Concordance correlation coefficient: Difference between revisions

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{{For|the formula describing ice formation|Stefan's equation}}
 
In [[thermodynamics]], '''Stefan’s formula''' says that the [[specific surface energy]] at a given interface is determined by the respective [[enthalpy]] difference <math>\scriptstyle \Delta H^*</math>.
 
: <math>\sigma = \gamma_0 \left( \frac{\Delta H^*}{N_A^{1/3}V_m^{2/3}}\right),</math>
 
where σ is the [[specific surface energy]], ''N''<sub>''A''</sub> is [[Avogadro's number]],  <math>\gamma_0</math></sub> is a steric [[dimensionless]] coefficient, and ''V''<sub>''m''</sub> is the [[molar volume]].
 
==References==
* Guencheva, V., Grantscharova, E. & Gutzow, I., Thermodynamic Properties of the Amorphous and Crystalline Modifications of Carbon and the Metastable Synthesis of Diamond, [[Cryst. Res. Technol.]], 2001, 36, 1411–1428
 
[[Category:Thermodynamics]]
[[Category:Chemical thermodynamics]]

Revision as of 06:05, 4 February 2014

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In thermodynamics, Stefan’s formula says that the specific surface energy at a given interface is determined by the respective enthalpy difference ΔH*.

σ=γ0(ΔH*NA1/3Vm2/3),

where σ is the specific surface energy, NA is Avogadro's number, γ0 is a steric dimensionless coefficient, and Vm is the molar volume.

References

  • Guencheva, V., Grantscharova, E. & Gutzow, I., Thermodynamic Properties of the Amorphous and Crystalline Modifications of Carbon and the Metastable Synthesis of Diamond, Cryst. Res. Technol., 2001, 36, 1411–1428