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| '''Landau theory''' in [[physics]] was introduced by [[Lev Landau]] in an attempt to formulate a general theory of second-order [[phase transition]]s.<ref>[http://www.ujp.bitp.kiev.ua/files/journals/53/si/53SI08p.pdf Landau L.D., Zh. Eksp. Teor. Fiz. 7, pp. 19–32 (1937)]</ref>
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| ==Mean-field formulation (no long-range correlation)==
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| {{main|Mean field theory}}
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| Landau was motivated to suggest that the free energy of any system should obey two conditions:
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| *it is analytic
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| *it obeys the symmetry of the [[Hamiltonian mechanics|Hamiltonian]]
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| Given these two conditions, one can write down (in the vicinity of the critical temperature, ''T''<sub>''c''</sub>) a phenomenological expression for the free energy as a [[Taylor expansion]] in the [[Phase transitions#Order parameters|order parameter]].
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| ===Ising Model Example===
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| For example, the [[Ising model]] free energy may be written as the following, where the variable <math>\Psi</math> is the coarse-grained field of spins, known as the [[Phase transition#Order parameters|order parameter]] or the total magnetization.
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| :<math> F = a + r\Psi^2 + s\Psi^4 + H\Psi \,</math>
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| where,for physical reasons{{which|date=November 2013}}, the parameter
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| :<math>r = r_0 (T - T_c) \,</math>
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| and the constant <math>a</math> can be safely taken to be zero{{why|date=November 2013}}.
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| The Ising model theory of Landau first raised the order parameter to prominence. Note that the Ising model exhibits the following discrete symmetry: If every spin in the model is flipped, such that <math> {S_i} \rightarrow {-S_i} </math>, where <math> S_i </math> is the value of the <math> i^{th} </math> spin, the Hamiltonian (and consequently the free energy) remains unchanged for zero external field <math> (H=0) </math>. This symmetry is reflected in the even powers of <math> \Psi </math> in <math> F </math>.
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| ===Applications===
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| Landau theory has been extraordinarily useful. While the exact values of the parameters <math>r</math> and <math>s</math> were unknown, [[critical exponent]]s could still be calculated with ease, and only depend on the original assumptions of symmetry and analyticity. For the Ising model case, the equilibrium magnetization <math>\Psi</math> assumes the following value below the critical temperature <math>T_c</math>:
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| :<math> \Psi = \pm \sqrt{\frac{-r_0 (T - T_c)}{2s}}. </math>
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| At the time, it was known experimentally that the liquid-gas coexistence curve and the ferromagnet magnetization curve both exhibited a scaling relation of the form <math> |T - T_c|^{\beta} </math>, where <math>\beta</math> was mysteriously the same for both systems. This is the phenomenon of [[Phase transition|universality]]. It was also known that simple liquid-gas models are exactly mappable to simple magnetic models, which implied that the two systems possess the same symmetries. It then followed from Landau theory why these two apparently disparate systems should have the same critical exponents, despite having different microscopic parameters. It is now known that the phenomenon of [[Phase transition|universality]] arises for other reasons (see [[Renormalization group]]). In fact, Landau theory predicts the incorrect critical exponents for the Ising and liquid-gas systems.
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| The great virtue of Landau theory is that it makes specific predictions{{which|date=November 2013}} for what kind of non-analytic behavior one should see when the underlying free energy is analytic. Then, all the non-analyticity at the critical point, the critical exponents, are because the ''equilibrium value'' of the order parameter changes non-analytically, as a square root, whenever the free energy loses its unique minimum.
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| The extension of Landau theory to include fluctuations in the order parameter shows that Landau theory is only strictly valid near the critical points of ordinary systems with spatial dimensions of higher than 4. This is the [[upper critical dimension]], and it can be much higher than four in more finely tuned phase transition. In [[Mukhamel]]'s analysis of the isotropic Lifschitz point, the critical dimension is 8. This is because Landau theory is a [[mean field theory]], and does not include long-range correlations.
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| This theory does not explain non-analyticity{{which|date=November 2013}} at the critical point, but when applied to [[superfluidity|superfluid]] and superconductor phase transition, Landau's theory provided inspiration for another theory, the [[Ginzburg–Landau theory]] of [[superconductivity]].
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| ==Including long-range correlations==
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| Consider the Ising model free energy above. Assume that the order parameter <math>\Psi </math> and external magnetic field, <math>H</math>, may have spatial variations. Now, the free energy of the system can be assumed to take the following modified form:
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| :<math> F := \int d^D x \ \left( a(T) + r(T) \psi^2(x) + s(T) \psi^4(x) \ + f(T) (\nabla \psi(x))^2 \ +h(x) \psi(x)\ \ + \mathcal{O}(\psi^6 ; (\nabla \psi)^4) \right) </math>
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| where <math>D</math> is the total ''spatial'' dimensionality. So,
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| :<math> \langle \psi(x) \rangle := \frac{\text{Tr}\ \psi(x) \exp^{-\beta H}}{Z} </math>
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| Assume that, for a ''localized'' external magnetic perturbation <math> h(x) \rightarrow 0 + h_0 \delta(x) </math>, the order parameter takes the form <math> \psi(x) \rightarrow \psi_0 + \phi(x) </math>. Then,
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| :<math> \frac{\delta \langle \psi(x) \rangle}{\delta h(0)} = \frac{\phi(x)}{h_0} = \beta \left ( \langle \psi(x) \psi(0) \rangle - \langle \psi(x) \rangle \langle \psi(0) \rangle \right ) </math>
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| That is, the fluctuation <math>\phi(x)</math> in the order parameter corresponds to the order-order correlation. Hence, neglecting this fluctuation (like in the earlier mean-field approach) corresponds to neglecting the order-order correlation, which diverges near the critical point.
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| One can also solve <ref>"Equilibrium Statistical Physics" by Michael Plischke, Birger Bergersen, Section 3.10, 3rd ed</ref> for <math> \phi(x)</math>, from which the scaling exponent, <math> \nu </math>, for correlation length <math> \xi \sim (T-T_c)^{-\nu} </math> can deduced. From these, the [[Ginzburg criterion]] for the [[upper critical dimension]] for the validity of the Ising mean-field Landau theory (the one without long-range correlation) can be calculated as:
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| :<math> D \ge 2 + 2 \frac{\beta}{\nu}</math>
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| In our current Ising model, mean-field Landau theory gives <math>\beta = 1/2 = \nu </math> and so, it (the Ising mean-field Landau theory) is valid only for spatial dimensionality greater than or equal to 4 (at the marginal values of <math>D=4</math>, there are small corrections to the exponents). This modified version of mean-field Landau theory is sometimes also referred to as the Landau-Ginzburg theory of Ising phase transitions. As a clarification, there is also a [[Landau-Ginzburg theory]] specific to superconductivity phase transition, which also includes fluctuations.
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| ==See also==
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| [[Ginzburg–Landau theory]]
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| [[Ginzburg criterion]]
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| ==Further reading== | |
| * Landau L.D. ''Collected Papers'' (Nauka, Moscow, 1969)
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| * Michael C. Cross, ''Landau theory of second order phase transitions'', [http://www.pma.caltech.edu/~mcc/Ph127/b/Lecture6.pdf] (Caltech statistical mechanics lecture notes).
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| * Yukhnovskii, I R, ''Phase Transitions of the Second Order - Collective Variables Method'', World Scientific, 1987, ISBN 9971-5-0087-6
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| ==Footnotes==
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| <references />
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| [[Category:Statistical mechanics]]
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| [[Category:Condensed matter physics]]
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