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<!-- To obtain a blank version of this page, type subst:chembox supplement inside of double curly braces, {{}}, and save the page -->
 
This page provides supplementary chemical data on [[chloroform]]. <!-- replace with proper wikilink -->
 
== Material Safety Data Sheet == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
 
The handling of this chemical may incur notable safety precautions. It is highly recommend that you seek the Material Safety Datasheet ([[Material safety data sheet|MSDS]]) for this chemical from a reliable source and follow its directions.
*[http://www2.siri.org/msds/index.php SIRI]
*[http://www.sciencestuff.com/msds/C1497.html Science Stuff]
*[https://fscimage.fishersci.com/msds/95979.htm Fisher Scientific]
 
== Structure and properties == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
 
{| border="1" cellspacing="0" cellpadding="3" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
! {{chembox header}} | Structure and properties
|-
| [[Index of refraction]], ''n''<sub>D</sub>
| 1.4459 at 19&nbsp;°C <!-- Please omit if not applicable` -->
|-
| [[Abbe number]]
|? <!-- Please omit if not applicable -->
|-
| [[Dielectric constant]], ε<sub>r</sub>
| 4.8069 ε<sub>0</sub> at 20&nbsp;°C <!-- Please omit if not applicable -->
|-
| [[Bond strength]]
| ? <!-- Specify which bond. Please omit if not applicable -->
|-
| [[Bond length]]<ref name="R. Fourme, M. Renaud 1966, p 69">R. Fourme, M. Renaud, ''C. R. Acad. Sci, Ser. C(Chim)'',1966, p 69</ref>
| C-Cl 1.75&nbsp;Å <!-- Specify which bond. Please omit if not applicable -->
|-
| [[Bond angle]]<ref name="R. Fourme, M. Renaud 1966, p 69"/>
| Cl-C-Cl 110.3° <!-- Specify which angle, e.g. Cl-P-O. Please omit if not applicable -->
|-
| [[Dipole#Molecular dipoles|Dipole moment]]
| 1.08 D (gas){{citation needed|date=July 2012}}<br>1.04 D<ref name="CRC HCP 89">''CRC Handbook of Chemistry and Physics''. 89th ed./David R. Lide ed.-in-chief. CRC Press: Boca Raton, 2008. - p. 9–58</ref>
|-
| [[Magnetic susceptibility]]
| ? - Close to that of Teflon <!-- Please omit if not applicable -->
|-
| [[Surface tension]]
| 28.5 dyn/cm at 10&nbsp;°C<br>27.1 dyn/cm at 20&nbsp;°C<br>26.67 dyn/cm at 25&nbsp;°C<br>23.44 dyn/cm at 50&nbsp;°C<br>21.7 dyn/cm at 60&nbsp;°C<br>20.20 dyn/cm at 75&nbsp;°C
|-
| [[Viscosity]]<ref name="lange1669">''Lange's Handbook of Chemistry'', 10th ed. pp 1669-1674</ref>
| 0.786 mPa·s at –10&nbsp;°C<br>0.699 mPa·s at 0&nbsp;°C<br>0.563 mPa·s at 20&nbsp;°C<br>0.542 mPa·s at 25&nbsp;°C<br>0.464 mPa·s at 40&nbsp;°C<br>0.389 mPa·s at 60&nbsp;°C
|-
|}
 
== Thermodynamic properties == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
 
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
! {{chembox header}} | Phase behavior
|-
| [[Triple point]]
| 209.61 K (–63.54&nbsp;°C), ? Pa
|-
| [[Critical point (chemistry)|Critical point]]
| 537 K (264&nbsp;°C), 5328.68 kPa
|-
| [[Standard enthalpy change of fusion|Std enthalpy change<br/>of fusion]], Δ<sub>fus</sub>''H''<sup><s>o</s></sup>
| 8.8 kJ/mol
|-
| [[Standard entropy change of fusion|Std entropy change<br/>of fusion]], Δ<sub>fus</sub>''S''<sup><s>o</s></sup>
| 42 J/(mol·K)
|-
| [[Standard enthalpy change of vaporization|Std enthalpy change<br/>of vaporization]], Δ<sub>vap</sub>''H''<sup><s>o</s></sup>
| 31.4 kJ/mol
|-
| [[Standard entropy change of vaporization|Std entropy change<br/>of vaporization]], Δ<sub>vap</sub>''S''<sup><s>o</s></sup>
| 105.3 J/(mol·K)
|-
! {{chembox header}} | Solid properties
|-
| [[Standard enthalpy change of formation|Std enthalpy change<br/>of formation]], Δ<sub>f</sub>''H''<sup><s>o</s></sup><sub>solid</sub>
| ? kJ/mol
|-
| [[Standard molar entropy]],<br/>''S''<sup><s>o</s></sup><sub>solid</sub>
| ? J/(mol K)
|-
| [[Heat capacity]], ''c<sub>p</sub>''
| ? J/(mol K)
|-
! {{chembox header}} | Liquid properties
|-
| [[Standard enthalpy change of formation|Std enthalpy change<br/>of formation]], Δ<sub>f</sub>''H''<sup><s>o</s></sup><sub>liquid</sub>
| –134.3 kJ/mol
|-
| [[Standard molar entropy]],<br/>''S''<sup><s>o</s></sup><sub>liquid</sub>
| ? J/(mol K)
|-
| [[Enthalpy of combustion]]
| –473.2 kJ/mol Δ<sub>c</sub>''H''<sup><s>o</s></sup>
|-
| [[Heat capacity]], ''c<sub>p</sub>''
| 114.25 J/(mol K)
|-
! {{chembox header}} | Gas properties
|-
| [[Standard enthalpy change of formation|Std enthalpy change<br/>of formation]], Δ<sub>f</sub>''H''<sup><s>o</s></sup><sub>gas</sub>
| –103.18 kJ/mol
|-
| [[Standard molar entropy]],<br/>''S''<sup><s>o</s></sup><sub>gas</sub>
| 295.6 J/(mol K) at 25&nbsp;°C
|-
| [[Heat capacity]], ''c<sub>p</sub>''
| 65.33 J/(mol K) at 25&nbsp;°C
|-
| [[van der Waals equation|van der Waals' constants]]<ref name="lange1522">''Lange's Handbook of Chemistry'' 10th ed, pp 1522–1524</ref>
| a = 1537 L<sup>2</sup> kPa/mol<sup>2</sup><br> b = 0.1022 liter per mole
|-
|}
 
==Vapor pressure of liquid==
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|-
| {{chembox header}} | '''P in mm Hg''' || 1 || 10 || 40 || 100 || 400 || 760 || 1520 || 3800 || 7600 || 15200 || 30400 || 45600
|-
| {{chembox header}} | '''T in °C''' || –58.0 || –29.7 || –7.1 || 10.4 || 42.7 || 61.3 || 83.9 || 120.0 || 152.3 || 191.8 || 237.5 || &nbsp;—
|}
Table data obtained from ''CRC Handbook of Chemistry and Physics'' 44th ed.
 
[[Image:LogChloroformVaporPressure.png|thumb|812px|left|'''log<sub>10</sub> of Chloroform vapor pressure.''' Uses formula: <math>\scriptstyle \log_e P_{mmHg} =</math><math>\scriptstyle \log_e (\frac {760} {101.325}) - 10.07089 \log_e(T+273.15) - \frac {6351.140} {T+273.15} + 81.14393 + 9.127608 \times 10^{-6} (T+273.15)^2</math> obtained from CHERIC<ref name="cheric_p">{{Cite web|url=http://www.cheric.org/research/kdb/hcprop/cmpsrch.php|title=Pure Component Properties|format=Queriable database|publisher=Chemical Engineering Research Information Center|accessdate=16 May 2007}}</ref>]]{{Clear}}
 
==Distillation data==
{|
|- valign="top"
|
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|-
| bgcolor="#D0D0D0" align="center" colspan="3" | '''Vapor-liquid Equilibrium<br>for Chloroform/[[Ethanol]]'''<ref name="cheric_b">{{Cite web|url=http://www.cheric.org/research/kdb/hcvle/hcvle.php|title=Binary Vapor-Liquid Equilibrium Data|publisher=Chemical Engineering Research Information Center|format=Queriable database|accessdate=17 May 2007}}</ref><br>''P'' = 101.325 kPa
|- {{chembox header}}
! rowspan="2" | BP<br>Temp.<br>°C
! colspan="2" | % by mole chlorform
|- {{chembox header}}
! liquid !! vapor
|-
| 78.15 || 0.0 || 0.0
|-
| 78.07 || 0.52 || 1.59
|-
| 77.83 || 1.02 || 3.01
|-
| 76.81 || 2.21 || 7.45
|-
| 74.90 || 5.80 || 17.10
|-
| 74.39 || 6.72 || 19.40
|-
| 73.55 || 8.38 || 23.31
|-
| 72.85 || 10.57 || 28.05
|-
| 72.24 || 11.80 || 30.52
|-
| 71.58 || 13.18 || 33.13
|-
| 69.72 || 17.65 || 41.00
|-
| 68.95 || 19.62 || 43.66
|-
| 68.58 || 20.71 || 45.43
|-
| 67.35 || 23.86 || 49.77
|-
| 65.89 || 28.54 || 55.09
|-
| 64.87 || 32.35 || 58.48
|-
| 63.88 || 36.07 || 61.27
|-
| 63.23 || 39.34 || 64.50
|-
| 62.61 || 41.38 || 65.49
|-
| 62.17 || 44.41 || 67.57
|-
| 61.48 || 49.97 || 71.11
|-
| 61.00 || 53.92 || 72.91
|-
| 60.49 || 54.76 || 73.57
|-
| 60.35 || 59.65 || 74.68
|-
| 60.30 || 61.60 || 75.53
|-
| 60.20 || 63.04 || 76.12
|-
| 60.09 || 64.48 || 76.69
|-
| 59.97 || 66.90 || 77.74
|-
| 59.54 || 72.01 || 79.33
|-
| 59.32 || 79.07 || 82.62
|-
| 59.26 || 82.99 || 83.59
|-
| 59.28 || 84.97 || 84.69
|-
| 59.31 || 85.96 || 85.24
|-
| 59.46 || 89.92 || 87.93
|-
| 59.72 || 91.10 || 88.73
|-
| 59.70 || 92.44 || 89.79
|-
| 59.84 || 93.90 || 91.02
|-
| 59.91 || 95.26 || 92.56
|-
| 60.18 || 96.13 || 93.58
|-
| 60.88 || 98.89 || 97.93
|-
| 61.13 || 100.00 || 100.00
|-
|}
| &nbsp; &nbsp;
|
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|-
| bgcolor="#D0D0D0" align="center" colspan="3" | '''Vapor-liquid Equilibrium<br>for Chloroform/[[Acetone]]'''<ref name="cheric_b"/><br>''P'' = 101.325 kPa
|- {{chembox header}}
! rowspan="2" | BP<br>Temp.<br>°C
! colspan="2" | % by mole acetone
|- {{chembox header}}
! liquid !! vapor
|-
| 62.11 || 7.5 || 4.9
|-
| 63.45 || 17.7 || 13.7
|-
| 63.95 || 22.9 || 19.1
|-
| 64.19 || 26.2 || 23.0
|-
| 64.29 || 28.5 || 25.9
|-
| 64.45 || 34.5 || 33.9
|-
| 64.47 || 35.7 || 35.6
|-
| 64.47 || 36.5 || 36.6
|-
| 64.46 || 38.7 || 39.6
|-
| 64.43 || 39.5 || 40.8
|-
| 64.40 || 40.4 || 42.0
|-
| 64.20 || 45.2 || 48.8
|-
| 64.05 || 46.6 || 51.0
|-
| 64.04 || 47.4 || 52.0
|-
| 63.67 || 51.9 || 57.9
|-
| 63.19 || 56.4 || 64.1
|-
| 62.73 || 59.4 || 67.9
|-
| 62.42 || 61.0 || 69.7
|-
| 62.16 || 62.4 || 71.5
|-
| 61.24 || 68.4 || 78.0
|-
| 60.23 || 74.7 || 84.0
|-
| 57.23 || 91.8 || 96.1
|-
|}
| &nbsp; &nbsp;
|
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|-
| bgcolor="#D0D0D0" align="center" colspan="3" | '''Vapor-liquid Equilibrium<br>for Chloroform/[[Methanol]]'''<ref name="cheric_b"/><br>''P'' = 760&nbsp;mm Hg
|- {{chembox header}}
! rowspan="2" | BP<br>Temp.<br>°C
! colspan="2" | % by mole chloroform
|- {{chembox header}}
! liquid !! vapor
|-
| 63 || 4.0 || 10.2
|-
| 62 || 6.5 || 15.4
|-
| 60.9 || 9.5 || 21.5
|-
| 59.3 || 14.6 || 30.4
|-
| 57.8 || 19.6 || 37.8
|-
| 57.0 || 23.0 || 42.0
|-
| 55.9 || 28.7 || 47.2
|-
| 55.3 || 33.2 || 50.7
|-
| 54.7 || 38.3 || 54.0
|-
| 54.3 || 42.5 || 56.4
|-
| 54.0 || 45.9 || 58.0
|-
| 53.8 || 52.0 || 60.7
|-
| 53.7 || 55.7 || 61.9
|-
| 53.5 || 62.8 || 64.3
|-
| 53.5 || 63.6 || 64.6
|-
| 53.5 || 66.7 || 65.5
|-
| 53.7 || 75.3 || 68.4
|-
| 53.9 || 79.7 || 70.1
|-
| 54.4 || 85.5 || 73.0
|-
| 55.2 || 90.4 || 76.8
|-
| 56.3 || 93.7 || 81.2
|-
| 57.9 || 97.0 || 87.5
|-
|}
|}
 
== Spectral data == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
 
{| border="1" cellspacing="0" cellpadding="3" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
! {{chembox header}} | [[UV/VIS spectroscopy|UV-Vis]]
|-
| [[Lambda-max|λ<sub>max</sub>]]
| ? [[Nanometre|nm]]
|-
| [[molar absorptivity|Extinction coefficient]], ε
| ?
|-
! {{chembox header}} | [[Infrared|IR]]
|-
| Major absorption bands
| 1215, 761, 668&nbsp;cm<sup>&minus;1</sup>
|-
! {{chembox header}} | [[NMR Spectroscopy|NMR]]
|-
| [[Proton NMR]] <!-- Link to image of spectrum -->
| δ CDCl<sub>3</sub> 7.26 (s, 1H)
|-
| [[Carbon-13 NMR]] <!-- Link to image of spectrum -->
| δ CDCl<sub>3</sub> 77.2
|-
| Other NMR data <!-- Insert special data e.g. <sup>19</sup>F chem. shifts, omit if not used -->
| &nbsp;
|-
! {{chembox header}} | [[Mass Spectrometry|MS]]
|-
| Masses of <br>main fragments
| &nbsp; <!-- Give list of major fragments -->
|-
|}
 
==References==
<references/>
* {{Cite web|url=http://webbook.nist.gov/chemistry/|title=NIST Standard Reference Database|accessdate=16 May 2007}}
 
Except where noted otherwise, data relate to [[standard ambient temperature and pressure]].
 
[[wikipedia:Chemical infobox|Disclaimer]] applies.
 
{{DEFAULTSORT:Chloroform (Data Page)}}
[[Category:Chemical data pages]]

Revision as of 15:54, 30 January 2014

30 year-old Entertainer or Range Artist Wesley from Drumheller, really loves vehicle, property developers properties for sale in singapore singapore and horse racing. Finds inspiration by traveling to Works of Antoni Gaudí.

This page provides supplementary chemical data on chloroform.

Material Safety Data Sheet

The handling of this chemical may incur notable safety precautions. It is highly recommend that you seek the Material Safety Datasheet (MSDS) for this chemical from a reliable source and follow its directions.

Structure and properties

Structure and properties
Index of refraction, nD 1.4459 at 19 °C
Abbe number ?
Dielectric constant, εr 4.8069 ε0 at 20 °C
Bond strength ?
Bond length[1] C-Cl 1.75 Å
Bond angle[1] Cl-C-Cl 110.3°
Dipole moment 1.08 D (gas)Potter or Ceramic Artist Truman Bedell from Rexton, has interests which include ceramics, best property developers in singapore developers in singapore and scrabble. Was especially enthused after visiting Alejandro de Humboldt National Park.
1.04 D[2]
Magnetic susceptibility ? - Close to that of Teflon
Surface tension 28.5 dyn/cm at 10 °C
27.1 dyn/cm at 20 °C
26.67 dyn/cm at 25 °C
23.44 dyn/cm at 50 °C
21.7 dyn/cm at 60 °C
20.20 dyn/cm at 75 °C
Viscosity[3] 0.786 mPa·s at –10 °C
0.699 mPa·s at 0 °C
0.563 mPa·s at 20 °C
0.542 mPa·s at 25 °C
0.464 mPa·s at 40 °C
0.389 mPa·s at 60 °C

Thermodynamic properties

Phase behavior
Triple point 209.61 K (–63.54 °C), ? Pa
Critical point 537 K (264 °C), 5328.68 kPa
Std enthalpy change
of fusion, ΔfusHo 		8.8 kJ/mol
Std entropy change
of fusion, ΔfusSo 		42 J/(mol·K)
Std enthalpy change
of vaporization, ΔvapHo 		31.4 kJ/mol
Std entropy change
of vaporization, ΔvapSo 		105.3 J/(mol·K)
Solid properties
Std enthalpy change
of formation, ΔfHosolid 		? kJ/mol
Standard molar entropy,
Sosolid 		? J/(mol K)
Heat capacity, cp ? J/(mol K)
Liquid properties
Std enthalpy change
of formation, ΔfHoliquid 		–134.3 kJ/mol
Standard molar entropy,
Soliquid 		? J/(mol K)
Enthalpy of combustion –473.2 kJ/mol ΔcHo
Heat capacity, cp 114.25 J/(mol K)
Gas properties
Std enthalpy change
of formation, ΔfHogas 		–103.18 kJ/mol
Standard molar entropy,
Sogas 		295.6 J/(mol K) at 25 °C
Heat capacity, cp 65.33 J/(mol K) at 25 °C
van der Waals' constants[4] a = 1537 L2 kPa/mol2
b = 0.1022 liter per mole

Vapor pressure of liquid

P in mm Hg 1 10 40 100 400 760 1520 3800 7600 15200 30400 45600
T in °C –58.0 –29.7 –7.1 10.4 42.7 61.3 83.9 120.0 152.3 191.8 237.5  —

Table data obtained from CRC Handbook of Chemistry and Physics 44th ed.

File:LogChloroformVaporPressure.png
log10 of Chloroform vapor pressure. Uses formula: logePmmHg=loge(760101.325)−10.07089loge(T+273.15)−6351.140T+273.15+81.14393+9.127608×10−6(T+273.15)2 obtained from CHERIC[5]

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Distillation data

Vapor-liquid Equilibrium
for Chloroform/Ethanol[6]
P = 101.325 kPa
BP
Temp.
°C 		% by mole chlorform
liquid vapor
78.15 0.0 0.0
78.07 0.52 1.59
77.83 1.02 3.01
76.81 2.21 7.45
74.90 5.80 17.10
74.39 6.72 19.40
73.55 8.38 23.31
72.85 10.57 28.05
72.24 11.80 30.52
71.58 13.18 33.13
69.72 17.65 41.00
68.95 19.62 43.66
68.58 20.71 45.43
67.35 23.86 49.77
65.89 28.54 55.09
64.87 32.35 58.48
63.88 36.07 61.27
63.23 39.34 64.50
62.61 41.38 65.49
62.17 44.41 67.57
61.48 49.97 71.11
61.00 53.92 72.91
60.49 54.76 73.57
60.35 59.65 74.68
60.30 61.60 75.53
60.20 63.04 76.12
60.09 64.48 76.69
59.97 66.90 77.74
59.54 72.01 79.33
59.32 79.07 82.62
59.26 82.99 83.59
59.28 84.97 84.69
59.31 85.96 85.24
59.46 89.92 87.93
59.72 91.10 88.73
59.70 92.44 89.79
59.84 93.90 91.02
59.91 95.26 92.56
60.18 96.13 93.58
60.88 98.89 97.93
61.13 100.00 100.00
   
Vapor-liquid Equilibrium
for Chloroform/Acetone[6]
P = 101.325 kPa
BP
Temp.
°C 		% by mole acetone
liquid vapor
62.11 7.5 4.9
63.45 17.7 13.7
63.95 22.9 19.1
64.19 26.2 23.0
64.29 28.5 25.9
64.45 34.5 33.9
64.47 35.7 35.6
64.47 36.5 36.6
64.46 38.7 39.6
64.43 39.5 40.8
64.40 40.4 42.0
64.20 45.2 48.8
64.05 46.6 51.0
64.04 47.4 52.0
63.67 51.9 57.9
63.19 56.4 64.1
62.73 59.4 67.9
62.42 61.0 69.7
62.16 62.4 71.5
61.24 68.4 78.0
60.23 74.7 84.0
57.23 91.8 96.1
   
Vapor-liquid Equilibrium
for Chloroform/Methanol[6]
P = 760 mm Hg
BP
Temp.
°C 		% by mole chloroform
liquid vapor
63 4.0 10.2
62 6.5 15.4
60.9 9.5 21.5
59.3 14.6 30.4
57.8 19.6 37.8
57.0 23.0 42.0
55.9 28.7 47.2
55.3 33.2 50.7
54.7 38.3 54.0
54.3 42.5 56.4
54.0 45.9 58.0
53.8 52.0 60.7
53.7 55.7 61.9
53.5 62.8 64.3
53.5 63.6 64.6
53.5 66.7 65.5
53.7 75.3 68.4
53.9 79.7 70.1
54.4 85.5 73.0
55.2 90.4 76.8
56.3 93.7 81.2
57.9 97.0 87.5

Spectral data

UV-Vis
λmax ? nm
Extinction coefficient, ε ?
IR
Major absorption bands 1215, 761, 668 cm−1
NMR
Proton NMR δ CDCl3 7.26 (s, 1H)
Carbon-13 NMR δ CDCl3 77.2
Other NMR data  
MS
Masses of
main fragments 		 

References

  1. ↑ 1.0 1.1 R. Fourme, M. Renaud, C. R. Acad. Sci, Ser. C(Chim),1966, p 69
  2. ↑ CRC Handbook of Chemistry and Physics. 89th ed./David R. Lide ed.-in-chief. CRC Press: Boca Raton, 2008. - p. 9–58
  3. ↑ Lange's Handbook of Chemistry, 10th ed. pp 1669-1674
  4. ↑ Lange's Handbook of Chemistry 10th ed, pp 1522–1524
  5. ↑ Template:Cite web
  6. ↑ 6.0 6.1 6.2 Template:Cite web

Except where noted otherwise, data relate to standard ambient temperature and pressure.

Disclaimer applies.

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