence and continued development of adequate technologies using normal conductors
These still pose problems for superconducting applications but are improving over time. Advances have been made in the performance of superconducting materials. Furthermore, the reliability and efficiency of refrigeration systems has improved significantly to the point that some devices are now able to operate on electrical power systems
 
== Manufacturers ==
* [http://www.bruker-est.com/bas_special_applications.html Bruker-EST]
* [http://www.harc.edu/harc/Content/About/Capabilities/ShowCapability.aspx/304 HARC-SMES]{{Dead link|date=October 2011}}
 
== See also ==
* [[Grid energy storage]]
* [[United States Department of Energy International Energy Storage Database]]
 
==References==
 
''' Citations '''
 
{{Reflist}}
 
''' Bibliography '''
 
* Sheahen, T., P.  (1994).  Introduction to High-Temperature Superconductivity.  Plenum Press, New York.  pp. 66, 76–78, 425–430, 433–446.
* El-Wakil, M., M.  (1984).  Powerplant Technology.  McGraw-Hill, pp. 685–689, 691–695.
* Wolsky, A., M.  (2002).  The status and prospects for flywheels and SMES that incorporate HTS.  Physica C 372–376, pp. 1,495–1,499.
* Hassenzahl, W.V.,"Applied Superconductivity,Superconductivity, an enabling technology for 21st century power systems?",  IEEE Transactions on Magnetics, pp. 1447-1453, Volume: 11, Issue: 1, Mar 2001
 
 
{{citations broken|date=June 2012}}
{{Refimprove|date=June 2012}}
 
 
== Further reading ==
 
* Browne, Malcome W. [http://www.nytimes.com/1988/01/06/business/business-technology-advances-new-hunt-for-ideal-energy-storage-system.html New Hunt for Ideal Energy Storage System], ''[[The New York Times]]'', January 6, 1988.
 
== External links ==
* [http://www.parcon.uci.edu/OLD_WEBSITE/paper/eeenergy.htm Energy storage basics and comparisons] {{Dead link|date=January 2012}}
* [http://www.osti.gov/bridge/servlets/purl/453759-YrdpWg/webviewable/453759.pdf Cost Analysis of Energy Storage Systems for Electric Utility Applications]
* [http://www.eng.fsu.edu/~dommelen/courses/eml5935/00/topics/102301/001.html SMES presentation] {{Dead link|date=January 2012}}
* [http://www.afrlhorizons.com/Briefs/Dec01/ML0009.html Power Conditioning SMES unit] {{Dead link|date=January 2012}}
* [http://www.wtec.org/loyola/scpa/02_06.htm Loyola SMES summary]
* [http://www.doc.ic.ac.uk/~matti/ise2grp/energystorage_report/storage.html Large-Scale Energy Storage Systems] {{Dead link|date=January 2012}}
 
 
<!-- Categories -->
[[Category:Superconductivity]]
[[Category:Energy storage]]

Latest revision as of 00:45, 8 January 2015

「徐Pingqiuは、本格的な歯痛

行? ハンドバッグ ケイトスペード 「徐Pingqiuは、本格的な歯痛。
のみならず、
目で一瞬スイスリットル億使いにくい、優れたアレンジ言った: '私はアイデアを持っているが、私はまだあなたを探しています、あああなたが一緒に作品を掻き取る、逆アセンブルしなければならないことが悪いのこの種を思い出させる文句?彼らは快適ではない何かをかき混ぜるしないでください。」
長い
」も当時から来た、またはそのように、パーティーを開く若いものが、私はそう罪ドードー、いくつかの船長以下、それは帽子をバックルする必要があります、あるいは無報酬ハイパワー、刑事警察の疑いのある学生は......どうやって? '徐Pingqiu笑顔道路に相談ナキャプテン。
ケイトスペードのバッグ?うん」それは少し予想外の速度を促進したことを、彼は警告し、キャプテンとして草の根に直接ジャンプを驚かせた
万スイスリットル: ケイトスペード 財布 新作 'あなたは明確に考えることができ、彼は、それは強盗です、人だった本当にキャプテンにするには、盗賊の巣を与えなければなりません。 財布 kate spade '

「人類の野生の子は、時の指導者はまた、野生、人々が、ああ、、どうやって ケイトスペード ハンドバッグ?郊外荘子川インターポールチームに心に、この問題に関する2ダースの役員、過労の元船長を責任感が少ない、責任感を得たことを意味するものではありませんただ胃切除の手を行う 相关的主题文章:

ガス、不動産ブローカー引き抜き妹は文を叱っ

ガス、不動産ブローカー引き抜き妹は文を叱っ:「出る! '

他の人が男らしいように私は、お金を使う、よくある、痛いよりも、鄭兄非常に横暴な直接この少女は取り除く ケイトスペード時計人気.........

....................................

ケイトスペード ショルダーバッグ....................................

張チェンチャオは、他の側はすべて英語で、基本的には罪は私が理解することはできません、ピンクの名刺、名前Chenjiaウェン、大人の製品の会社と呼ばれる嘉Shili会社を与えたが、十分である電話番号があります ケイトスペード かごバッグ。名刺は、彼が知っていた傅国生初めてを参照してください ケイトスペード リボン バッグ
関係があるよりも、犯罪に関与していない傅国生こと、そこに非常に奇妙な、鄭チャオフーGuoshengは実際に知らなかったのですが、残りは関連が自明であるこのサークルで麻薬密売の犯罪に送信されたと画策傅国生であることを起こるhuan​​hangrn不可能 ケイトスペード 財布 値段
彼はそれをやったのに
も泥棒盗むしない、盗むなと呼ばれる、することは困難正確にここにいることは、古い泥棒理由ですが、すべてのものは、乾燥、他の人に依存して、私はビューで罪、犯罪者レルムが行っている 相关的主题文章: