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Latest revision as of 20:35, 20 April 2013

A carbon dioxide scrubber is a device which absorbs carbon dioxide (CO₂). It is used to treat exhaust gases from industrial plants or from exhaled air in life support systems such as rebreathers or in spacecraft, submersible craft or airtight chambers. Carbon dioxide scrubbers are also used in controlled atmosphere (CA) storage.

Technologies

Amine scrubbing

Mining Engineer (Excluding Oil ) Truman from Alma, loves to spend time knotting, largest property developers in singapore developers in singapore and stamp collecting. Recently had a family visit to Urnes Stave Church. The dominant application for CO₂ scrubbing is for removal of CO₂ from the exhaust of coal- and gas-fired power plants. Virtually the only technology being seriously evaluated involves the use of various amines, e.g. monoethanolamine. Cold solutions of these organic compounds bind CO₂, but the binding is reversed at higher temperatures:

CO₂ + 2HOCH₂CH₂NH₂

\vec{\leftarrow}

HOCH₂CH₂NH₃⁺HOCH₂CH₂NH(CO₂^-)

This technology has only been lightly implemented because of capital costs of installing the facility and the operating costs of utilizing it.^[1]

Minerals and zeolites

Several minerals and mineral-like materials reversibly bind CO₂.^[2] Most often, these minerals are oxides, and often the CO₂ is bound as carbonate. Carbon dioxide reacts with quicklime (calcium oxide), to form limestone (calcium carbonate).^[3] The process is called Carbonate Looping. Other minerals include serpentinite, a magnesium silicate hydroxide and olivine.^[4]^[5] Molecular sieves also function in this capacity.

Various scrubbing processes have been proposed to remove CO₂ from the air, or from flue gases. These usually involve using a variant of the Kraft process. Scrubbing processes may be based on sodium hydroxide.^[6]^[7] The CO₂ is absorbed into solution, transferred to lime via a process called causticization and released in a kiln. With some modifications to the existing processes, mainly an oxygen-fired kiln, the end result is a concentrated stream of CO₂ ready for storage or use in fuels. An alternative to this thermo-chemical process is an electrical one in which a nominal voltage is applied across the carbonate solution to release the CO₂. While simpler, this electrical process consumes more energy as it splits water at the same time. Since it depends on electricity, the electricity needs to be renewable, like PV. Otherwise the CO₂ produced during electricity production has to be taken into account. Early incarnations of air capture used electricity as the energy source; hence, were dependent on a carbon-free source. Thermal air capture systems use heat generated on-site, which reduces the inefficiencies associated with off-site electricity production, but of course it still needs a source of (carbon-free) heat. Concentrated solar power is an example of such a source.^[8]

Sodium hydroxide

Zeman and Lackner outlined a specific method of air capture.^[9]

First, CO₂ is absorbed by an alkaline NaOH solution to produce dissolved sodium carbonate. The absorption reaction is a gas liquid reaction, strongly exothermic, (below)

2NaOH(aq) + CO₂(g) → Na₂CO₃(aq) + H₂O(l)

Na₂CO₃(aq) + Ca(OH)₂(s) →-> 2NaOH(aq) + CaCO₃(s)

ΔH° = -5.3 kJ/mol

Causticization is performed ubiquitously in the pulp and paper industry and readily transfers 94% of the carbonate ions from the sodium to the calcium cation.^[9] Subsequently, the calcium carbonate precipitate is filtered from solution and thermally decomposed to produce gaseous CO₂. The calcination reaction is the only endothermic reaction in the process and is shown (below).

CaCO₃(s) → CaO(s) + CO₂(g)

ΔH° = + 179.2 kJ/mol

The thermal decomposition of calcite is performed in a lime kiln fired with oxygen in order to avoid an additional gas separation step. Hydration of the lime (CaO) completes the cycle. Lime hydration is an exothermic reaction that can be performed with water or steam. Using water, it is a liquid/solid reaction as shown (below).

CaO(s) + H₂O(l) → Ca(OH)₂(s)

ΔH° = -64.5 kJ/mol

Lithium hydroxide

Other strong bases such as soda lime, sodium hydroxide, potassium hydroxide, and lithium hydroxide are able to remove carbon dioxide by chemically reacting with it. In particular, lithium hydroxide is used aboard spacecraft to remove carbon dioxide from the atmosphere. It reacts with carbon dioxide to make lithium carbonate:^[10]

2 LiOH(s) + 2 H₂O(g) → 2 LiOH.H₂O(s)

2 LiOH.H₂O(s) + CO₂(g) → Li₂CO₃(s) + 3 H₂O(g)

The net reaction being:

2 LiOH(s) + CO₂(g) → Li₂CO₃(s) + H₂O(g)

Lithium peroxide can also be used as it absorbs more CO₂ per unit weight with the added advantage of releasing oxygen.^[11] This is useful for breathing air systems and was used to remove CO₂ from the Apollo spacecraft.

Regenerative carbon dioxide removal system

The regenerative carbon dioxide removal system (RCRS) on the space shuttle orbiter used a two-bed system that provided continuous removal of carbon dioxide without expendable products. Regenerable systems allowed a shuttle mission a longer stay in space without having to replenish its sorbent canisters. Older lithium hydroxide (LiOH)-based systems, which are non-regenerable, were replaced by regenerable metal-oxide-based systems. A system based on metal oxide primarily consisted of a metal oxide sorbent canister and a regenerator assembly. It worked by removing carbon dioxide using a sorbent material and then regenerating the sorbent material. The metal-oxide sorbent canister was regenerated by pumping air at approximately Template:Convert through it at a standardTemplate:Clarify flow rate of Template:Convert for 10 hours.^[12]

Activated carbon

Activated carbon can be used as a carbon dioxide scrubber. Air with high carbon dioxide content, such as air from fruit storage locations, can be blown through beds of activated carbon and the carbon dioxide will adsorb onto the activated carbon. Once the bed is saturated it must then be "regenerated" by blowing low carbon dioxide air, such as ambient air, through the bed. This will release the carbon dioxide from the bed, and it can then be used to scrub again, leaving the net amount of carbon dioxide in the air the same as when the process was started.

Other methods

Many other methods and materials have been discussed for scrubbing carbon dioxide.

Adsorption^[13]
Regenerative carbon dioxide removal system (RCRS)
Photosynthesis: e.g. Algae based carbon sink
Polymer membrane gas separators^[14]^[15]
Reversing heat exchangers

References

43 year old Petroleum Engineer Harry from Deep River, usually spends time with hobbies and interests like renting movies, property developers in singapore new condominium and vehicle racing. Constantly enjoys going to destinations like Camino Real de Tierra Adentro.

Template:Underwater breathing apparatus

↑ Gary T. Rochelle "Amine Scrubbing for CO₂ Capture" Science volumen 325, 1652 (2009). Electronic Instrument Positions Staff (Standard ) Cameron from Clarence Creek, usually spends time with hobbies and interests which include knotting, property developers in singapore apartment For sale and boomerangs. Has enrolled in a world contiki journey. Is extremely thrilled specifically about visiting .
↑ Sunho Choi, Jeffrey H. Drese, and Christopher W. Jones "Adsorbent Materials for Carbon Dioxide Capture from Large Anthropogenic Point Sources" ChemSusChem 2009, 2, 796 – 854. Electronic Instrument Positions Staff (Standard ) Cameron from Clarence Creek, usually spends time with hobbies and interests which include knotting, property developers in singapore apartment For sale and boomerangs. Has enrolled in a world contiki journey. Is extremely thrilled specifically about visiting .
↑ Template:Cite web
↑ Template:Cite web
↑ [1]Template:Dead link
↑ Template:Cite news
↑ Template:Cite web
↑ Template:Cite web
↑ ^9.0 ^9.1 One of the biggest reasons investing in a Singapore new launch is an effective things is as a result of it is doable to be lent massive quantities of money at very low interest rates that you should utilize to purchase it. Then, if property values continue to go up, then you'll get a really high return on funding (ROI). Simply make sure you purchase one of the higher properties, reminiscent of the ones at Fernvale the Riverbank or any Singapore landed property Get Earnings by means of Renting

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Discover out more about real estate funding in the area, together with info on international funding incentives and property possession. Many Singaporeans have been investing in property across the causeway in recent years, attracted by comparatively low prices. However, those who need to exit their investments quickly are likely to face significant challenges when trying to sell their property – and could finally be stuck with a property they can't sell. Career improvement programmes, in-house valuation, auctions and administrative help, venture advertising and marketing, skilled talks and traisning are continuously planned for the sales associates to help them obtain better outcomes for his or her shoppers while at Knight Frank Singapore. No change Present Rules

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A vendor's stamp duty has been launched on industrial property for the primary time, at rates ranging from 5 per cent to 15 per cent. The Authorities might be trying to reassure the market that they aren't in opposition to foreigners and PRs investing in Singapore's property market. They imposed these measures because of extenuating components available in the market." The sale of new dual-key EC models will even be restricted to multi-generational households only. The models have two separate entrances, permitting grandparents, for example, to dwell separately. The vendor's stamp obligation takes effect right this moment and applies to industrial property and plots which might be offered inside three years of the date of buy. JLL named Best Performing Property Brand for second year running

The data offered is for normal info purposes only and isn't supposed to be personalised investment or monetary advice. Motley Fool Singapore contributor Stanley Lim would not personal shares in any corporations talked about. Singapore private home costs increased by 1.eight% within the fourth quarter of 2012, up from 0.6% within the earlier quarter. Resale prices of government-built HDB residences which are usually bought by Singaporeans, elevated by 2.5%, quarter on quarter, the quickest acquire in five quarters. And industrial property, prices are actually double the levels of three years ago. No withholding tax in the event you sell your property. All your local information regarding vital HDB policies, condominium launches, land growth, commercial property and more

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Discover out more about real estate funding in the area, together with info on international funding incentives and property possession. Many Singaporeans have been investing in property across the causeway in recent years, attracted by comparatively low prices. However, those who need to exit their investments quickly are likely to face significant challenges when trying to sell their property – and could finally be stuck with a property they can't sell. Career improvement programmes, in-house valuation, auctions and administrative help, venture advertising and marketing, skilled talks and traisning are continuously planned for the sales associates to help them obtain better outcomes for his or her shoppers while at Knight Frank Singapore. No change Present Rules

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A vendor's stamp duty has been launched on industrial property for the primary time, at rates ranging from 5 per cent to 15 per cent. The Authorities might be trying to reassure the market that they aren't in opposition to foreigners and PRs investing in Singapore's property market. They imposed these measures because of extenuating components available in the market." The sale of new dual-key EC models will even be restricted to multi-generational households only. The models have two separate entrances, permitting grandparents, for example, to dwell separately. The vendor's stamp obligation takes effect right this moment and applies to industrial property and plots which might be offered inside three years of the date of buy. JLL named Best Performing Property Brand for second year running

The data offered is for normal info purposes only and isn't supposed to be personalised investment or monetary advice. Motley Fool Singapore contributor Stanley Lim would not personal shares in any corporations talked about. Singapore private home costs increased by 1.eight% within the fourth quarter of 2012, up from 0.6% within the earlier quarter. Resale prices of government-built HDB residences which are usually bought by Singaporeans, elevated by 2.5%, quarter on quarter, the quickest acquire in five quarters. And industrial property, prices are actually double the levels of three years ago. No withholding tax in the event you sell your property. All your local information regarding vital HDB policies, condominium launches, land growth, commercial property and more

There are various methods to go about discovering the precise property. Some local newspapers (together with the Straits Instances ) have categorised property sections and many local property brokers have websites. Now there are some specifics to consider when buying a 'new launch' rental. Intended use of the unit Every sale begins with 10 p.c low cost for finish of season sale; changes to 20 % discount storewide; follows by additional reduction of fiftyand ends with last discount of 70 % or extra. Typically there is even a warehouse sale or transferring out sale with huge mark-down of costs for stock clearance. Deborah Regulation from Expat Realtor shares her property market update, plus prime rental residences and houses at the moment available to lease Esparina EC @ Sengkang
↑ Template:Cite doi
↑ Template:Cite web
↑ Template:Cite web
↑ [2]Template:Dead link
↑ [3]Template:Dead link

[1] Gary T. Rochelle "Amine Scrubbing for CO₂ Capture" Science volumen 325, 1652 (2009). Electronic Instrument Positions Staff (Standard ) Cameron from Clarence Creek, usually spends time with hobbies and interests which include knotting, property developers in singapore apartment For sale and boomerangs. Has enrolled in a world contiki journey. Is extremely thrilled specifically about visiting .

[2] Sunho Choi, Jeffrey H. Drese, and Christopher W. Jones "Adsorbent Materials for Carbon Dioxide Capture from Large Anthropogenic Point Sources" ChemSusChem 2009, 2, 796 – 854. Electronic Instrument Positions Staff (Standard ) Cameron from Clarence Creek, usually spends time with hobbies and interests which include knotting, property developers in singapore apartment For sale and boomerangs. Has enrolled in a world contiki journey. Is extremely thrilled specifically about visiting .

[3] Template:Cite web

[4] Template:Cite web

[5] [1]Template:Dead link

[ChangNYT2008-6] Template:Cite news

[7] Template:Cite web

[newscientist1-8] Template:Cite web

[naoh-zeman-9] 9.0 ^9.1 One of the biggest reasons investing in a Singapore new launch is an effective things is as a result of it is doable to be lent massive quantities of money at very low interest rates that you should utilize to purchase it. Then, if property values continue to go up, then you'll get a really high return on funding (ROI). Simply make sure you purchase one of the higher properties, reminiscent of the ones at Fernvale the Riverbank or any Singapore landed property Get Earnings by means of Renting

In its statement, the singapore property listing - website link, government claimed that the majority citizens buying their first residence won't be hurt by the new measures. Some concessions can even be prolonged to chose teams of consumers, similar to married couples with a minimum of one Singaporean partner who are purchasing their second property so long as they intend to promote their first residential property. Lower the LTV limit on housing loans granted by monetary establishments regulated by MAS from 70% to 60% for property purchasers who are individuals with a number of outstanding housing loans on the time of the brand new housing purchase. Singapore Property Measures - 30 August 2010 The most popular seek for the number of bedrooms in Singapore is 4, followed by 2 and three. Lush Acres EC @ Sengkang

Discover out more about real estate funding in the area, together with info on international funding incentives and property possession. Many Singaporeans have been investing in property across the causeway in recent years, attracted by comparatively low prices. However, those who need to exit their investments quickly are likely to face significant challenges when trying to sell their property – and could finally be stuck with a property they can't sell. Career improvement programmes, in-house valuation, auctions and administrative help, venture advertising and marketing, skilled talks and traisning are continuously planned for the sales associates to help them obtain better outcomes for his or her shoppers while at Knight Frank Singapore. No change Present Rules

Extending the tax exemption would help. The exemption, which may be as a lot as $2 million per family, covers individuals who negotiate a principal reduction on their existing mortgage, sell their house short (i.e., for lower than the excellent loans), or take part in a foreclosure course of. An extension of theexemption would seem like a common-sense means to assist stabilize the housing market, but the political turmoil around the fiscal-cliff negotiations means widespread sense could not win out. Home Minority Chief Nancy Pelosi (D-Calif.) believes that the mortgage relief provision will be on the table during the grand-cut price talks, in response to communications director Nadeam Elshami. Buying or promoting of blue mild bulbs is unlawful.

A vendor's stamp duty has been launched on industrial property for the primary time, at rates ranging from 5 per cent to 15 per cent. The Authorities might be trying to reassure the market that they aren't in opposition to foreigners and PRs investing in Singapore's property market. They imposed these measures because of extenuating components available in the market." The sale of new dual-key EC models will even be restricted to multi-generational households only. The models have two separate entrances, permitting grandparents, for example, to dwell separately. The vendor's stamp obligation takes effect right this moment and applies to industrial property and plots which might be offered inside three years of the date of buy. JLL named Best Performing Property Brand for second year running

The data offered is for normal info purposes only and isn't supposed to be personalised investment or monetary advice. Motley Fool Singapore contributor Stanley Lim would not personal shares in any corporations talked about. Singapore private home costs increased by 1.eight% within the fourth quarter of 2012, up from 0.6% within the earlier quarter. Resale prices of government-built HDB residences which are usually bought by Singaporeans, elevated by 2.5%, quarter on quarter, the quickest acquire in five quarters. And industrial property, prices are actually double the levels of three years ago. No withholding tax in the event you sell your property. All your local information regarding vital HDB policies, condominium launches, land growth, commercial property and more

There are various methods to go about discovering the precise property. Some local newspapers (together with the Straits Instances ) have categorised property sections and many local property brokers have websites. Now there are some specifics to consider when buying a 'new launch' rental. Intended use of the unit Every sale begins with 10 p.c low cost for finish of season sale; changes to 20 % discount storewide; follows by additional reduction of fiftyand ends with last discount of 70 % or extra. Typically there is even a warehouse sale or transferring out sale with huge mark-down of costs for stock clearance. Deborah Regulation from Expat Realtor shares her property market update, plus prime rental residences and houses at the moment available to lease Esparina EC @ Sengkang

[10] One of the biggest reasons investing in a Singapore new launch is an effective things is as a result of it is doable to be lent massive quantities of money at very low interest rates that you should utilize to purchase it. Then, if property values continue to go up, then you'll get a really high return on funding (ROI). Simply make sure you purchase one of the higher properties, reminiscent of the ones at Fernvale the Riverbank or any Singapore landed property Get Earnings by means of Renting

In its statement, the singapore property listing - website link, government claimed that the majority citizens buying their first residence won't be hurt by the new measures. Some concessions can even be prolonged to chose teams of consumers, similar to married couples with a minimum of one Singaporean partner who are purchasing their second property so long as they intend to promote their first residential property. Lower the LTV limit on housing loans granted by monetary establishments regulated by MAS from 70% to 60% for property purchasers who are individuals with a number of outstanding housing loans on the time of the brand new housing purchase. Singapore Property Measures - 30 August 2010 The most popular seek for the number of bedrooms in Singapore is 4, followed by 2 and three. Lush Acres EC @ Sengkang

Discover out more about real estate funding in the area, together with info on international funding incentives and property possession. Many Singaporeans have been investing in property across the causeway in recent years, attracted by comparatively low prices. However, those who need to exit their investments quickly are likely to face significant challenges when trying to sell their property – and could finally be stuck with a property they can't sell. Career improvement programmes, in-house valuation, auctions and administrative help, venture advertising and marketing, skilled talks and traisning are continuously planned for the sales associates to help them obtain better outcomes for his or her shoppers while at Knight Frank Singapore. No change Present Rules

Extending the tax exemption would help. The exemption, which may be as a lot as $2 million per family, covers individuals who negotiate a principal reduction on their existing mortgage, sell their house short (i.e., for lower than the excellent loans), or take part in a foreclosure course of. An extension of theexemption would seem like a common-sense means to assist stabilize the housing market, but the political turmoil around the fiscal-cliff negotiations means widespread sense could not win out. Home Minority Chief Nancy Pelosi (D-Calif.) believes that the mortgage relief provision will be on the table during the grand-cut price talks, in response to communications director Nadeam Elshami. Buying or promoting of blue mild bulbs is unlawful.

A vendor's stamp duty has been launched on industrial property for the primary time, at rates ranging from 5 per cent to 15 per cent. The Authorities might be trying to reassure the market that they aren't in opposition to foreigners and PRs investing in Singapore's property market. They imposed these measures because of extenuating components available in the market." The sale of new dual-key EC models will even be restricted to multi-generational households only. The models have two separate entrances, permitting grandparents, for example, to dwell separately. The vendor's stamp obligation takes effect right this moment and applies to industrial property and plots which might be offered inside three years of the date of buy. JLL named Best Performing Property Brand for second year running

The data offered is for normal info purposes only and isn't supposed to be personalised investment or monetary advice. Motley Fool Singapore contributor Stanley Lim would not personal shares in any corporations talked about. Singapore private home costs increased by 1.eight% within the fourth quarter of 2012, up from 0.6% within the earlier quarter. Resale prices of government-built HDB residences which are usually bought by Singaporeans, elevated by 2.5%, quarter on quarter, the quickest acquire in five quarters. And industrial property, prices are actually double the levels of three years ago. No withholding tax in the event you sell your property. All your local information regarding vital HDB policies, condominium launches, land growth, commercial property and more

There are various methods to go about discovering the precise property. Some local newspapers (together with the Straits Instances ) have categorised property sections and many local property brokers have websites. Now there are some specifics to consider when buying a 'new launch' rental. Intended use of the unit Every sale begins with 10 p.c low cost for finish of season sale; changes to 20 % discount storewide; follows by additional reduction of fiftyand ends with last discount of 70 % or extra. Typically there is even a warehouse sale or transferring out sale with huge mark-down of costs for stock clearance. Deborah Regulation from Expat Realtor shares her property market update, plus prime rental residences and houses at the moment available to lease Esparina EC @ Sengkang

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@@ Line 1: / Line 1: @@
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+A '''carbon dioxide scrubber''' is a device which absorbs [[carbon dioxide]] (CO<sub>2</sub>). It is used to treat [[exhaust gas]]es from [[industrial plant]]s or from exhaled air in [[life support system]]s such as [[rebreather]]s or in [[spacecraft]], [[submersible]] craft or [[airtight chamber]]s. Carbon dioxide scrubbers are also used in [[controlled atmosphere]] (CA) storage.
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+==Technologies==
+===Amine scrubbing===
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+{{main|Amine gas treating}}
+The dominant application for CO<sub>2</sub> scrubbing is for removal of CO<sub>2</sub> from the exhaust of coal- and gas-fired [[power plant]]s.  Virtually the only technology being seriously evaluated involves the use of various [[amine]]s, e.g. [[monoethanolamine]].  Cold solutions of these organic compounds bind CO<sub>2</sub>, but the binding is reversed at higher temperatures:
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+:CO<sub>2</sub>  +  2HOCH<sub>2</sub>CH<sub>2</sub>NH<sub>2</sub>   <math>\overrightarrow{\leftarrow}</math>   HOCH<sub>2</sub>CH<sub>2</sub>NH<sub>3</sub><sup>+</sup>HOCH<sub>2</sub>CH<sub>2</sub>NH(CO<sub>2</sub><sup>-</sup>)
+This technology has only been lightly implemented because of capital costs of installing the facility and the operating costs of utilizing it.<ref>
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+Gary T. Rochelle "Amine Scrubbing for CO<sub>2</sub> Capture" Science volumen 325, 1652 (2009). {{DOI|10.1126/science.1176731}}</ref>
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-== Mikiny Nike Levně  pokánie ==
+===Minerals and zeolites===
+Several minerals and mineral-like materials reversibly bind CO<sub>2</sub>.<ref>Sunho Choi, Jeffrey H. Drese, and Christopher W. Jones "Adsorbent Materials for Carbon Dioxide Capture from Large Anthropogenic Point Sources" ChemSusChem 2009, 2, 796 – 854. {{DOI|10.1002/cssc.200900036}}</ref>  Most often, these minerals are oxides, and often the CO<sub>2</sub> is bound as carbonate. Carbon dioxide reacts with [[quicklime]] (calcium oxide), to form [[limestone]] ([[calcium carbonate]]).<ref>{{cite web|url=http://www.sciencedaily.com/releases/2002/04/020412080812.htm|title=Imagine No Restrictions On Fossil-Fuel Usage And No Global Warming|publisher=ScienceDaily|date=April 15, 2002}}</ref> The process is called Carbonate Looping. Other minerals include [[serpentinite]], a [[magnesium]] [[silicate]] [[hydroxide]] and [[olivine]].<ref>{{cite web|url=http://www.sciencedaily.com/releases/2004/09/040903084832.htm |title=Natural Mineral Locks Up Carbon Dioxide |publisher=Sciencedaily.com |date=2004-09-03 |accessdate=2011-06-01}}</ref><ref>[http://www.tececo.com/sustainability.tececo_kiln.php ]{{dead link|date=June 2011}}</ref>   [[Molecular sieve]]s also function in this capacity.
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+Various scrubbing processes have been proposed to remove CO<sub>2</sub> from the air, or from flue gases.  These usually involve using a variant of the [[Kraft process]]. Scrubbing processes may be based on [[sodium hydroxide]].<ref name="ChangNYT2008">{{cite news | first=Kenneth | last=Chang | coauthors= |authorlink= | title=Scientists would turn greenhouse gas into gasoline | date=2008-02-19 | publisher= | url =http://www.nytimes.com/2008/02/19/science/19carb.html | work =New York Times | pages = | accessdate = 2009-10-29 | language = }}</ref><ref>{{cite web|url=http://www.newscientist.com/article/dn12727 |title=Chemical 'sponge' could filter CO2 from the air - environment - 03 October 2007 |publisher=New Scientist |date= |accessdate=2009-10-29}}</ref>  The CO<sub>2</sub> is absorbed into solution, transferred to lime via a process called causticization and released in a [[kiln]]. With some modifications to the existing processes, mainly an oxygen-fired kiln, the end result is a concentrated stream of CO<sub>2</sub> ready for storage or use in fuels. An alternative to this thermo-chemical process is an electrical one in which a nominal voltage is applied across the carbonate solution to release the CO<sub>2</sub>. While simpler, this electrical process consumes more energy as it splits water at the same time. Since it depends on electricity, the electricity needs to be renewable, like PV. Otherwise the CO<sub>2</sub> produced during electricity production has to be taken into account.  Early incarnations of air capture used electricity as the energy source; hence, were dependent on a carbon-free source. Thermal air capture systems use heat generated on-site, which reduces the inefficiencies associated with off-site electricity production, but of course it still needs a source of (carbon-free) heat. [[Concentrated solar power]] is an example of such a source.<ref name="newscientist1">{{cite web|url=http://www.newscientist.com/article/mg20126901.200-can-technology-clear-the-air.html?full=true |title=Can technology clear the air? - environment - 12 January 2009 |publisher=[[New Scientist]] |date=2009-01-12 |accessdate=2009-10-29}}</ref>
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-== Nike Shox AMC ==
+====Sodium hydroxide====
+Zeman and Lackner outlined a specific method of air capture.<ref name="naoh-zeman">{{cite journal |author1=Zeman, F. S. |author2=Lackner, K. S. |title=Capturing carbon dioxide directly from the atmosphere |journal=World Resour. Rev. |volume=16 |pages=157–72 |year=2004}}</ref>
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+First, CO<sub>2</sub> is absorbed by an alkaline NaOH solution to produce dissolved sodium carbonate. The absorption reaction is a gas liquid reaction, strongly exothermic, (below)
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+:2NaOH(aq) + CO<sub>2</sub>(g) → Na<sub>2</sub>CO<sub>3</sub>(aq) + H<sub>2</sub>O(l)
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+:Na<sub>2</sub>CO<sub>3</sub>(aq) + Ca(OH)<sub>2</sub>(s) →-> 2NaOH(aq) + CaCO<sub>3</sub>(s)
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+:ΔH° = -5.3 kJ/mol
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+Causticization is performed ubiquitously in the [[pulp and paper industry]] and readily transfers 94% of the carbonate ions from the sodium to the calcium cation.<ref name="naoh-zeman"/><!-- is this it??? --> Subsequently, the calcium carbonate precipitate is filtered from solution and thermally decomposed to produce gaseous CO<sub>2</sub>. The calcination reaction is the only endothermic reaction in the process and is shown (below).
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+:CaCO<sub>3</sub>(s) → CaO(s) + CO<sub>2</sub>(g)
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+:ΔH° = + 179.2 kJ/mol
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+:CaO(s) + H<sub>2</sub>O(l) → Ca(OH)<sub>2</sub>(s)
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+:ΔH° = -64.5 kJ/mol
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+====Lithium hydroxide====
+Other strong [[base (chemistry)|bases]] such as [[soda lime]], [[sodium hydroxide]], [[potassium hydroxide]], and [[lithium hydroxide]] are able to remove carbon dioxide by [[chemically reacting]] with it. In particular, [[lithium hydroxide]] is used aboard [[spacecraft]] to remove carbon dioxide from the atmosphere. It reacts with carbon dioxide to make [[lithium carbonate]]:<ref>{{cite journal |last=Jaunsen |first=JR |title=The Behavior and Capabilities of Lithium Hydroxide Carbon Dioxide Scrubbers in a Deep Sea Environment |journal=US Naval Academy Technical Report |volume=USNA-TSPR-157 |year=1989 |url=http://archive.rubicon-foundation.org/4998 |accessdate=2008-06-17 }}</ref>
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+:2 LiOH(s) + 2 H<sub>2</sub>O(g) &rarr; 2 LiOH.H<sub>2</sub>O(s)
+:2 LiOH.H<sub>2</sub>O(s) + CO<sub>2</sub>(g) &rarr; Li<sub>2</sub>CO<sub>3</sub>(s) + 3 H<sub>2</sub>O(g)
-   <li>[http://onlyirishschools.com/index.php?page=item&id=491490 http://onlyirishschools.com/index.php?page=item&id=491490]</li>
+The net reaction being:
-   <li>[http://grhdx.site02.51eway.com/news/html/?426025.html http://grhdx.site02.51eway.com/news/html/?426025.html]</li>
+:2 LiOH(s) + CO<sub>2</sub>(g) &rarr; Li<sub>2</sub>CO<sub>3</sub>(s) + H<sub>2</sub>O(g)
-   <li>[http://www.muzykadawna.com/forum/profile.php?id=94482 http://www.muzykadawna.com/forum/profile.php?id=94482]</li>
+[[Lithium peroxide]] can also be used as it absorbs more CO<sub>2</sub> per unit weight with the added advantage of releasing oxygen.<ref>{{cite doi | 10.1002/14356007.a04_011.pub2}}</ref> This is useful for breathing air systems and was used to remove CO<sub>2</sub> from the Apollo spacecraft.
-   <li>[http://verdamilio.info/org/spip.php?article573/ http://verdamilio.info/org/spip.php?article573/]</li>
+===Regenerative carbon dioxide removal system===
-   <li>[http://elec.newroomschat.com/spip.php?article30/ http://elec.newroomschat.com/spip.php?article30/]</li>
+The regenerative carbon dioxide removal system (RCRS) on the [[space shuttle]] orbiter used a two-bed system that provided continuous removal of carbon dioxide without expendable products. Regenerable systems allowed a shuttle mission a longer stay in space without having to replenish its [[sorbent]] canisters. Older [[lithium hydroxide]] (LiOH)-based systems, which are non-regenerable, were replaced by regenerable [[metal]]-[[oxide]]-based systems. A system based on metal oxide primarily consisted of a metal oxide sorbent canister and a regenerator assembly. It worked by removing carbon dioxide using a sorbent material and then regenerating the sorbent material. The metal-oxide sorbent canister was regenerated by pumping air at approximately {{convert|400|°F|°C|abbr=on}} through it at a standard{{clarify|Which standard? This matters. See [[volumetric flow rate]]|date=November 2012}} flow rate of {{convert|7.5|cuft/min|m3/s|abbr=on}} for 10 hours.<ref>{{cite web|url=http://www.hamiltonsundstrand.com/hsc/proddesc_display/0,4494,CLI1_DIV25_ETI5338_PRD776,00.html|archiveurl=http://web.archive.org/web/20071031085108/http://www.hamiltonsundstrand.com/hsc/proddesc_display/0,4494,CLI1_DIV25_ETI5338_PRD776,00.html|archivedate=2007-10-31|accessdate=2008-10-27|title= Carbon Dioxide Removal|publisher=Hamilton Sundstrand|quote= The new metal-oxide-based system replaces the existing non-regenerable lithium hydroxide (LiOH) carbon dioxide (CO2) removal system located in the EMU’s Primary Life Support System.}}</ref>
- </ul>
+===Activated carbon===
+[[Activated carbon]] can be used as a carbon dioxide scrubber. Air with high carbon dioxide content, such as air from fruit storage locations, can be blown through beds of activated carbon and the carbon dioxide will adsorb onto the activated carbon. Once the bed is [[saturation (chemistry)|saturated]] it must then be "regenerated" by blowing low carbon dioxide air, such as ambient air, through the bed. This will release the carbon dioxide from the bed, and it can then be used to scrub again, leaving the net amount of carbon dioxide in the air the same as when the process was started.
+===Other methods===
+Many other methods and materials have been discussed for scrubbing carbon dioxide.
+* [[Adsorption]]<ref>{{cite web|url=http://www.netl.doe.gov/publications/proceedings/01/carbon_seq/3b3.pdf |title=Adsorption and Desorption of CO2 on Solid Sorbents |format=PDF |date= |accessdate=2011-06-01}}</ref>
+* [[Regenerative carbon dioxide removal system]] (RCRS)
+* Photosynthesis: e.g. Algae based [[carbon sink]]
+* [[Polymer membrane gas separator]]s<ref>[http://www.medal.airliquide.com/en/membranes/carbon/index.asp ]{{dead link|date=June 2011}}</ref><ref>[http://www.medal.airliquide.com/en/membranes/carbon/coal.asp ]{{dead link|date=June 2011}}</ref>
+* Reversing [[heat exchanger]]s
+==See also==
+*[[Breath]]
+*[[Carbon capture and storage]]
+*[[Carbon dioxide air capture]]
+*[[Greenhouse gas]]
+*[[Rebreather]]
+==References==
+{{Reflist}}
+{{Underwater breathing apparatus}}
+[[Category:Scrubbers]]
+[[Category:Carbon dioxide]]
+[[Category:Space suit components]]
+[[Category:Spacecraft life support systems]]
+[[Category:Rebreathers]]

Erdős–Diophantine graph: Difference between revisions

Latest revision as of 20:35, 20 April 2013

Contents

Technologies

Amine scrubbing

Minerals and zeolites

Sodium hydroxide

Lithium hydroxide

Regenerative carbon dioxide removal system

Activated carbon

Other methods

See also

References

Navigation menu

Erdős–Diophantine graph: Difference between revisions

Latest revision as of 20:35, 20 April 2013

Technologies

Amine scrubbing

Minerals and zeolites

Sodium hydroxide

Lithium hydroxide

Regenerative carbon dioxide removal system

Activated carbon

Other methods

See also

References

Navigation menu

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