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In physics, '''Berry connection''' and '''Berry curvature''' are related concepts, which can be viewed, respectively, as a local gauge potential and gauge field associated with the [[Berry phase]]. These concepts were introduced by [[Michael Berry (physicist)|Michael Berry]] in a paper published in 1984<ref>
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{{cite journal
|author = Berry, M. V.
|title = Quantal Phase Factors Accompanying Adiabatic Changes
|volume = 392
|number = 1802
|pages = 45–57
|year = 1984
|doi = 10.1098/rspa.1984.0023
|url = http://rspa.royalsocietypublishing.org/content/392/1802/45.abstract
|eprint = http://rspa.royalsocietypublishing.org/content/392/1802/45.full.pdf+html
|journal = [[Proceedings of the Royal Society A]]
|bibcode = 1984RSPSA.392...45B }}</ref>
emphasizing how [[geometric phase]]s provide a powerful unifying concept in several branches of [[Classical physics|classical]] and [[quantum physics]]. Such phases have come to be known as [[geometric phase|Berry phases]].
 
==Berry phase and cyclic adiabatic evolution==
 
In quantum mechanics, the Berry phase arises in a cyclic [[Adiabatic theorem|adiabatic]] evolution. The quantum [[adiabatic theorem]] applies to a system whose [[Hamiltonian (quantum mechanics)|Hamiltonian]] <math>H(\mathbf R)</math> depends on a (vector) parameter <math>\mathbf R</math> that varies with time <math>t</math>.  If the <math>n</math>'th [[eigenvalue]] <math>\varepsilon_n(\mathbf R)</math> remains non-degenerate everywhere along the path and the variation with time ''t'' is sufficiently slow, then a system initially in the [[eigenstate]]
<math>\, |n(\mathbf R(0))\rangle </math> will remain in an instantaneous eigenstate <math>\, |n(\mathbf R(t))\rangle </math> of the Hamiltonian <math>\, H(\mathbf R(t))</math>, up to a phase, throughout the process. Regarding the phase, the state at time ''t'' can be written as<ref name=Sakurai>
{{cite book
|author= Sakurai, J.J.
|title= Modern Quantum Mechanics
|year=2005
|publisher=Addison–Wesley
|volume= Revised Edition
|url= http://books.google.com/books?id=w2a8QgAACAAJ}}
</ref>
:<math>
|\Psi_n(t)\rangle =e^{i\gamma_n(t)}\,
e^{-{i\over\hbar}\int_0 ^t dt'\varepsilon_n(\mathbf R(t'))}\,
| n(\mathbf R(t))\rangle,
</math>
where the second exponential term is the "dynamic phase factor." The first exponential term is the geometric term, with <math>\gamma_n</math> being the Berry phase.  By plugging into the [[Schr%C3%B6dinger_equation#Time_dependent_equation|time-dependent Schrödinger equation]], it can be shown that
:<math>
\gamma_n(t)=i\int_0^t dt'\,\langle n(\mathbf R(t'))|{d\over dt'}|n(\mathbf R(t'))\rangle=i\int_{\mathbf R(0)}^{\mathbf R(t)} d\mathbf R\,\langle n(\mathbf R)|\nabla_{\mathbf R}|n(\mathbf R)\rangle,
</math>
indicating that the Berry phase only depends on the path in the parameter space, not on the rate at which the path is traversed.
 
In the case of a cyclic evolution around a closed path <math>\mathcal C</math> such that <math>\mathbf R(T)=\mathbf R(0)</math>, the closed-path Berry phase is
:<math>
\gamma_n=i\oint_{\mathcal C} d\mathbf R\,\langle n(\mathbf R)|\nabla_{\mathbf R}|n(\mathbf R)\rangle.
</math>
An example of physical system where an electron moves along a closed path is cyclotron motion (details are given in the page of [[Geometric_phase|Berry phase]]). Berry phase must be considered to obtain the correct quantization condition.
 
 
==Gauge transformation==
 
Without changing the physics, we can make a [[Gauge theory#Mathematical formalism|gauge transformation]]
:<math>
|\tilde n(\mathbf R)\rangle=e^{-i\beta(\mathbf R)}|n(\mathbf R)\rangle
</math>
to a new set of states that differ from the original ones only by an <math>\mathbf R</math>-dependent phase factor.  This modifies the open-path Berry phase to be <math>\tilde\gamma_n(t)=\gamma_n(t)+\beta(t)-\beta(0)</math>.  For a closed path, continuity requires that <math>\beta(T)-\beta(0)=2\pi m</math> (<math>m</math> an integer), and it follows that <math>\gamma_n</math> is invariant, modulo <math>2\pi</math>, under an arbitrary gauge transformation.
 
==Berry connection==
The closed-path Berry phase defined above can be expressed as
:<math>
\gamma_n=\int_\mathcal{C} d\mathbf R\cdot \mathcal{A}_n(\mathbf R)
</math>
where
:<math>
\mathcal{A}_n(\mathbf R)=i\langle n(\mathbf R)|\nabla_{\mathbf R}|n(\mathbf R)\rangle.
</math>
is a vector-valued function known as the Berry connection (or Berry potential). The Berry connection is gauge-dependent, transforming as
<math>\tilde{\mathcal{A}}_n(\mathbf R)=\mathcal{A}_n (\mathbf R)+\nabla_{\mathbf R\,}\beta(\mathbf R)</math>. Hence the local Berry connection <math>\mathcal{A}_n(\mathbf R)</math> can never be physically observable. However, its integral along a closed path, the Berry phase <math>\gamma_n</math>, is gauge-invariant up to an integer multiple of <math>2\pi</math>. Thus, <math>e^{i\gamma_n}</math> is absolutely gauge-invariant, and may be related to physical observables.
 
==Berry curvature==
 
The Berry curvature is an [[anti-symmetric]] second-rank tensor derived from the Berry connection via
:<math>
\Omega_{n,\mu\nu} (\mathbf R)={\partial\over\partial R^\mu}\mathcal{A}_{n,\nu}(\mathbf R)-{\partial\over\partial R^\nu}\mathcal{A}_{n,\mu}(\mathbf R).
</math>
In a three-dimensional parameter space the Berry curvature can be written in the [[pseudovector]] form
:<math>
\mathbf\Omega_n(\mathbf R)=\nabla_{\mathbf R} \times\mathcal{A}_n(\mathbf R).
</math>
The tensor and pseduovector forms of the Berry curvature are related to each other through the [[Levi-Civita symbol|Levi-Civita]] antisymmetric tensor as
<math>\Omega_{n,\mu\nu}=\epsilon_{\mu\nu\xi}\,\mathbf\Omega_{n,\xi}</math>.  In contrast to the Berry connection, which is physical only after integrating around a closed path, the Berry curvature is a gauge-invariant local manifestation of the geometric properties of the wavefunctions in the parameter space, and has proven to be an essential physical ingredient for understanding a variety of electronic properties.<ref name=resta2000>
{{cite journal
  |title = Manifestations of Berry's phase in molecules and in condensed matter
  |author = Resta, Raffaele
  |journal = J. Phys.: Condens. Matter
  |volume = 12
  |pages = R107
  |year = 2000
  |doi = 10.1088/0953-8984/12/9/201
|bibcode = 2000JPCM...12R.107R }}
</ref><ref name=BerryMod>
{{cite journal
  |title = Berry phase effects on electronic properties
  |author = Xiao, Di
  |author2 = Chang, Ming-Che
  |author3 = Niu, Qian
  |journal = Rev. Mod. Phys.
  |volume = 82
  |number = 3
  |pages = 1959–2007
  |numpages = 48
  |date=Jul 2010
  |doi = 10.1103/RevModPhys.82.1959
  |publisher = American Physical Society
|bibcode=2010RvMP...82.1959X
|arxiv = 0907.2021 }}
</ref>
 
For a closed path <math>\mathcal C</math> that forms the boundary of a surface <math>\mathcal{S}</math>, the closed-path Berry phase can be rewritten using [[Stokes' theorem]] as
:<math>
\gamma_n=\int_\mathcal{S} d\mathbf S\cdot\mathbf\Omega_n (\mathbf R).
</math>
If the surface is a closed manifold, the boundary term vanishes, but the indeterminacy of the boundary term modulo <math>2\pi</math> manifests itself in the [[Chern–Gauss–Bonnet theorem|Chern theorem]], which states that the integral of the Berry curvature over a closed manifold is quantized in units of <math>2\pi</math>. This number is the so-called [[Chern number]], and is essential for understanding various quantization effects.
 
Finally, note that the Berry curvature can also be written, using [[perturbation theory]], as a sum over all other eigenstates in the form
:<math>
\Omega_{n,\mu\nu}(\mathbf R)=i\sum_{n'\neq n}{\langle n|(\partial H/\partial R_\mu) |n'\rangle\langle n'|(\partial H/\partial R_\nu) | n\rangle-(\nu\leftrightarrow\mu)\over(\varepsilon_n-\varepsilon_{n'})^2}.
</math>
 
==Example: Spinor in a magnetic field==
 
The Hamiltonian of a spin-1/2 particle in a [[magnetic field]] can be written as<ref name=Sakurai/>
:<math>
H=\mu\mathbf\sigma\cdot\mathbf B,
</math>
where <math>\mathbf\sigma</math> denote the [[Pauli matrices]], <math>\mu</math> is the [[magnetic moment]], and '''B''' is the magnetic field. In three dimensions, the eigenstates have energies <math>\pm\mu B</math> and their eigenvectors are
:<math>
|u_-\rangle=
\begin{pmatrix}
\sin{\theta\over 2}e^{-i\phi}\\
-\cos{\theta\over 2}
\end{pmatrix},
|u_+\rangle=
\begin{pmatrix}
\cos{\theta\over 2}e^{-i\phi}\\
\sin{\theta\over 2}
\end{pmatrix}.
</math>
Now consider the <math>|u_-\rangle</math> state. Its Berry connection can be computed as
<math>\mathcal{A}_\theta=\langle u|i\partial_\theta u\rangle=0,
</math>
<math>
\mathcal{A}_\phi=\langle u|i\partial_\phi u\rangle=\sin^2{\theta\over 2}
</math>,
and the Berry curvature is
<math>
\Omega_{\theta\phi}=\partial_\theta\mathcal{A}_\phi-\partial_\phi\mathcal A_\theta={1\over 2}\sin\theta.
</math>
If we choose a new gauge by multiplying <math>|u_-\rangle</math> by <math>e^{i\phi}</math>, the Berry connections are
<math>\mathcal{A}_\theta=0</math> and <math>\mathcal{A}_\phi=-\cos^2{\theta\over 2}</math>, while the Berry curvature remains the same. This is consistent with the conclusion that the Berry connection is gauge-dependent while the Berry curvature is not.
 
The Berry curvature per solid angle is given by <math>\overline{\Omega}_{\theta\phi}=\Omega_{\theta\phi}/\sin\theta=1/2</math>. In this case, the Berry phase corresponding to any given path on the unit sphere <math>\mathcal S^2</math> in magnetic-field space is just half the solid angle subtended by the path.
The integral of the Berry curvature over the whole sphere is therefore exactly <math>2\pi</math>, so that the Chern number is unity, consistent with the Chern theorem.
 
==Applications in crystals==
 
The Berry phase plays an important role in modern investigations of electronic properties in crystalline solids<ref name=BerryMod/> and in the theory of the [[quantum_Hall_effect#Mathematics|quantum Hall effect]].<ref>
{{cite journal
|title = Quantized Hall Conductance in a Two-Dimensional Periodic Potential
|author = Thouless, D. J.
|author2 = Kohmoto, M.
|author2 = Nightingale, M. P.
|author2 = den Nijs, M.
|journal = Phys. Rev. Lett.
|volume = 49
|number = 6
|pages = 405–408
|numpages = 3
|date=Aug 1982
|doi = 10.1103/PhysRevLett.49.405
|publisher = American Physical Society
|bibcode=1982PhRvL..49..405T
}}
</ref>
The periodicity of the crystalline potential allows the application of the [[Bloch theorem]], which states that the Hamiltonian eigenstates take the form
:<math>
\psi_{n\mathbf k}(\mathbf r)=e^{i\mathbf k\cdot\mathbf r}u_{n\mathbf k}(\mathbf r),
</math>
where <math>n</math> is a band index, <math>\mathbf k</math> is a wavevector in the [[reciprocal space|reciprocal-space]] ([[Brillouin zone]]), and <math>u_{n\mathbf k}(\mathbf r)</math> is a periodic function of <math>\mathbf r</math>. Then, letting <math>\mathbf k</math> play the role of the parameter <math>\mathbf R</math>, one can define Berry phases, connections, and curvatures in the reciprocal space. For example, the Berry connection in reciprocal space is
:<math>
\mathcal{A}_n(\mathbf k)=i\langle n(\mathbf k)|\nabla_{\mathbf k}|n(\mathbf k)\rangle.
</math>
Because the Bloch theorem also implies that the reciprocal space itself is closed, with the Brillouin zone having the topology of a 3-torus in three dimensions, the requirements of integrating over a closed loop or manifold can easily be satisfied. In this way, such properties as the [[electric polarization]], orbital [[magnetization]], [[Hall_effect#Anomalous_Hall_effect|anomalous Hall conductivity]], and orbital magnetoelectric coupling can be expressed in terms of Berry phases, connections, and curvatures.<ref name=BerryMod/><ref>
{{cite journal
  |author=Chang, Ming-Che
  |author2=Niu, Qian
  |title=Berry curvature, orbital moment, and effective quantum theory of electrons in electromagnetic fields
  |journal=Journal of Physics: Condensed Matter
  |volume=20
  |number=19
  |pages=193202
  |url=http://stacks.iop.org/0953-8984/20/i=19/a=193202
  |year=2008}}
</ref><ref name=resta2010>
{{cite journal
  |title = Electrical polarization and orbital magnetization: the modern theories
  |author = Resta, Raffaele
  |journal = J. Phys.: Condens. Matter
  |volume = 22
  |pages = 123201
  |year = 2010
  |doi = 10.1088/0953-8984/22/12/123201
|bibcode = 2010JPCM...22l3201R }}
</ref>
 
==References==
 
{{reflist}}
 
==External links==
*"[http://books.google.com/books?hl=en&lr=&id=5jOvlny96AkC&oi=fnd&pg=PR5&dq=+geometric+phases+shapere&ots=IoFIBvrl3O&sig=TKqsDeqR44j3q8fq0vieNlx1Foo#v=onepage&q&f=false The quantum phase, five years after.]" by M. Berry.
*"[http://www.physics.rutgers.edu/~dhv/talks/rahman.pdf Berry Phases and Curvatures in Electronic Structure Theory.]" A talk by D. Vanderbilt.
*"[http://www.physics.rutgers.edu/~dhv/talks/psik-vanderbilt-2010.pdf Berry-ology, Orbital Magnetolectric Effects, and Topological Insulators]" A talk by D. Vanderbilt.
 
[[Category:Quantum mechanics]]
[[Category:Classical mechanics]]
[[Category:Quantum phases]]

Latest revision as of 23:24, 14 November 2014

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