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| {{Use dmy dates|date=July 2013}}
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| {{Chembox
| |
| | Watchedfields = changed
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| | verifiedrevid = 477167117
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| | ImageFileL1 = Ethanol-2D-flat.png
| |
| | ImageFileL1_Ref = {{chemboximage|correct|??}}
| |
| | ImageSizeL1 = 131
| |
| | ImageNameL1 = Full structural formula of ethanol
| |
| | ImageFileR1 = Ethanol-2D-skeletal.svg
| |
| | ImageFileR1_Ref = {{chemboximage|correct|??}}
| |
| | ImageSizeR1 = 111
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| | ImageNameR1 = Skeletal formula of ethanol
| |
| | ImageFileL2 = Ethanol-3D-balls.png
| |
| | ImageFileL2_Ref = {{chemboximage|correct|??}}
| |
| | ImageSizeL2 = 131
| |
| | ImageNameL2 = Ball-and-stick model of ethanol
| |
| | ImageFileR2 = Ethanol-3D-vdW.png
| |
| | ImageFileR2_Ref = {{chemboximage|correct|??}}
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| | ImageSizeR2 = 111
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| | ImageNameR2 = Space-filling model of ethanol
| |
| | SystematicName = Ethanol<ref name="Pubchem">{{cite web|title = Ethanol – Compound Summary|url = http://pubchem.ncbi.nlm.nih.gov/summary/summary.cgi?cid=702|work = The PubChem Project|location = USA|publisher = National Center for Biotechnology Information}}</ref>
| |
| | OtherNames = {{Plainlist|
| |
| * Absolute alcohol
| |
| * Alcohol
| |
| * Drinking alcohol
| |
| * Ethyl alcohol
| |
| * Ethyl hydrate
| |
| * Ethyl hydroxide
| |
| * Ethylic alcohol
| |
| * Ethylol
| |
| * Grain alcohol
| |
| * Hydroxyethane
| |
| * Methylcarbinol
| |
| }}
| |
| | Section1 = {{Chembox Identifiers
| |
| | CASNo = 64-17-5
| |
| | CASNo_Ref = {{cascite|correct|CAS}}
| |
| | PubChem = 702
| |
| | PubChem_Ref = {{Pubchemcite|correct|PubChem}}
| |
| | ChemSpiderID = 682
| |
| | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| |
| | UNII = 3K9958V90M
| |
| | UNII_Ref = {{fdacite|correct|FDA}}
| |
| | EINECS = 200-578-6
| |
| | UNNumber = 1170
| |
| | DrugBank_Ref = {{drugbankcite|correct|drugbank}}
| |
| | DrugBank = DB00898
| |
| | KEGG = D00068
| |
| | KEGG_Ref = {{keggcite|correct|kegg}}
| |
| | MeSHName = Ethanol
| |
| | ChEBI_Ref = {{ebicite|correct|EBI}}
| |
| | ChEBI = 16236
| |
| | ChEMBL = 545
| |
| | ChEMBL_Ref = {{ebicite|correct|EBI}}
| |
| | RTECS = KQ6300000
| |
| | ATCCode_prefix = D01
| |
| | ATCCode_suffix = AE06
| |
| | ATC_Supplemental = {{ATC|D08|AX08}}, {{ATC|V03|AB16}}, {{ATC|V03|AZ01}}
| |
| | Beilstein = 1718733
| |
| | Gmelin = 787
| |
| | 3DMet = B01253
| |
| | SMILES = CCO
| |
| | StdInChI = 1S/C2H6O/c1-2-3/h3H,2H2,1H3
| |
| | StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| |
| | InChI = 1/C2H6O/c1-2-3/h3H,2H2,1H3
| |
| | StdInChIKey = LFQSCWFLJHTTHZ-UHFFFAOYSA-N
| |
| | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| |
| | InChIKey = LFQSCWFLJHTTHZ-UHFFFAOYAB}}
| |
| | Section2 = {{Chembox Properties
| |
| | C = 2
| |
| | H = 6
| |
| | O = 1
| |
| | ExactMass = 46.041864814 g mol<sup>−1</sup>
| |
| | Appearance = Colorless liquid
| |
| | Density = 0.789 g/cm<sup>3</sup> (at 20°C)
| |
| | MeltingPtC = −114
| |
| | BoilingPtC = 78.37
| |
| | LogP = -0.18
| |
| | VaporPressure = 5.95 kPa (at 20 °C)
| |
| | pKa = 15.9<ref>{{cite journal|doi=10.1021/ja01489a008|year=1960|last1=Ballinger|first1=P.|last2=Long|first2=F. A.|journal=Journal of the American Chemical Society|volume=82|issue=4|page=795}}</ref>
| |
| | pKb = -1.9
| |
| | RefractIndex = 1.361
| |
| | Viscosity = 0.0012 Pa s (at 20 °C), 0.001074 Pa s (at 25 °C)<ref name=crc92>{{Cite book|editor=Lide, David R.|title=CRC Handbook of Chemistry and Physics|edition=92|year=2012|publisher=CRC Press/Taylor and Francis|location=Boca Raton, FL.|pages=6–232}}</ref>
| |
| | Dipole = 1.69 D<ref name=crc89>{{Cite book|editor=Lide, David R.|title=CRC Handbook of Chemistry and Physics|edition=89|year=2008|publisher=CRC Press|location=Boca Raton|pages=9–55}}</ref>
| |
| }}
| |
| | Section3 = {{Chembox Pharmacology
| |
| | AdminRoutes = Intramuscular<br />
| |
| Intravenous<br />
| |
| Oral<br />
| |
| Topical
| |
| | Metabolism = Hepatic
| |
| | [[Dependence liability]] – low-moderate
| |
| }}
| |
| | Section4 = {{Chembox Hazards
| |
| | EUIndex = 603-002-00-5
| |
| | EUClass = {{Hazchem F}}
| |
| | RPhrases = {{R11}}
| |
| | SPhrases = {{S2}}, {{S7}}, {{S16}}
| |
| | NFPA-H = 2
| |
| | NFPA-F = 3
| |
| | NFPA-R = 0
| |
| | FlashPt = 13–14 °C
| |
| | Autoignition = 363 °C<ref>{{cite web |url=http://www.engineeringtoolbox.com/fuels-ignition-temperatures-d_171.html |title=Fuels and Chemicals – Autoignition Temperatures |publisher=engineeringtoolbox.com |postscript=<!-- Bot inserted parameter. Either remove it; or change its value to "." for the cite to end in a ".", as necessary. -->{{inconsistent citations}}
| |
| }}</ref>
| |
| | LD50 = 5628 mg kg<sup>−1</sup> (oral, rat)
| |
| }}
| |
| }}
| |
| | |
| This page provides supplementary chemical data on [[ethanol]]. Except where noted otherwise, data relate to [[standard ambient temperature and pressure]].
| |
| | |
| == Material Safety Data Sheet == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
| |
| | |
| The handling of this chemical may incur notable safety precautions. It is highly recommend that you seek the Material Safety Datasheet ([[Material safety data sheet|MSDS]]) for this chemical from a reliable source and follow its directions.
| |
| | |
| == Structure and properties == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
| |
| | |
| {| border="1" cellspacing="0" cellpadding="3" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
| |
| ! {{chembox header}} | Structure and properties
| |
| |-
| |
| | [[Index of refraction]], ''n''<sub>25</sub>
| |
| | 1.361 <!-- Please omit if not applicable -->
| |
| |-
| |
| | [[Dielectric constant]], ε<sub>r</sub>
| |
| | 24.3 ε<sub>0</sub> at 25 °C <!-- Please omit if not applicable -->
| |
| |-
| |
| | [[Bond strength (chemistry)|Bond strength]]
| |
| | ? <!-- Specify which bond. Please omit if not applicable -->
| |
| |-
| |
| | [[Bond length]]
| |
| | ? <!-- Specify which bond. Please omit if not applicable -->
| |
| |-
| |
| | [[Bond angle]]
| |
| | ? <!-- Specify which angle, e.g. Cl-P-O. Please omit if not applicable -->
| |
| |-
| |
| | [[Magnetic susceptibility]]<ref>[http://nmr.chem.umn.edu/ResReports/NMR002.html NMR-002: Sample Devices and Magnetic Susceptibility<!-- Bot generated title -->]</ref>
| |
| | 5.8·10<sup>−7</sup> ([[cgs]] units, volume)
| |
| |-
| |
| | [[Surface tension]]
| |
| | 22.39 dyn/cm at 25 °C
| |
| |-
| |
| | [[Viscosity]]<ref name="cheric_p">{{Cite web|url=http://www.cheric.org/research/kdb/hcprop/cmpsrch.php|title=Pure Component Properties|format=Queriable database|publisher=Chemical Engineering Research Information Center|accessdate=12 May 2007}}</ref>
| |
| |
| |
| {|
| |
| |-
| |
| | 6.285 mPa·s || at –50 °C
| |
| |-
| |
| | 4.656 mPa·s || at –40 °C
| |
| |-
| |
| | 3.530 mPa·s || at –30 °C
| |
| |-
| |
| | 2.731 mPa·s || at –20 °C
| |
| |-
| |
| | 2.419 mPa·s || at –15 °C
| |
| |-
| |
| | 2.151 mPa·s || at –10 °C
| |
| |-
| |
| | 1.920 mPa·s || at –5 °C
| |
| |-
| |
| | 1.720 mPa·s || at 0 °C
| |
| |-
| |
| | 1.546 mPa·s || at 5 °C
| |
| |-
| |
| | 1.394 mPa·s || at 10 °C
| |
| |-
| |
| | 1.261 mPa·s || at 15 °C
| |
| |-
| |
| | 1.144 mPa·s || at 20 °C
| |
| |-
| |
| | 1.040 mPa·s || at 25 °C
| |
| |-
| |
| | 0.949 mPa·s || at 30 °C
| |
| |-
| |
| | 0.794 mPa·s || at 40 °C
| |
| |-
| |
| | 0.670 mPa·s || at 50 °C
| |
| |-
| |
| | 0.570 mPa·s || at 60 °C
| |
| |-
| |
| | 0.487 mPa·s || at 70 °C
| |
| |-
| |
| | 0.452 mPa·s || at 75 °C
| |
| |-
| |
| |}
| |
| |}
| |
| | |
| == Thermodynamic properties == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
| |
| | |
| {| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
| |
| ! {{chembox header}} | Phase behavior
| |
| |-
| |
| | [[Triple point]]
| |
| | 150 K (−123 °C), 0.00043 Pa
| |
| |-
| |
| | [[Critical point (thermodynamics)|Critical point]]
| |
| | 514 K (241 °C), 63 bar
| |
| |-
| |
| | [[Standard enthalpy change of fusion|Std enthalpy change<br/>of fusion]], Δ<sub>fus</sub>''H''<sup><s>o</s></sup>
| |
| | +4.9 kJ/mol
| |
| |-
| |
| | [[Standard entropy change of fusion|Std entropy change<br/>of fusion]], Δ<sub>fus</sub>''S''<sup><s>o</s></sup>
| |
| | +31 J/(mol·K)
| |
| |-
| |
| | [[Standard enthalpy change of vaporization|Std enthalpy change<br/>of vaporization]], Δ<sub>vap</sub>''H''<sup><s>o</s></sup>
| |
| | +38.56 kJ/mol
| |
| |-
| |
| | [[Standard entropy change of vaporization|Std entropy change<br/>of vaporization]], Δ<sub>vap</sub>''S''<sup><s>o</s></sup>
| |
| | 109.67 J/(mol·K)
| |
| |-
| |
| | [[Freezing-point depression|Molal freezing point constant]]
| |
| | –1.99 °C kg/mol
| |
| |-
| |
| | [[Boiling-point elevation|Molal boiling point constant]]
| |
| | 1.19 °C kg/mol
| |
| |-
| |
| ! {{chembox header}} | Solid properties
| |
| |-
| |
| | [[Standard enthalpy change of formation|Std enthalpy change<br/>of formation]], Δ<sub>f</sub>''H''<sup><s>o</s></sup><sub>solid</sub>
| |
| | –277.7 kJ/mol
| |
| |-
| |
| | [[Standard molar entropy]],<br/>''S''<sup><s>o</s></sup><sub>solid</sub>
| |
| | 160.7 J/(mol K)<ref name=atkins>{{cite book|last=Atkins|first=Peter|title=Atkins' Physical Chemistry|year=2010|publisher=Oxford University Press|pages=913–947}}</ref>
| |
| |-
| |
| | [[Heat capacity]], ''c<sub>p</sub>''
| |
| | 111.46 J/(mol K) <ref name="atkins"/>
| |
| |-
| |
| ! {{chembox header}} | Liquid properties
| |
| |-
| |
| | [[Standard enthalpy change of formation|Std enthalpy change<br/>of formation]], Δ<sub>f</sub>''H''<sup><s>o</s></sup><sub>liquid</sub>
| |
| | −277.38 kJ/mol
| |
| |-
| |
| | [[Standard molar entropy]],<br/>''S''<sup><s>o</s></sup><sub>liquid</sub>
| |
| | 159.9 J/(mol K)
| |
| |-
| |
| | [[Enthalpy of combustion]], Δ<sub>c</sub>''H''<sup><s>o</s></sup>
| |
| | –1370.7 kJ/mol
| |
| |-
| |
| | [[Heat capacity]], ''c<sub>p</sub>''
| |
| | 112.4 J/(mol K)
| |
| |-
| |
| ! {{chembox header}} | Gas properties
| |
| |-
| |
| | [[Standard enthalpy change of formation|Std enthalpy change<br/>of formation]], Δ<sub>f</sub>''H''<sup><s>o</s></sup><sub>gas</sub>
| |
| | −235.3 kJ/mol
| |
| |-
| |
| | [[Standard molar entropy]],<br/>''S''<sup><s>o</s></sup><sub>gas</sub>
| |
| | 283 J/(mol K)
| |
| |-
| |
| | [[Heat capacity]],<ref name="lange1525">''Lange's Handbook of Chemistry'' 10th ed, pp 1525-1528</ref><ref name="crc1582">''CRC Handbook of Chemistry and Physics'' 44th ed. pp 2582-2584</ref> ''c<sub>p</sub>''
| |
| | 78.28 J/(mol K) at 90 °C<br>87.53 J/(mol K) at 110-220 °C
| |
| |-
| |
| | [[Heat capacity ratio]],<ref name="lange1525"/><ref name="crc1582"/><br> ''γ'' = ''c<sub>p</sub>''/''c<sub>v</sub>''
| |
| | 1.13 at 90 °C
| |
| |-
| |
| | [[van der Waals equation|van der Waals' constants]]<ref name="lange1522">''Lange's Handbook of Chemistry'' 10th ed, pp 1522-1524</ref>
| |
| | a = 1217.9 L<sup>2</sup> kPa/mol<sup>2</sup><br> b = 0.08407 liter per mole
| |
| |-
| |
| |}
| |
| | |
| == Spectral data == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
| |
| | |
| {| border="1" cellspacing="0" cellpadding="3" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
| |
| ! {{chembox header}} | [[UV/VIS spectroscopy|UV-Vis]]
| |
| |-
| |
| | [[Lambda-max|λ<sub>max</sub>]]
| |
| | ? [[Nanometre|nm]]
| |
| |-
| |
| | [[molar absorptivity|Extinction coefficient]], ε
| |
| | ?
| |
| |-
| |
| ! {{chembox header}} | [[Infrared|IR]]
| |
| |-
| |
| | Major absorption bands<ref name="aist">{{Cite web|url=http://riodb01.ibase.aist.go.jp/sdbs/cgi-bin/cre_index.cgi?lang=eng|title=Spectral Database for Organic Compounds|publisher=Advanced Industrial Science and Technology|format=Queriable database|accessdate=9 June 2007}}</ref>
| |
| |
| |
| {|
| |
| |-
| |
| | colspan="2" align="center" | (liquid film)
| |
| |-
| |
| ! Wave number !! transmittance
| |
| |-
| |
| | 880 cm<sup>−1</sup> || 22%
| |
| |-
| |
| | 1048 cm<sup>−1</sup> || 6%
| |
| |-
| |
| | 1089 cm<sup>−1</sup> || 19%
| |
| |-
| |
| | 1275 cm<sup>−1</sup> || 52%
| |
| |-
| |
| | 1329 cm<sup>−1</sup> || 44%
| |
| |-
| |
| | 1384 cm<sup>−1</sup> || 32%
| |
| |-
| |
| | 1418 cm<sup>−1</sup> || 33%
| |
| |-
| |
| | 1650 cm<sup>−1</sup> || 26%
| |
| |-
| |
| | 1926 cm<sup>−1</sup> || 62%
| |
| |-
| |
| | 2899 cm<sup>−1</sup> || 12%
| |
| |-
| |
| | 2930 cm<sup>−1</sup> || 13%
| |
| |-
| |
| | 2977 cm<sup>−1</sup> || 4%
| |
| |}
| |
| |-
| |
| ! {{chembox header}} | [[NMR Spectroscopy|NMR]]
| |
| |-
| |
| | [[Proton NMR]] <!-- Link to image of spectrum -->
| |
| |
| |
| |-
| |
| | [[Carbon-13 NMR]] <!-- Link to image of spectrum -->
| |
| | http://riodb01.ibase.aist.go.jp/sdbs/cgi-bin/IMG.cgi?fname=CDS00245&imgdir=cdsW;
| |
| |-
| |
| | Other NMR data <!-- Insert special data e.g. <sup>19</sup>F chem. shifts, omit if not used -->
| |
| |
| |
| |-
| |
| ! {{chembox header}} | [[Mass Spectrometry|MS]]
| |
| |-
| |
| | Masses of <br>main fragments
| |
| | <!-- Give list of major fragments -->
| |
| |-
| |
| |}
| |
| | |
| ==Vapor pressure of liquid ==
| |
| | |
| {|
| |
| |-
| |
| |
| |
| {| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
| |
| |- align=center
| |
| | {{chembox header}} | '''P in mm Hg''' || 1 || 10 || 40 || 100 || 400 || 760 || 1520 || 3800 || 7600 || 15200 || 30400 || 45600
| |
| |- align=center
| |
| | {{chembox header}} | '''P in Pa''' || 133.3 || 1333 || 5333 || 13332 || 53329 || 101325 || 202650 || 506625 || 1013250 || 2026500 || 4053000 || 6079501
| |
| |- align=center
| |
| | {{chembox header}} | '''T in °C''' || –31.3 || –2.3 || 19.0 || 34.9 || 63.5 || 78.4 || 97.5 || 126.0 || 151.8 || 183.0 || 218.0 || 242.0
| |
| |- align=center
| |
| | {{chembox header}} | '''T in K''' || 241.85 || 270.85 || 292.15 || 308.05 || 336.65 || 351.55 || 370.65 || 399.15 || 424.95 || 456.15 || 491.15 || 515.15
| |
| |}
| |
| |-
| |
| |
| |
| {|
| |
| |
| |
| [[Image:EtOHvaporpressureL.png|thumb|302px|left|Ethanol vapor pressure vs. temperature. Uses formula: <math>\scriptstyle P_{mmHg} = 10^{8.04494 - \frac {1554.3} {222.65+T}}</math> from ''Lange's Handbook of Chemistry'' 10th ed.]]
| |
| |
| |
| [[Image:EtOHlogVaporPressureL.png|thumb|500px|left|Log<sub>10</sub> of ethanol vapor pressure vs. temperature. Uses formula: <math>\scriptstyle \log_{10} {P_{mmHg}} = 8.04494 - \frac {1554.3} {222.65+T}</math>]]
| |
| |}
| |
| |}
| |
| {{Clear}}
| |
| | |
| ==Density of ethanol at various temperatures (''kg/l'' or ''g/cm<sup>3</sup>'')==
| |
| Data obtained from ''Lange's Handbook of Chemistry'', 10th ed.
| |
| | |
| {| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
| |
| |- {{chembox header}} bgcolor="#F8EABA"
| |
| | 3 °C || 0.80374 || 16 °C || 0.79283 || 29 °C || 0.78182
| |
| |-
| |
| | 4 °C || 0.80290 || 17 °C || 0.79198 || 30 °C || 0.78097
| |
| |-
| |
| | 5 °C || 0.80207 || 18 °C || 0.79114 || 31 °C || 0.78012
| |
| |-
| |
| | 6 °C || 0.80123 || 19 °C || 0.79029 || 32 °C || 0.77927
| |
| |-
| |
| | 7 °C || 0.80039 || 20 °C || 0.78945 || 33 °C || 0.77841
| |
| |-
| |
| | 8 °C || 0.79956 || 21 °C || 0.78860 || 34 °C || 0.77756
| |
| |-
| |
| | 9 °C || 0.79872 || 22 °C || 0.78775 || 35 °C || 0.77671
| |
| |-
| |
| | 10 °C || 0.79788 || 23 °C || 0.78691 || 36 °C || 0.77585
| |
| |-
| |
| | 11 °C || 0.79704 || 24 °C || 0.78606 || 37 °C || 0.77500
| |
| |-
| |
| | 12 °C || 0.79620 || 25 °C || 0.78522 || 38 °C || 0.77414
| |
| |-
| |
| | || || 39 °C || 0.77329 || 40 °C || 0.77244
| |
| |}
| |
| These data correlate as Density (g/cm<sup>3</sup>) = -8.461834E-4 T( °C) + 0.8063372 with an R<sup>2</sup> coefficient of determination of 0.99999.
| |
| | |
| ==Properties of aqueous ethanol solutions==
| |
| Data obtained from ''Lange's Handbook of Chemistry'', 10th ed. The annotation, '''d a °C/b °C''', indicates density of solution at temperature '''a''' divided by density of pure water at temperature '''b'''.
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| | |
| {| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
| |
| |- {{chembox header}}
| |
| | '''% wt<br>ethanol''' || '''% vol<br>ethanol''' || '''grams<br>ethanol<br>per 100 cc<br>15.56 °C''' || '''d 10 °C/4 °C''' || '''d 20 °C/4 °C''' || '''d 25 °C/4 °C''' || '''d 30 °C/4 °C''' || '''d 20 °C/20 °C''' || '''d 25 °C/25 °C''' || '''freezing<br>temp.'''
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| |-
| |
| | 0.0 || 0.0 || 0.0 || 0.99973 || 0.99823 || 0.99708 || 0.99568 || 1.00000 || 1.00000 || 0 °C
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| |-
| |
| | 1.0 || || || 0.99785 || 0.99636 || 0.99520 || 0.99379 || 0.99813 || 0.99811 ||
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| |-
| |
| | 2.0 || || || 0.99602 || 0.99453 || 0.99336 || 0.99194 || 0.99629 || 0.99627 ||
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| |-
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| | 2.5 || 3.13 || || || 0.99363 || || || || || –1 °C
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| |-
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| | 3.0 || || || 0.99426 || 0.99275 || 0.99157 || 0.99014 || 0.99451 || 0.99447 ||
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| |-
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| | 4.0 || 5.00 || 3.97 || 0.99258 || 0.99103 || 0.98984 || 0.98839 || 0.99279 || 0.99274 ||
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| | 4.8 || 6.00 || 4.76 || || 0.98971 || || || || || –2 °C
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| |-
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| | 5.0 || || || 0.99098 || 0.98938 || 0.98817 || 0.98670 || 0.99113 || 0.99106 ||
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| |-
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| | 5.05 || 6.30 || 5.00 || || 0.98930 || || || || ||
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| |-
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| | 6.0 || || || 0.98946 || 0.98780 || 0.98656 || 0.98507 || 0.98955 || 0.98945 ||
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| |-
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| | 6.8 || 8.47 || || || 0.98658 || || || || || –3 °C
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| |-
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| | 7.0 || || || 0.98801 || 0.98627 || 0.98500 || 0.98347 || 0.98802 || 0.98788 ||
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| |-
| |
| | 8.0 || || || 0.98660 || 0.98478 || 0.98346 || 0.98189 || 0.98653 || 0.98634 ||
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| |-
| |
| | 9.0 || || || 0.98524 || 0.98331 || 0.98193 || 0.98031 || 0.98505 || 0.98481 ||
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| |-
| |
| | 10.0 || 12.40 || 9.84 || 0.98393 || 0.98187 || 0.98043 || 0.97575 || 0.98361 || 0.98330 ||
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| |
| | 11.0 || || || 0.98267 || 0.98047 || 0.97897 || 0.97723 || 0.98221 || 0.98184 ||
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| | 11.3 || 14.0 || 11.11 || || 0.98006 || || || || || –5 °C
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| |-
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| | 12.0 || || || 0.98145 || 0.97910 || 0.97753 || 0.97573 || 0.98084 || 0.98039 ||
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| |-
| |
| | 13.0 || || || 0.98026 || 0.97775 || 0.97611 || 0.97424 || 0.97948 || 0.97897 ||
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| |-
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| | 13.78 || 17.00 || 13.49 || || || || || || || –6.1 °C
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| |-
| |
| | 14.0 || || || 0.97911 || 0.97643 || 0.97472 || 0.97278 || 0.97816 || 0.97757 ||
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| |-
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| | 15.0 || || || 0.97800 || 0.97514 || 0.97334 || 0.97133 || 0.97687 || 0.97619 ||
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| |-
| |
| | 15.02 || 18.50 || 14.68 || || 0.97511 || || || || ||
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| |-
| |
| | 16.0 || || || 0.97692 || 0.97387 || 0.97199 || 0.96990 || 0.97560 || 0.97484 ||
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| |-
| |
| | 16.4 || 20.2 || || || 0.97336 || || || || || –7.5 °C
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| |-
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| | 17.0 || || || 0.97583 || 0.97259 || 0.97062 || 0.96844 || 0.97431 || 0.97346 ||
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| |-
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| | 17.5 || 21.5 || || || 0.97194 || || || || || –8.7 °C
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| |-
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| | 18.0 || 22.10 || 17.54 || 0.97473 || 0.97129 || 0.96923 || 0.96697 || 0.97301 || 0.97207 ||
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| | 18.8 || 23.1 || || || 0.97024 || || || || || –9.4 °C
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| |-
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| | 19.0 || || || 0.97363 || 0.96997 || 0.96782 || 0.96547 || 0.97169 || 0.97065 ||
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| |-
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| | 20.0 || || || 0.97252 || 0.96864 || 0.96639 || 0.96395 || 0.97036 || 0.96922 ||
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| |-
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| | 20.01 || 24.50 || 19.44 || || 0.96863 || || || || ||
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| |-
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| | 20.3 || 24.8 || || || 0.96823 || || || || || –10.6 °C
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| |-
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| | 21.0 || || || 0.97139 || 0.96729 || 0.96495 || 0.96242 || 0.96901 || 0.96778 ||
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| |-
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| | 22.0 || || || 0.97024 || 0.96592 || 0.96348 || 0.96087 || 0.96763 || 0.96630 ||
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| | 22.11 || 27.00 || 21.43 || || 0.96578 || || || || || –12.2 °C
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| | 23.0 || || || 0.96907 || 0.96453 || 0.96199 || 0.95929 || 0.96624 || 0.96481 ||
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| | 24.0 || || || 0.96787 || 0.96312 || 0.96048 || 0.95769 || 0.96483 || 0.96329 ||
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| | 24.2 || 29.5 || || || 0.96283 || || || || || –14.0 °C
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| | 25.0 || 30.40 || 24.12 || 0.96665 || 0.96168 || 0.95895 || 0.95607 || 0.96339 || 0.96176 ||
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| | 26.0 || || || 0.96539 || 0.96020 || 0.95738 || 0.95422 || 0.96190 || 0.96018 ||
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| | 26.7 || 32.4 || || || 0.95914 || || || || || –16.0 °C
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| |-
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| | 27.0 || || || 0.96406 || 0.95867 || 0.95576 || 0.95272 || 0.96037 || 0.95856 ||
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| |-
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| | 28.0 || 33.90 || 26.90 || 0.96268 || 0.95710 || 0.95410 || 0.95098 || 0.95880 || 0.95689 ||
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| | 29.0 || || || 0.96125 || 0.95548 || 0.95241 || 0.94922 || 0.95717 || 0.95520 ||
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| |-
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| | 29.9 || 36.1 || || || 0.95400 || || || || || –18.9 °C
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| |-
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| | 30.0 || 36.20 || 28.73 || 0.95977 || 0.95382 || 0.95067 || 0.94741 || 0.95551 || 0.95345 ||
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| | 31.0 || || || 0.95823 || 0.95212 || 0.94890 || 0.94557 || 0.95381 || 0.95168 ||
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| |-
| |
| | 32.0 || || || 0.95665 || 0.95038 || 0.94709 || 0.94370 || 0.95207 || 0.94986 ||
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| |-
| |
| | 33.0 || || || 0.95502 || 0.94860 || 0.94525 || 0.94180 || 0.95028 || 0.94802 ||
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| |-
| |
| | 33.8 || 40.5 || || || 0.94715 || || || || || –23.6 °C
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| |-
| |
| | 34.0 || || || 0.95334 || 0.94679 || 0.94337 || 0.93986 || 0.94847 || 0.94613 ||
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| |-
| |
| | 35.0 || || || 0.95162 || 0.94494 || 0.94146 || 0.93790 || 0.94662 || 0.94422 ||
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| |-
| |
| | 35.04 || 41.90 || 33.25 || || 0.94486 || || || || ||
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| |-
| |
| | 36.0 || || || 0.94986 || 0.94306 || 0.93952 || 0.93591 || 0.94473 || 0.94227 ||
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| |-
| |
| | 37.0 || || || 0.94805 || 0.94114 || 0.93756 || 0.93390 || 0.94281 || 0.94031 ||
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| |-
| |
| | 38.0 || || || 0.94620 || 0.93919 || 0.93556 || 0.93186 || 0.94086 || 0.93830 ||
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| |-
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| | 39.0 || 46.3 || || 0.94431 || 0.93720 || 0.93353 || 0.92979 || 0.93886 || 0.93626 || –28.7 °C
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| |-
| |
| | 40.0 || || || 0.94238 || 0.93518 || 0.93148 || 0.92770 || 0.93684 || 0.93421 ||
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| |-
| |
| | 40.04 || 47.40 || 37.61 || || 0.93510 || || || || ||
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| |-
| |
| | 41.0 || || || 0.94042 || 0.93314 || 0.92940 || 0.92558 || 0.93479 || 0.93212 ||
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| |-
| |
| | 42.0 || || || 0.93842 || 0.93107 || 0.92729 || 0.92344 || 0.93272 || 0.93001 ||
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| |-
| |
| | 43.0 || || || 0.93639 || 0.92897 || 0.92516 || 0.92128 || 0.93062 || 0.92787 ||
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| |-
| |
| | 44.0 || || || 0.93433 || 0.92685 || 0.92301 || 0.91910 || 0.92849 || 0.92571 ||
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| |-
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| | 45.0 || || || 0.93226 || 0.92472 || 0.92085 || 0.91692 || 0.92636 || 0.92355 ||
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| |-
| |
| | 45.31 || 53.00 || 42.07 || || 0.92406 || || || || ||
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| |-
| |
| | 46.0 || || || 0.93017 || 0.92257 || 0.91868 || 0.91472 || 0.92421 || 0.92137 ||
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| |-
| |
| | 46.3 || 53.8 || || || 0.92193 || || || || || –33.9 °C
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| |-
| |
| | 47.0 || || || 0.92806 || 0.92041 || 0.91649 || 0.91250 || 0.92204 || 0.91917 ||
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| |-
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| | 48.0 || || || 0.92593 || 0.91823 || 0.91429 || 0.91028 || 0.91986 || 0.91697 ||
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| |-
| |
| | 49.0 || || || 0.92379 || 0.91604 || 0.91208 || 0.90805 || 0.91766 || 0.91475 ||
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| |-
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| | 50.0 || || || 0.92162 || 0.91384 || 0.90985 || 0.90580 || 0.91546 || 0.91251 ||
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| |-
| |
| | 50.16 || 58.0 || 46.04 || || 0.91349 || || || || ||
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| |-
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| | 51.0 || || || 0.91943 || 0.91160 || 0.90760 || 0.90353 || 0.91322 || 0.91026 ||
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| |-
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| | 52.0 || || || 0.91723 || 0.90936 || 0.90524 || 0.90125 || 0.91097 || 0.90799 ||
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| |-
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| | 53.0 || || || 0.91502 || 0.90711 || 0.90307 || 0.89896 || 0.90872 || 0.90571 ||
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| | 54.0 || || || 0.91279 || 0.90485 || 0.90079 || 0.89667 || 0.90645 || 0.90343 ||
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| |-
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| | 55.0 || || || 0.91055 || 0.90258 || 0.89850 || 0.89437 || 0.90418 || 0.90113 ||
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| |-
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| | 55.16 || 63.0 || 50.00 || || 0.90220 || || || || ||
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| |-
| |
| | 56.0 || || || 0.90831 || 0.90031 || 0.89621 || 0.89206 || 0.90191 || 0.89833 ||
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| |-
| |
| | 56.1 || 63.6 || || || 0.90008 || || || || || –41.0 °C
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| |-
| |
| | 57.0 || || || 0.90607 || 0.89803 || 0.89392 || 0.88975 || 0.89962 || 0.89654 ||
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| |-
| |
| | 58.0 || || || 0.90381 || 0.89574 || 0.89162 || 0.88744 || 0.89733 || 0.89423 ||
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| |-
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| | 59.0 || || || 0.90154 || 0.89344 || 0.88931 || 0.88512 || 0.89502 || 0.89191 ||
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| |-
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| | 60.0 || || || 0.89927 || 0.89113 || 0.88699 || 0.88278 || 0.89271 || 0.88959 ||
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| |-
| |
| | 60.33 || 68.0 || 53.98 || || 0.89038 || || || || ||
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| |-
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| | 61.0 || || || 0.89898 || 0.88882 || 0.88466 || 0.88044 || 0.89040 || 0.88725 ||
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| |-
| |
| | 62.0 || || || 0.89468 || 0.88650 || 0.88233 || 0.87809 || 0.88807 || 0.88491 ||
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| | 63.0 || || || 0.89237 || 0.88417 || 0.87998 || 0.87574 || 0.88574 || 0.88256 ||
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| |-
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| | 64.0 || || || 0.89006 || 0.88183 || 0.87763 || 0.87337 || 0.88339 || 0.88020 ||
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| |-
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| | 65.0 || || || 0.88774 || 0.87948 || 0.87527 || 0.87100 || 0.88104 || 0.87783 ||
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| |-
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| | 66.0 || || || 0.88541 || 0.87713 || 0.87291 || 0.86863 || 0.87869 || 0.87547 ||
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| |-
| |
| | 67.0 || || || 0.88308 || 0.87477 || 0.87054 || 0.86625 || 0.87632 || 0.87309 ||
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| |-
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| | 68.0 || || || 0.88071 || 0.87241 || 0.86817 || 0.86387 || 0.87396 || 0.87071 ||
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| |-
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| | 69.0 || || || 0.87839 || 0.87004 || 0.86579 || 0.86148 || 0.87158 || 0.86833 ||
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| |-
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| | 70.0 || || || 0.87602 || 0.86766 || 0.86340 || 0.85908 || 0.86920 || 0.86593 ||
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| |-
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| | 71.0 || || || 0.87365 || 0.86527 || 0.86100 || 0.85667 || 0.86680 || 0.86352 ||
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| |-
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| | 71.9 || 78.3 || || || 0.86311 || || || || || –51.3 °C
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| |-
| |
| | 72.0 || || || 0.87127 || 0.86287 || 0.85859 || 0.85426 || 0.86440 || 0.86110 ||
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| |-
| |
| | 73.0 || || || 0.86888 || 0.86047 || 0.85618 || 0.85184 || 0.86200 || 0.85869 ||
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| |-
| |
| | 74.0 || || || 0.86648 || 0.85806 || 0.85376 || 0.84941 || 0.85958 || 0.85626 ||
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| |-
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| | 75.0 || || || 0.86408 || 0.85564 || 0.85135 || 0.84698 || 0.85716 || 0.85383 ||
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| |-
| |
| | 76.0 || || || 0.86168 || 0.85322 || 0.84891 || 0.84455 || 0.85473 || 0.85140 ||
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| | 77.0 || || || 0.85927 || 0.85079 || 0.84647 || 0.84211 || 0.85230 || 0.84895 ||
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| |-
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| | 78.0 || || || 0.85685 || 0.84835 || 0.84403 || 0.83966 || 0.84985 || 0.84650 ||
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| |-
| |
| | 79.0 || || || 0.85422 || 0.84590 || 0.84158 || 0.83720 || 0.84740 || 0.84404 ||
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| |-
| |
| | 80.0 || || || 0.85197 || 0.84344 || 0.83911 || 0.83473 || 0.84494 || 0.84157 ||
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| |-
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| | 81.0 || || || 0.84950 || 0.84096 || 0.83664 || 0.83224 || 0.84245 || 0.83909 ||
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| |-
| |
| | 82.0 || || || 0.84702 || 0.83848 || 0.83415 || 0.82974 || 0.83997 || 0.83659 ||
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| |-
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| | 83.0 || || || 0.84453 || 0.83599 || 0.83164 || 0.82724 || 0.83747 || 0.83408 ||
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| |-
| |
| | 84.0 || || || 0.84203 || 0.83348 || 0.82913 || 0.82473 || 0.83496 || 0.83156 ||
| |
| |-
| |
| | 85.0 || || || 0.83951 || 0.83095 || 0.82660 || 0.82220 || 0.83242 || 0.82902 ||
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| |-
| |
| | 86.0 || || || 0.83697 || 0.82840 || 0.82405 || 0.81965 || 0.82987 || 0.82646 ||
| |
| |-
| |
| | 87.0 || || || 0.83441 || 0.82554 || 0.82148 || 0.81708 || 0.82729 || 0.82389 ||
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| |-
| |
| | 88.0 || || || 0.83181 || 0.82323 || 0.81888 || 0.81448 || 0.82469 || 0.82128 ||
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| |-
| |
| | 89.0 || || || 0.82919 || 0.82062 || 0.81626 || 0.81186 || 0.82207 || 0.81865 ||
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| |-
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| | 90.0 || || || 0.82654 || 0.81797 || 0.81362 || 0.80922 || 0.81942 || 0.81600 ||
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| |-
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| | 91.00 || 94.00 || 74.62 || 0.82386 || 0.81529 || 0.81094 || 0.80655 || 0.81674 || 0.81331 ||
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| |-
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| | 92.0 || || || 0.82114 || 0.81257 || 0.80823 || 0.80384 || 0.81401 || 0.81060 ||
| |
| |-
| |
| | 93.0 || || || 0.81839 || 0.80983 || 0.80549 || 0.80111 || 0.81127 || 0.80785 ||
| |
| |-
| |
| | 94.0 || || || 0.81561 || 0.80705 || 0.80272 || 0.79835 || 0.80848 || 0.80507 ||
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| |-
| |
| | 95.0 || || || 0.81278 || 0.80424 || 0.79991 || 0.79555 || 0.80567 || 0.80225 ||
| |
| |-
| |
| | 96.0 || || || 0.80991 || 0.80138 || 0.79706 || 0.79271 || 0.80280 || 0.79939 ||
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| |-
| |
| | 97.0 || || || 0.80698 || 0.79846 || 0.79415 || 0.78981 || 0.79988 || 0.79648 ||
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| |-
| |
| | 98.0 || || || 0.80399 || 0.79547 || 0.79117 || 0.78684 || 0.79688 || 0.79349 ||
| |
| |-
| |
| | 99.0 || || || 0.80094 || 0.79243 || 0.78814 || 0.78382 || 0.79383 || 0.79045 ||
| |
| |-
| |
| | 100.0 || 100.0 || 79.39 || 0.79784 || 0.78934 || 0.78506 || 0.78075 || 0.79074 || 0.78736 || −114.3 °C
| |
| |- {{chembox header}}
| |
| | '''% wt<br>ethanol''' || '''% vol<br>ethanol''' || '''grams<br>ethanol<br>per 100 cc<br>15.56 °C''' || '''d 10 °C/4 °C''' || '''d 20 °C/4 °C''' || '''d 25 °C/4 °C''' || '''d 30 °C/4 °C''' || '''d 20 °C/20 °C''' || '''d 25 °C/25 °C''' || '''freezing<br>temp.'''
| |
| |}
| |
| | |
| ==Boiling points of aqueous solutions==<!-- This section is linked from [[Azeotrope]] -->
| |
| Data obtained from ''CRC Handbook of Chemistry'' 44th ed., p2391
| |
| | |
| {| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
| |
| |- {{chembox header}}
| |
| | rowspan="2" | '''BP °C'''
| |
| | colspan="2" | '''Weight % ethanol'''
| |
| | rowspan="2" |
| |
| | rowspan="2" | '''BP °C'''
| |
| | colspan="2" | '''Weight % ethanol'''
| |
| |- {{chembox header}}
| |
| | '''liquid''' || '''vapor''' || '''liquid''' || '''vapor'''
| |
| |-
| |
| | 78.1 || 95.5<sup>‡</sup> || 95.5<sup>‡</sup>
| |
| | rowspan="29" |
| |
| | || ||
| |
| |-
| |
| | 78.2 || 91 || 92 || 86.5 || 18 || 71
| |
| |-
| |
| | 78.4 || 85 || 89 || 87.0 || 17 || 70
| |
| |-
| |
| | 78.6 || 82 || 88 || 87.5 || 16 || 69
| |
| |-
| |
| | 78.8 || 80 || 87 || 88.0 || 15 || 68
| |
| |-
| |
| | 79.0 || 78 || 86 || 88.5 || 13 || 67
| |
| |-
| |
| | 79.2 || 76 || 85 || 89.0 || 12 || 65
| |
| |-
| |
| | 79.4 || 74 || 85 || 89.5 || 11 || 63
| |
| |-
| |
| | 79.6 || 72 || 84 || 90.0 || 10 || 61
| |
| |-
| |
| | 79.8 || 69 || 84 || 90.5 || 10 || 59
| |
| |-
| |
| | 80.0 || 67 || 83 || 91.0 || 9 || 57
| |
| |-
| |
| | 80.2 || 64 || 83 || 91.5 || 8 || 55
| |
| |-
| |
| | 80.4 || 62 || 82 || 92.0 || 8 || 53
| |
| |-
| |
| | 80.6 || 59 || 82 || 92.5 || 7 || 51
| |
| |-
| |
| | 80.8 || 56 || 81 || 93.0 || 6 || 49
| |
| |-
| |
| | 81.0 || 53 || 81 || 93.5 || 6 || 46
| |
| |-
| |
| | 81.2 || 50 || 80 || 94.0 || 5 || 44
| |
| |-
| |
| | 81.4 || 47 || 80 || 94.5 || 5 || 42
| |
| |-
| |
| | 81.6 || 45 || 80 || 95.0 || 4 || 39
| |
| |-
| |
| | 81.8 || 43 || 79 || 95.5 || 4 || 36
| |
| |-
| |
| | 82.0 || 41 || 79 || 96.0 || 3 || 33
| |
| |-
| |
| | 82.5 || 36 || 78 || 96.5 || 3 || 30
| |
| |-
| |
| | 83.0 || 33 || 78 || 97.0 || 2 || 27
| |
| |-
| |
| | 83.5 || 30 || 77 || 97.5 || 2 || 23
| |
| |-
| |
| | 84.0 || 27 || 77 || 98.0 || 1 || 19
| |
| |-
| |
| | 84.5 || 25 || 75 || 98.5 || 1 || 15
| |
| |-
| |
| | 85.0 || 23 || 74 || 99.0 || < 1 || 10
| |
| |-
| |
| | 85.5 || 21 || 73 || 99.5 || < 1 || 5
| |
| |-
| |
| | 86.0 || 20 || 72 || 100.0 || 0 || 0
| |
| |}
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| <sup>‡</sup>[[azeotrope|Azeotropic mixture]]
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| ==References==
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| <references/>
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| *{{nist}}
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| {{DEFAULTSORT:Ethanol (Data Page)}}
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| [[Category:Chemical data pages]]
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