Ecological Debt Day: Difference between revisions

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By investing in a premium Word - Press theme, you're investing in the future of your website. This means you can setup your mailing list and auto-responder on your wordpress site and then you can add your subscription form to any other blog, splash page, capture page or any other site you like. Your parishioners and certainly interested audience can come in to you for further information from the group and sometimes even approaching happenings and systems with the church. In the recent years, there has been a notable rise in the number of companies hiring Indian Word - Press developers. You can customize the appearance with PSD to Word - Press conversion ''. <br><br>Any business enterprise that is certainly worth its name should really shell out a good deal in making sure that they have the most effective website that provides related info to its prospect. You do not catch a user's attention through big and large pictures that usually takes a millennium to load up. This plugin allows a blogger get more Facebook fans on the related fan page. Apart from these, you are also required to give some backlinks on other sites as well. Moreover, many Word - Press themes need to be purchased and designing your own WP site can be boring. <br><br>It is very easy to install Word - Press blog or website. It was also the very first year that the category of Martial Arts was included in the Parents - Connect nationwide online poll, allowing parents to vote for their favorite San Antonio Martial Arts Academy. Setting Up Your Business Online Using Free Wordpress Websites. You or your web designer can customize it as per your specific needs.  Here's more about [http://deurl.de/backup_plugin_597075 wordpress backup plugin] look at our web page. For any web design and development assignment, this is definitely one of the key concerns, specifically for online retail outlets as well as e-commerce websites. <br><br>Whether your Word - Press themes is premium or not, but nowadays every theme is designed with widget-ready. Russell HR Consulting provides expert knowledge in the practical application of employment law as well as providing employment law training and HR support services. Some examples of its additional features include; code inserter (for use with adding Google Analytics, Adsense section targeting etc) Webmaster verification assistant, Link Mask Generator, Robots. It's now become a great place to sell it thanks to Woo - Commerce. Fortunately, Word - Press Customization Service is available these days, right from custom theme design, to plugin customization and modifying your website, you can take any bespoke service for your Word - Press development project. <br><br>More it extends numerous opportunities where your firm is at comfort and rest assured of no risks & errors. Being a Plugin Developer, it is important for you to know that development of Word - Press driven website should be done only when you enable debugging. As a result, it is really crucial to just take aid of some experience when searching for superior quality totally free Word - Press themes, Word - Press Premium Themes for your web site. )  Remote Login:  With the process of PSD to Wordpress conversion comes the advantage of flexibility. I have never seen a plugin with such a massive array of features, this does everything that platinum SEO and All In One SEO, also throws in the functionality found within SEO Smart Links and a number of other plugins it is essentially the swiss army knife of Word - Press plugins.
| verifiedrevid = 451151193
|  Name = Dimethylphenylphosphine
|  ImageFile = Dimethylphenylphosphine.png
| ImageSize =
|  ImageName = Dimethylphenylphosphine
|  IUPACName = Dimethylphenylphosphane
|  OtherNames = Dimethylphenylphosphine
| Section1 = {{Chembox Identifiers
|  ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 62800
| PubChem = 69597
| InChI = 1/C8H11P/c1-9(2)8-6-4-3-5-7-8/h3-7H,1-2H3
| ChEBI_Ref = {{ebicite|correct|EBI}}
| ChEBI = 30671
| SMILES = P(c1ccccc1)(C)C
| InChIKey = HASCQPSFPAKVEK-UHFFFAOYAS
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/C8H11P/c1-9(2)8-6-4-3-5-7-8/h3-7H,1-2H3
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = HASCQPSFPAKVEK-UHFFFAOYSA-N
| CASNo_Ref = {{cascite|correct|CAS}}
| CASNo = 672-66-2
|  EINECS = 211-595-3
  }}
| Section2 = {{Chembox Properties
|  Formula = C<sub>8</sub>H<sub>11</sub>P
|  MolarMass = 138.14 g/mol
|  Appearance = Colorless light pale yellow liquid
|  Density = 0.971 g/cm<sup>3</sup>
|  Solubility = Insoluble
|  MeltingPt = N/A
|  BoilingPt = 74-75°C @ 12 mmHg
  }}
| Section3 = {{Chembox Structure
|  MolShape = Pyramidal
  }}
| Section7 = {{Chembox Hazards
|  ExternalMSDS = [http://www.sigmaaldrich.com/MSDS/MSDS/DisplayMSDSPage.do]
|  FlashPtC = 49
| RPhrases =  {{R10}} {{R36}} {{R37}} {{R38}}
| SPhrases =  {{S26}} {{S36}}
  }}
}}
''' Dimethylphenylphosphine ''' is an [[organophosphorus compound]] with a formula P(C<sub>6</sub>H<sub>5</sub>)(CH<sub>3</sub>)<sub>2</sub>. The [[phosphorus]] is connected to a [[phenyl]] group and two [[methyl]] groups. This colorless air sensitive liquid is commonly used as a [[ligand]] in [[transition metal complex]]es. These complexes are often soluble in organic solvents.
 
==Preparation==
Dimethylphenylphosphine is prepared by the reaction of [[Grignard reaction|methylmagnesium halide]] with [[dichlorophenylphosphine]].
 
:(C<sub>6</sub>H<sub>5</sub>)Cl<sub>2</sub>P  +  2CH<sub>3</sub>MgBr  →  (C<sub>6</sub>H<sub>5</sub>)(CH<sub>3</sub>)<sub>2</sub>P  +  2MgBrCl
 
The [[phosphine]] is purified by distillation under reduced pressure.<ref>C. Frajerman; B. Meunier; M. E. Strem., ''Inorganic Syntheses'', Preparation of Dimethylphenylphosphine, 2007, volume 22, 133-135, {{DOI|10.1002/9780470132531}}. ch29</ref>
A solution of (C<sub>6</sub>H<sub>5</sub>)(CH<sub>3</sub>)<sub>2</sub>P in CDCl<sub>3</sub> shows [[proton NMR]] signals at δ = 7.0-7.5 and a doublet at δ = 1.2. The [[phosphorus-31 NMR]] spectrum shows a singlet at -45.89 ppm in CDCl<sub>3</sub>.<ref>Laszlo T. Mika, Laszlo Orha, Norbert Farkas and Istvan T. Horvath, Organometallics, 2009, 28, 1593</ref>
 
==Structure and properties==
Dimethylphenylphosphine is a [[Trigonal pyramidal molecular geometry|pyramidal molecule]] where the [[phenyl]] group and two [[methyl]] groups are connected to the phosphorus. The [[bond length]] and angles are the following: P-C<sub>Me</sub>: 1.844, P-C<sub>Ph</sub>: 1.845 Å, C-C: 1.401 Å, C-H<sub>Me</sub>: 1.090 Å, C-H<sub>Ph</sub>: 1.067 Å, C-P-C: 96.9°, C-P-C (ring): 103.4°, P-C-H: 115.2°.<ref>Novikov, V.P., Kolomeets, V.I., Syshchikov, Yu.N., Vilkov, L.V., Yarkov, A.V., Tsvetkov, E.N., Raevskii, O.A.: Zh. Strukt. Khim., ''J. Struc. Chem''., Investigation of structure of dimethylphenylphosphine by means of gas-phase electron diffraction and vibrational spectroscopy, 1984, volume 25, No.5, 688. {{DOI|10.1007/BF00747909}}</ref>
 
==Comparisons with related phosphine ligands==
The υ<sub>CO</sub> of Ir-Cl(CO)(PPh<sub>3</sub>)<sub>2</sub> and Ir-Cl(CO)(PMe<sub>2</sub>Ph)<sub>2</sub> are both at 1960&nbsp;cm<sup>−1</sup>, whereas the υ<sub>CO</sub> for Ir-Cl(CO)(PMe<sub>3</sub>)<sub>2</sub> is at 1938&nbsp;cm<sup>−1</sup>.<ref>S.A. Cotton, Chemistry of Precious Metals., 1997, 152-157, ISBN 0-7514-0413-6, ISBN 978-0-7514-0413-5</ref><ref>A.R. Norrris ; J.A.V. Kessel, ''Canadian Journal of Chemistry'', Oxidative addition of 3,5-Dinitrobenzoyl Chloride to trans-Chlorocarbonylbis(dimethylphenylphosphine)iridium(I), 1973, 51, 4145-4151, {{DOI|10.1139/CJC-51-24-4145}}.</ref>
Also when comparing the acidity of HPR<sub>3</sub> (PR<sub>3</sub> = PMe<sub>2</sub>Ph, PPh<sub>3</sub>, PEt<sub>3</sub>) in CD<sub>2</sub>Cl<sub>2</sub>, the resulting [[pKa|pK<sub>a</sub>]] value is the following: [HPMe<sub>2</sub>Ph]<sup>+</sup>= 6.8, [HPPh<sub>3</sub>]<sup>+</sup> = 2.7, [HPEt<sub>3</sub>]<sup>+</sup> = 8.7.<ref>Russell C; Bush and Robert J. Angelici. Inorg. Chem, Phosphine Basicities As Determined by Enthalpies of Protonation 1988, 27, 681-686. {{doi|10.1021/ic00277a022}}</ref><ref>Tianshu Li ; Alan J.; Robert H., ''Chemistry- A European Journal'', An Acidity scale of Tetrafluoroborate Salts of Phosphonium and Iron Hydride compounds in [D2]Dichloromethane, 2007, volume 13, 3796-3803, {{DOI| 10.1002/chem..200601484}}.</ref> Thus PMe2Ph is intermediate in basicity relative to PPh<sub>3</sub> and PEt<sub>3</sub>.
 
The ligand [[cone angle]] (θ) is the apex angle of a cylindrical cone, which is centered 2.28 Å from the center of the P atom. However, the cone angle of an unsymmetrical ligand cannot be determined in the same. In order to determine an effective cone angle for an unsymmetrical ligand PX<sub>1</sub>X<sub>2</sub>X<sub>3</sub>, the following equation is used:
 
:<math>\theta = \frac{2}{3}\sum_{i=1}^3 \frac{\theta_i}2</math>
 
Where θ<sub>i</sub> represent the half angle.
 
The resulting angles for -PMe<sub>3</sub>, PMe<sub>2</sub>Ph, PPh<sub>3</sub> are the following:
PMe<sub>3</sub>= 118°, PMe<sub>2</sub>Ph= 122°, PPh<sub>3</sub>= 145°. Thus PMe<sub>2</sub>Ph is intermediate in size relative to PMe<sub>3</sub> and PPh<sub>3</sub>.<ref>C.A.Tolman, ''Chem.Rev''., Steric effects of phosphorus ligands in organometallic chemistry and homogeneous catalysis., 1977, 313-348, {{DOI|10.1021/cr60307a002}}</ref>
 
==References==
{{Reflist}}
 
[[Category:Tertiary phosphines]]
[[Category:Aromatic compounds]]

Revision as of 10:36, 5 March 2014

By investing in a premium Word - Press theme, you're investing in the future of your website. This means you can setup your mailing list and auto-responder on your wordpress site and then you can add your subscription form to any other blog, splash page, capture page or any other site you like. Your parishioners and certainly interested audience can come in to you for further information from the group and sometimes even approaching happenings and systems with the church. In the recent years, there has been a notable rise in the number of companies hiring Indian Word - Press developers. You can customize the appearance with PSD to Word - Press conversion .

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