Pseudospectrum: Difference between revisions
en>Sullivan.t.j Eigenvectors have to be non-trivial! |
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{{chembox | |||
| verifiedrevid = 435546139 | |||
| Name = Arsenic pentoxide | |||
| ImageFile = Arsenic-pentoxide-3D-polyhedra.png | |||
| ImageName = Arsenic pentoxide | |||
| OtherNames = Arsenic(V) oxide<br />Arsenic oxide<br />Arsenic anhydride | |||
| Section1 = {{Chembox Identifiers | |||
| InChI = 1/As2O5/c3-1(4)7-2(5)6 | |||
| SMILES = O=[As](=O)O[As](=O)=O | |||
| InChIKey = COHDHYZHOPQOFD-UHFFFAOYAN | |||
| StdInChI_Ref = {{stdinchicite|correct|chemspider}} | |||
| StdInChI = 1S/As2O5/c3-1(4)7-2(5)6 | |||
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} | |||
| StdInChIKey = COHDHYZHOPQOFD-UHFFFAOYSA-N | |||
| CASNo_Ref = {{cascite|correct|CAS}} | |||
| CASNo = 1303-28-2 | |||
| PubChem = 14771 | |||
| EINECS = 215-116-9 | |||
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | |||
| ChemSpiderID = 14088 | |||
| RTECS = CG2275000 | |||
}} | |||
| Section2 = {{Chembox Properties | |||
| Formula = As<sub>2</sub>O<sub>5</sub> | |||
| MolarMass = 229.8402 g/mol | |||
| Appearance = white [[hygroscopic]] powder | |||
| Density = 4.32 g/cm<sup>3</sup> | |||
| MeltingPt = 315 °C (decomposes) | |||
| BoilingPt = | |||
| Solubility = 59.5 g/100 mL (0 °C) <br> 65.8 g/100 mL (20 °C) <br> 8.20 g/100 mL (100 °C) | |||
| SolubleOther = soluble in [[alcohol]] | |||
| pKa = 7 | |||
}} | |||
| Section7 = {{Chembox Hazards | |||
| ExternalMSDS = | |||
| EUClass = Very toxic ('''T+''')<br />Carc. Cat. 1<br />Dangerous for the environment ('''N''') | |||
| NFPA-H = 4 | |||
| NFPA-F = 0 | |||
| NFPA-R = 0 | |||
| RPhrases = {{R45}}, {{R23/25}}, {{R50/53}} | |||
| SPhrases = {{S53}}, {{S45}}, {{S60}}, {{S61}} | |||
| LD50 = 8 mg/kg (rat, oral) | |||
}} | |||
| Section8 = {{Chembox Other | |||
| OtherAnions = | |||
| OtherCations = [[Phosphorus pentoxide]]<br />[[Antimony pentoxide]] | |||
| OtherCpds = [[Arsenic trioxide]]<br />[[Arsenic acid]]}} | |||
}} | |||
'''Arsenic pentoxide''' is the [[inorganic compound]] with the formula As<sub>2</sub>O<sub>5</sub>.<ref>{{Greenwood&Earnshaw2nd}}</ref> This glassy, white, [[deliquescent]] solid is relatively unstable, consistent with the rarity of the As(V) oxidation state. More common, and far more important commercially, is [[arsenic(III) oxide]] (As<sub>2</sub>O<sub>3</sub>). All arsenic compounds are highly toxic and thus find only limited commercial applications. | |||
==Structure== | |||
The structure consists of tetrahedral {AsO<sub>4</sub>} and octahedral {AsO<sub>6</sub>} centres linked by sharing corners.<ref name = "Jansen">{{cite journal | author = Martin Jansen | title = Crystal Structure of As<sub>2</sub>O<sub>5</sub> | year = 1977 | journal = Angewandte Chemie International Edition in English | volume = 16 | issue = 5 | pages = 314–315 | doi = 10.1002/anie.197703142}}</ref> The structure differs from that of the corresponding phosphorus(V) oxide. | |||
==Synthesis== | |||
===Historical=== | |||
[[Paracelsus]] Macquer found a crystallizable salt which he called ‘sel neutre arsenical’. This salt was the obtaining residue after distilling [[nitric acid]] from a mixture of [[potassium nitrate]] and [[arsenic trioxide]]. Previously Paracelsus heated a mixture of arsenic trioxide and potassium nitrate. He applied the term ‘arsenicum fixum’ to the product. A. [[Libavius]] called the same product ‘butyrum arsenici’ (butter of arsenic), although this term was actually used for arsenic tricholoride. The products that Paracelsus and Libavius found were all impure alkali arsenates.<ref name = "Mellor">{{cite journal | author = J. W. Mellor | title = Comprehensive Treatise on Inorganic & Theoretical Chemistry | journal = http://www.rexresearch.com/alchemy10/melloras.htm English | volume = IX - Arsenic }}</ref> [[Scheele]] prepared a number of arsenates by the action of arsenic acid on the alkalies. One of the arsenates that he prepared, was arsenic pentoxide.<ref name = "Zenger">{{cite journal | author = C.W. Zenger et al | title = Arsenic 149 | journal = http://tera-3.ul.cs.cmu.edu/NASD/4dcb85c3-9fee-4c83-9e6d-fe6ce5522b59/China/disk4/75/75-2/31005153/HTML/00000166.htm}}</ref> The water in the alkalies evaporated at 180˚C, and the arsenic pentoxide was stable below 400˚C .<ref name = "Mellor"/> | |||
===Modern methods=== | |||
Arsenic pentoxide can be crystallized by heating As<sub>2</sub>O<sub>3</sub> under oxygen. This reaction is reversible:<ref name = "Jansen"/> | |||
As<sub>2</sub>O<sub>5</sub> <math>\overrightarrow{\leftarrow}</math> As<sub>2</sub>O<sub>3</sub> + O<sub>2</sub> | |||
Strong [[oxidizing agents]] such as [[ozone]], [[hydrogen peroxide]], and [[nitric acid]] convert arsenic trioxide to the pentoxide. | |||
Arsenic acid can be generated via routine processing of arsenic compounds including the oxidation of arsenic and arsenic-containing minerals in air. Illustrative is the roasting of [[orpiment]], a typical arsenic sulfide ore:<ref name=Ullmann>{{Ullmann | author = Grund, S. C.; Hanusch, K.; Wolf, H. U. | title = Arsenic and Arsenic Compounds | doi = 10.1002/14356007.a03_113.pub2 }}</ref> | |||
2 As<sub>2</sub>S<sub>3</sub> + 11 O<sub>2</sub> → 2 As<sub>2</sub>O<sub>5</sub> + 6 SO<sub>2</sub> | |||
==Safety== | |||
{{main|arsenic toxicity}} | |||
Like all arsenic compounds, the pentoxide is highly toxic. Its reduced derivative arsenite, which is an As(III) compound, is even more toxic since it has a high affinity for thiol groups of [[cysteine]] residues in proteins. | |||
==References== | |||
<references/> | |||
==External links== | |||
*[http://www.cdc.gov/niosh/npg/npgd0038.html NIOSH Pocket Guide to Chemical Hazards] | |||
*[http://www-cie.iarc.fr/htdocs/monographs/suppl7/arsenic.html IARC Monograph – Arsenic and Arsenic Compounds] | |||
*[http://ntp.niehs.nih.gov/ntp/roc/eleventh/profiles/s015arse.pdf NTP Report on Carcinogens – Inorganic Arsenic Compounds] | |||
*[http://esis.jrc.ec.europa.eu/ ESIS: European chemical Substances Information System] | |||
*{{nist}} | |||
{{Arsenic compounds}} | |||
{{DEFAULTSORT:Arsenic Pentoxide}} | |||
[[Category:Arsenic compounds]] | |||
[[Category:Chalcoarsenics]] | |||
[[Category:Oxides]] | |||
[[Category:IARC Group 1 carcinogens]] |
Revision as of 18:53, 29 October 2012
Arsenic pentoxide is the inorganic compound with the formula As2O5.[1] This glassy, white, deliquescent solid is relatively unstable, consistent with the rarity of the As(V) oxidation state. More common, and far more important commercially, is arsenic(III) oxide (As2O3). All arsenic compounds are highly toxic and thus find only limited commercial applications.
Structure
The structure consists of tetrahedral {AsO4} and octahedral {AsO6} centres linked by sharing corners.[2] The structure differs from that of the corresponding phosphorus(V) oxide.
Synthesis
Historical
Paracelsus Macquer found a crystallizable salt which he called ‘sel neutre arsenical’. This salt was the obtaining residue after distilling nitric acid from a mixture of potassium nitrate and arsenic trioxide. Previously Paracelsus heated a mixture of arsenic trioxide and potassium nitrate. He applied the term ‘arsenicum fixum’ to the product. A. Libavius called the same product ‘butyrum arsenici’ (butter of arsenic), although this term was actually used for arsenic tricholoride. The products that Paracelsus and Libavius found were all impure alkali arsenates.[3] Scheele prepared a number of arsenates by the action of arsenic acid on the alkalies. One of the arsenates that he prepared, was arsenic pentoxide.[4] The water in the alkalies evaporated at 180˚C, and the arsenic pentoxide was stable below 400˚C .[3]
Modern methods
Arsenic pentoxide can be crystallized by heating As2O3 under oxygen. This reaction is reversible:[2]
Strong oxidizing agents such as ozone, hydrogen peroxide, and nitric acid convert arsenic trioxide to the pentoxide.
Arsenic acid can be generated via routine processing of arsenic compounds including the oxidation of arsenic and arsenic-containing minerals in air. Illustrative is the roasting of orpiment, a typical arsenic sulfide ore:[5] 2 As2S3 + 11 O2 → 2 As2O5 + 6 SO2
Safety
Mining Engineer (Excluding Oil ) Truman from Alma, loves to spend time knotting, largest property developers in singapore developers in singapore and stamp collecting. Recently had a family visit to Urnes Stave Church. Like all arsenic compounds, the pentoxide is highly toxic. Its reduced derivative arsenite, which is an As(III) compound, is even more toxic since it has a high affinity for thiol groups of cysteine residues in proteins.
References
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Discover out more about real estate funding in the area, together with info on international funding incentives and property possession. Many Singaporeans have been investing in property across the causeway in recent years, attracted by comparatively low prices. However, those who need to exit their investments quickly are likely to face significant challenges when trying to sell their property – and could finally be stuck with a property they can't sell. Career improvement programmes, in-house valuation, auctions and administrative help, venture advertising and marketing, skilled talks and traisning are continuously planned for the sales associates to help them obtain better outcomes for his or her shoppers while at Knight Frank Singapore. No change Present Rules
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The data offered is for normal info purposes only and isn't supposed to be personalised investment or monetary advice. Motley Fool Singapore contributor Stanley Lim would not personal shares in any corporations talked about. Singapore private home costs increased by 1.eight% within the fourth quarter of 2012, up from 0.6% within the earlier quarter. Resale prices of government-built HDB residences which are usually bought by Singaporeans, elevated by 2.5%, quarter on quarter, the quickest acquire in five quarters. And industrial property, prices are actually double the levels of three years ago. No withholding tax in the event you sell your property. All your local information regarding vital HDB policies, condominium launches, land growth, commercial property and more
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In its statement, the singapore property listing - website link, government claimed that the majority citizens buying their first residence won't be hurt by the new measures. Some concessions can even be prolonged to chose teams of consumers, similar to married couples with a minimum of one Singaporean partner who are purchasing their second property so long as they intend to promote their first residential property. Lower the LTV limit on housing loans granted by monetary establishments regulated by MAS from 70% to 60% for property purchasers who are individuals with a number of outstanding housing loans on the time of the brand new housing purchase. Singapore Property Measures - 30 August 2010 The most popular seek for the number of bedrooms in Singapore is 4, followed by 2 and three. Lush Acres EC @ Sengkang
Discover out more about real estate funding in the area, together with info on international funding incentives and property possession. Many Singaporeans have been investing in property across the causeway in recent years, attracted by comparatively low prices. However, those who need to exit their investments quickly are likely to face significant challenges when trying to sell their property – and could finally be stuck with a property they can't sell. Career improvement programmes, in-house valuation, auctions and administrative help, venture advertising and marketing, skilled talks and traisning are continuously planned for the sales associates to help them obtain better outcomes for his or her shoppers while at Knight Frank Singapore. No change Present Rules
Extending the tax exemption would help. The exemption, which may be as a lot as $2 million per family, covers individuals who negotiate a principal reduction on their existing mortgage, sell their house short (i.e., for lower than the excellent loans), or take part in a foreclosure course of. An extension of theexemption would seem like a common-sense means to assist stabilize the housing market, but the political turmoil around the fiscal-cliff negotiations means widespread sense could not win out. Home Minority Chief Nancy Pelosi (D-Calif.) believes that the mortgage relief provision will be on the table during the grand-cut price talks, in response to communications director Nadeam Elshami. Buying or promoting of blue mild bulbs is unlawful.
A vendor's stamp duty has been launched on industrial property for the primary time, at rates ranging from 5 per cent to 15 per cent. The Authorities might be trying to reassure the market that they aren't in opposition to foreigners and PRs investing in Singapore's property market. They imposed these measures because of extenuating components available in the market." The sale of new dual-key EC models will even be restricted to multi-generational households only. The models have two separate entrances, permitting grandparents, for example, to dwell separately. The vendor's stamp obligation takes effect right this moment and applies to industrial property and plots which might be offered inside three years of the date of buy. JLL named Best Performing Property Brand for second year running
The data offered is for normal info purposes only and isn't supposed to be personalised investment or monetary advice. Motley Fool Singapore contributor Stanley Lim would not personal shares in any corporations talked about. Singapore private home costs increased by 1.eight% within the fourth quarter of 2012, up from 0.6% within the earlier quarter. Resale prices of government-built HDB residences which are usually bought by Singaporeans, elevated by 2.5%, quarter on quarter, the quickest acquire in five quarters. And industrial property, prices are actually double the levels of three years ago. No withholding tax in the event you sell your property. All your local information regarding vital HDB policies, condominium launches, land growth, commercial property and more
There are various methods to go about discovering the precise property. Some local newspapers (together with the Straits Instances ) have categorised property sections and many local property brokers have websites. Now there are some specifics to consider when buying a 'new launch' rental. Intended use of the unit Every sale begins with 10 p.c low cost for finish of season sale; changes to 20 % discount storewide; follows by additional reduction of fiftyand ends with last discount of 70 % or extra. Typically there is even a warehouse sale or transferring out sale with huge mark-down of costs for stock clearance. Deborah Regulation from Expat Realtor shares her property market update, plus prime rental residences and houses at the moment available to lease Esparina EC @ Sengkang - ↑ One of the biggest reasons investing in a Singapore new launch is an effective things is as a result of it is doable to be lent massive quantities of money at very low interest rates that you should utilize to purchase it. Then, if property values continue to go up, then you'll get a really high return on funding (ROI). Simply make sure you purchase one of the higher properties, reminiscent of the ones at Fernvale the Riverbank or any Singapore landed property Get Earnings by means of Renting
In its statement, the singapore property listing - website link, government claimed that the majority citizens buying their first residence won't be hurt by the new measures. Some concessions can even be prolonged to chose teams of consumers, similar to married couples with a minimum of one Singaporean partner who are purchasing their second property so long as they intend to promote their first residential property. Lower the LTV limit on housing loans granted by monetary establishments regulated by MAS from 70% to 60% for property purchasers who are individuals with a number of outstanding housing loans on the time of the brand new housing purchase. Singapore Property Measures - 30 August 2010 The most popular seek for the number of bedrooms in Singapore is 4, followed by 2 and three. Lush Acres EC @ Sengkang
Discover out more about real estate funding in the area, together with info on international funding incentives and property possession. Many Singaporeans have been investing in property across the causeway in recent years, attracted by comparatively low prices. However, those who need to exit their investments quickly are likely to face significant challenges when trying to sell their property – and could finally be stuck with a property they can't sell. Career improvement programmes, in-house valuation, auctions and administrative help, venture advertising and marketing, skilled talks and traisning are continuously planned for the sales associates to help them obtain better outcomes for his or her shoppers while at Knight Frank Singapore. No change Present Rules
Extending the tax exemption would help. The exemption, which may be as a lot as $2 million per family, covers individuals who negotiate a principal reduction on their existing mortgage, sell their house short (i.e., for lower than the excellent loans), or take part in a foreclosure course of. An extension of theexemption would seem like a common-sense means to assist stabilize the housing market, but the political turmoil around the fiscal-cliff negotiations means widespread sense could not win out. Home Minority Chief Nancy Pelosi (D-Calif.) believes that the mortgage relief provision will be on the table during the grand-cut price talks, in response to communications director Nadeam Elshami. Buying or promoting of blue mild bulbs is unlawful.
A vendor's stamp duty has been launched on industrial property for the primary time, at rates ranging from 5 per cent to 15 per cent. The Authorities might be trying to reassure the market that they aren't in opposition to foreigners and PRs investing in Singapore's property market. They imposed these measures because of extenuating components available in the market." The sale of new dual-key EC models will even be restricted to multi-generational households only. The models have two separate entrances, permitting grandparents, for example, to dwell separately. The vendor's stamp obligation takes effect right this moment and applies to industrial property and plots which might be offered inside three years of the date of buy. JLL named Best Performing Property Brand for second year running
The data offered is for normal info purposes only and isn't supposed to be personalised investment or monetary advice. Motley Fool Singapore contributor Stanley Lim would not personal shares in any corporations talked about. Singapore private home costs increased by 1.eight% within the fourth quarter of 2012, up from 0.6% within the earlier quarter. Resale prices of government-built HDB residences which are usually bought by Singaporeans, elevated by 2.5%, quarter on quarter, the quickest acquire in five quarters. And industrial property, prices are actually double the levels of three years ago. No withholding tax in the event you sell your property. All your local information regarding vital HDB policies, condominium launches, land growth, commercial property and more
There are various methods to go about discovering the precise property. Some local newspapers (together with the Straits Instances ) have categorised property sections and many local property brokers have websites. Now there are some specifics to consider when buying a 'new launch' rental. Intended use of the unit Every sale begins with 10 p.c low cost for finish of season sale; changes to 20 % discount storewide; follows by additional reduction of fiftyand ends with last discount of 70 % or extra. Typically there is even a warehouse sale or transferring out sale with huge mark-down of costs for stock clearance. Deborah Regulation from Expat Realtor shares her property market update, plus prime rental residences and houses at the moment available to lease Esparina EC @ Sengkang - ↑ Template:Ullmann