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In [[quantum mechanics]], '''Kossakowski–Lindblad equation''' (after Andrzej Kossakowski and Göran Lindblad) or '''master equation in ''Lindblad form''''' is the most general type of [[Markov process|Markovian]] and [[time-homogeneous]] [[master equation]] describing non-unitary evolution of the [[density matrix]] <math>\rho</math> that is [[completely positive trace-preserving|trace-preserving and completely positive]] for any initial condition.


Lindblad master equation for an <math>N</math>-dimensional system's reduced density matrix <math>\ \rho</math> can be written:
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:<math>\dot\rho=-{i\over\hbar}[H,\rho]+\sum_{n,m = 1}^{N^2-1} h_{n,m}\big(L_n\rho L_m^\dagger-\frac{1}{2}\left(\rho L_m^\dagger L_n + L_m^\dagger L_n\rho\right)\big)</math>
 
where <math>\ H</math> is a ([[Hermitian]]) [[Hamiltonian (quantum mechanics)|Hamiltonian]] part, the <math>\ L_m</math> are an arbitrary [[orthonormal basis]] of the operators on the system's Hilbert space, and the <math>\ h_{n,m}</math> are constants which determine the dynamics. The coefficient matrix <math>\ h = (h_{n,m})</math> must be [[Positive-definite matrix|positive]] to ensure that the equation is trace-preserving and completely positive. The summation only runs to <math>\ N^2-1</math> because we have taken <math>\ L_{N^2}</math> to be proportional to the identity operator, in which case the [[Addition#Notation and terminology|summand]] vanishes.  Our convention implies that the <math>\ L_m</math> are traceless for <math>\ m<N^2</math>. The terms in the summation where <math>m=n</math> can be described in terms of the [[Lindblad superoperator]], <math> L(C)\rho=C\rho C^\dagger -\frac{1}{2}\left(C^\dagger C \rho +\rho C^\dagger C\right) </math>.
 
If the <math>\ L_m</math> terms are all zero, then this is [[Liouville's theorem (Hamiltonian)#Quantum_Liouville_equation|quantum Liouville equation]] (for a closed system), which is the quantum analog of the classical [[Liouville equation]]. A related equation describes the time evolution of the expectation values of observables, it is given by the [[Ehrenfest theorem]].
 
Note that <math>\ H</math> is ''not'' necessarily equal to the self-Hamiltonian of the system.  It may also incorporate effective unitary dynamics arising from the system-environment interaction.
 
==Diagonalization==
Since the matrix <math>\ h = (h_{n,m})</math> is positive, it can be [[Diagonalizable matrix|diagonalized]] with a [[Unitary transformation|unitary]] transformation u:
 
:<math>u^\dagger h u =
\begin{bmatrix}
\gamma_1 & 0        & \cdots & 0 \\
0        & \gamma_2 & \cdots & 0 \\
\vdots  & \vdots  & \ddots & \vdots \\
0        & 0        & \cdots & \gamma_{N^2-1}
\end{bmatrix}
</math>
 
where the eigenvalues <math>\ \gamma_i</math> are non-negative. If we define another orthonormal operator basis
 
:<math> A_i = \sum_{j = 1}^{N^2-1} u_{j,i} L_j </math>
 
we can rewrite Lindblad equation in ''diagonal'' form
 
:<math>\dot\rho=-{i\over\hbar}[H,\rho]+\sum_{i = 1}^{N^2-1} \gamma_{i}\big(A_i\rho A_i^\dagger -\frac{1}{2} \rho A_i^\dagger A_i -\frac{1}{2} A_i^\dagger A_i \rho \big) .</math>
 
This equation is invariant under a unitary transformation of Lindblad operators and constants,
 
:<math> \sqrt{\gamma_i} A_i \to \sqrt{\gamma_i'} A_i' = \sum_{j = 1}^{N^2-1} v_{j,i} \sqrt{\delta_i} A_j ,</math>
 
and also under the inhomogenous transformation
 
:<math> A_i \to A_i' =  A_i + a_i ,</math>
:<math> H \to H' =  H + \frac{1}{2i} \sum_{j=1}^{N^2-1} \gamma_j (a_j^* A_j - a_j A_J^\dagger) .</math>
 
However, the first transformation destroys the orthonormality of the operators <math>\ A_i</math> (unless all the <math>\ \gamma_i</math> are equal) and the second transformation destroys the tracelessness. Therefore, up to degeneracies among the <math>\ \gamma_i</math>, the <math>\ A_i</math> of the diagonal form of the Lindblad equation are uniquely determined by the dynamics so long as we require them to be orthonormal and traceless.
 
==Harmonic oscillator example==
The most common Lindblad equation is that describing the damping of a  [[quantum harmonic oscillator]], it has <math>\ L_0=a</math>, <math>\ L_1=a^{\dagger}</math>, <math>\ h_{0,1}=-(\gamma/2)(\bar n+1)</math>, <math>\ h_{1,0}=-(\gamma/2)\bar n</math> with all others <math>\ h_{n,m}=0</math>. Here <math>\bar n</math> is the mean number of excitations in the reservoir damping the oscillator and <math>\ \gamma</math> is the decay rate. Additional Lindblad operators can be included to model various forms of dephasing and vibrational relaxation. These methods have been incorporated into grid-based [[density matrix]] propagation methods.
 
==See also==
* [[Open quantum system]]
* [[Quantum jump method]]
 
==References==
* {{cite journal | last=Kossakowski | first=A. | title=On quantum statistical mechanics of non-Hamiltonian systems | journal=Rep. Math. Phys. | volume=3 | pages=247 | year=1972 | bibcode=1972RpMP....3..247K | doi=10.1016/0034-4877(72)90010-9 | issue=4}}
* {{cite journal | last=Lindblad | first=G. | title=On the generators of quantum dynamical semigroups | journal=Commun. Math. Phys. | volume=48 | pages=119 | year=1976 | doi=10.1007/BF01608499 | issue=2}}
* {{cite journal | last1=Gorini | first1=V. | last2=Kossakowski | first2=A. | last3=Sudarshan | first3=E.C.G. | title=Completely positive semigroups of N-level systems | journal=J. Math. Phys. | volume=17 | pages=821 | year=1976 | doi=10.1063/1.522979 | issue=5}}
* {{cite journal | last1=Banks | first1=T. | last2=Susskind | first2=L. | last3=Peskin | first3=M.E. | title=Difficulties for the evolution of pure states into mixed states | journal=Nuclear Physics B | volume=244 | pages=125–134 | year=1984 | bibcode=1984NuPhB.244..125B | doi=10.1016/0550-3213(84)90184-6}}
* {{cite book | last1=Accardi | first1=Luigi | last2=Lu | first2=Yun Gang | last3=Volovich | first3=I.V. | title=Quantum Theory and Its Stochastic Limit | publisher=Springer Verlag | location=New York | year=2002 | isbn=978-3-5404-1928-0}}
* {{cite book | last1=Alicki | first1=Robert | last2=Lendi | first2=Karl | title=Quantum Dynamical Semigroups and Applications | publisher=Springer Verlag | location=Berlin | year=1987 | isbn=978-0-3871-8276-6}}
* {{cite book | last1=Attal | first1=Stéphane | last2=Joye | first2=Alain | last3=Pillet | first3=Claude-Alain | title=Open Quantum Systems II: The Markovian Approach | publisher=Springer | year=2006 | isbn=978-3-5403-0992-5}}
* {{cite book | first1=Heinz-Peter | last1=Breuer | first2=F. | last2=Petruccione | title=The Theory of Open Quantum Systems | publisher=Oxford University Press | year=2002 | isbn=978-0-1985-2063-4}}
* {{cite book | last = Gardiner | first = C.W. | last2 = Zoller | first2 = Peter | author2-link = Peter Zoller | title = Quantum Noise | place = Berlin Heidelberg | publisher = Springer-Verlag | series = Springer Series in Synergetics | date = 2010 | edition = 3rd | isbn = 978-3-642-06094-6}}
* {{cite book | last1=Ingarden | first1=Roman S. | last2=Kossakowski | first2=A. | last3=Ohya | first3=M. | title=Information Dynamics and Open Systems: Classical and Quantum Approach | publisher=Springer Verlag | location=New York | year=1997 | isbn=978-0-7923-4473-5}}
* {{cite book | last=Lindblad | first=G. | title=Non-Equilibrium Entropy and Irreversibility | url=http://www.google.com/books?id=tvMcxdPNmRAC&dq=.+Non-Equilibrium+Entropy+and+Irreversibility | publisher=Delta Reidel | location=Dordrecht | year=1983 | isbn=1-4020-0320-X}}
* {{cite book | last=Tarasov | first=Vasily E. | title=Quantum Mechanics of Non-Hamiltonian and Dissipative Systems | publisher=Elsevier Science | location=Amsterdam, Boston, London, New York | year=2008 | isbn=978-0-0805-5971-1}}
 
==External links==
* [http://www.cmmp.ucl.ac.uk/~ajf/course_notes/node36.html The Lindblad master equation]
 
[[Category:Quantum mechanics]]
[[Category:Equations]]

Latest revision as of 13:27, 31 December 2014

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