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In [[statistical mechanics]], the '''hard hexagon model''' is a 2-dimensional [[Lattice model (physics)|lattice model]] of a gas, where particles are allowed to be on the vertices of a [[hexagonal lattice|triangular lattice]] but no two particles may be adjacent.  


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The model was solved by {{harvs|authorlink=Rodney J. Baxter|last=Baxter|year=1980|txt}}, who found that it was related to the [[Rogers-Ramanujan identities]].
 
==The partition function of the hard hexagon model==
 
For a triangular lattice with ''N'' sites, the [[grand partition function]] is
 
:<math>\displaystyle \mathcal Z(z) = \sum_n z^n g(n,N) = 1+Nz+ \tfrac{1}{2}N(N-7)z^2+\cdots</math>
 
where ''g''(''n'', ''N'') is the number of ways of placing ''n'' particles on distinct lattice sites such that no 2 are adjacent. The variable ''z'' is called the '''activity''' and larger values correspond roughly to denser configurations. The function &kappa; is defined by
 
:<math>\kappa(z) = \lim_{N\rightarrow\infty} \mathcal Z(z)^{1/N} = 1+z-3z^2+\cdots</math>
 
so that log(&kappa;) is the free energy per unit site. Solving the hard hexagon model means (roughly) finding an exact expression for &kappa; as a function of ''z''.
 
The '''mean density''' &rho; is given for small ''z'' by
 
:<math>\rho= z\frac{d\log(\kappa)}{dz}  =z-7z^2+58z^3-519z^4+4856z^5+\cdots.</math>
 
The vertices of the lattice fall into 3 classes numbered 1, 2, and 3, given by the 3 different ways to fill space with hard hexagons. There are 3 local densities &rho;<sub>1</sub>, &rho;<sub>2</sub>, &rho;<sub>3</sub>, corresponding to the 3 classes of sites. When the activity is large the system approximates one of these 3 packings, so the local densities differ, but when the activity is below a critical point the three local densities are the same. The critical point  separating the low-activity homogeneous phase from the high-activity ordered phase is ''z''<sub>''c''</sub> = (11&nbsp;+&nbsp;5<sup>3/2</sup>)/2 = 11.0917.... Above the critical point the local densities  differ and in the phase where most hexagons are on sites of type 1 can be expanded as  
 
:<math> \rho_1 = 1-z^{-1}-5z^{-2}-34z^{-3}-267z^{-4}-2037z^{-5}-\cdots</math>
:<math> \rho_2=\rho_3 = z^{-2} + 9z^{-3} + 80z^{-4} +  965z^{-5}-\cdots.</math>
 
==Solution==
The solution is given for small values of ''z''&nbsp;<&nbsp;''z''<sub>''c''</sub> by
 
:<math>\displaystyle z=\frac{-xH(x)^5}{G(x)^5}</math>
 
:<math>
\kappa = \frac{H(x)^3 Q(x^5)^2} {G(x)^2}
\prod_{n\ge 1} \frac{(1-x^{6n-4})(1-x^{6n-3})^2(1-x^{6n-2})}
{(1-x^{6n-5})(1-x^{6n-1})(1-x^{6n})^2}
</math>
 
:<math>\rho =\rho_1=\rho_2=\rho_3= \frac{-xG(x)H(x^6)P(x^3)}{P(x)}</math>
 
where
:<math>G(x) = \prod_{n\ge 1}\frac{1}{(1-x^{5n-4})(1-x^{5n-1})}</math>
 
:<math>H(x) = \prod_{n\ge 1}\frac{1}{(1-x^{5n-3})(1-x^{5n-2})}</math>
 
:<math>P(x) = \prod_{n\ge 1}(1-x^{2n-1}) = Q(x)/Q(x^2)</math>
 
:<math>Q(x) = \prod_{n\ge 1}(1-x^n).</math>
 
For large ''z''&nbsp;>&nbsp;''z''<sub>''c''</sub> the solution (in the phase where most occupied sites have type 1) is given by
:<math>\displaystyle z=\frac{G(x)^5}{xH(x)^5}</math>
 
:<math>
\kappa = \frac{G(x)^3 Q(x^5)^2} {H(x)^2}
\prod_{n\ge 1} \frac{(1-x^{3n-2})(1-x^{3n-1})}
{(1-x^{3n})^2}
</math>
 
:<math>\rho_1 = \frac{H(x)Q(x)(G(x)Q(x)+x^2H(x^9)Q(x^9))}{Q(x^3)^2}</math>
 
:<math>\rho_2=\rho_3 = \frac{x^2H(x)Q(x)H(x^9)Q(x^9)}{Q(x^3)^2}</math>
 
:<math>R=\rho_1-\rho_2= \frac{Q(x)Q(x^5)}{Q(x^3)^2}.</math>
 
The functions ''G'' and ''H'' turn up in the [[Rogers-Ramanujan identities]], and the function ''Q'' is closely related to the [[Dedekind eta function]]. If ''x'' = e<sup>2&pi;i&tau;</sup>, then ''q''<sup>&minus;1/60</sup>''G''(''x''), ''x''<sup>11/60</sup>''H''(''x''), ''x''<sup>&minus;1/24</sup>''P''(''x''), ''z'', &kappa;, &rho;, &rho;<sub>1</sub>,  &rho;<sub>2</sub>, and &rho;<sub>3</sub> are [[modular function]]s of &tau;, while ''x''<sup>1/24</sup>''Q''(''x'') is a modular form of weight 1/2. Since any two modular functions are related by an algebraic relation, this implies that the functions ''&kappa;'', ''z'', ''R'', ''&rho;'' are all algebraic functions of each other (of quite high degree) {{harv|Joyce|1988}}.
 
==References==
*{{Citation | doi=10.1073/pnas.78.9.5290 | authorlink=George E. Andrews | last1=Andrews | first1=George E. | title=The hard-hexagon model and Rogers-Ramanujan type identities | url=http://www.pnas.org/content/78/9/5290.abstract?ck=nck | id={{MathSciNet | id = 629656}} | year=1981 | journal=[[Proceedings of the National Academy of Sciences|Proceedings of the National Academy of Sciences of the United States of America]] | issn=0027-8424 | volume=78 | issue=9 | pages=5290&ndash;5292 | pmid=16593082 | pmc=348728}}
*{{Citation | last1=Baxter | first1=Rodney J. | title=Hard hexagons: exact solution | doi=10.1088/0305-4470/13/3/007  | id={{MathSciNet | id = 560533}} | year=1980 | journal=Journal of Physics. A. Mathematical and General | issn=0305-4470 | volume=13 | issue=3 | pages=L61&ndash;L70}}
*{{Citation | last1=Baxter | first1=Rodney J. | title=Exactly solved models in statistical mechanics | url=http://physics.anu.edu.au/theophys/_files/Exactly.pdf| publisher=Academic Press Inc. [Harcourt Brace Jovanovich Publishers] | location=London | isbn=978-0-12-083180-7 | id={{MathSciNet | id = 690578}} | year=1982}}
*{{Citation | last1=Joyce | first1=G. S. | title=Exact results for the activity and isothermal compressibility of the hard-hexagon model | doi=10.1088/0305-4470/21/20/005  | id={{MathSciNet | id = 966792}} | year=1988 | journal=Journal of Physics. A. Mathematical and General | issn=0305-4470 | volume=21 | issue=20 | pages=L983&ndash;L988}}
 
==External links==
*{{mathworld|urlname=HardHexagonEntropyConstant|title=Hard Hexagon  Entropy Constant}}
 
[[Category:Exactly solvable models]]
[[Category:Statistical mechanics]]
[[Category:Lattice models]]
[[Category:Modular forms]]

Revision as of 11:36, 15 January 2014

In statistical mechanics, the hard hexagon model is a 2-dimensional lattice model of a gas, where particles are allowed to be on the vertices of a triangular lattice but no two particles may be adjacent.

The model was solved by Template:Harvs, who found that it was related to the Rogers-Ramanujan identities.

The partition function of the hard hexagon model

For a triangular lattice with N sites, the grand partition function is

𝒵(z)=nzng(n,N)=1+Nz+12N(N7)z2+

where g(n, N) is the number of ways of placing n particles on distinct lattice sites such that no 2 are adjacent. The variable z is called the activity and larger values correspond roughly to denser configurations. The function κ is defined by

κ(z)=limN𝒵(z)1/N=1+z3z2+

so that log(κ) is the free energy per unit site. Solving the hard hexagon model means (roughly) finding an exact expression for κ as a function of z.

The mean density ρ is given for small z by

ρ=zdlog(κ)dz=z7z2+58z3519z4+4856z5+.

The vertices of the lattice fall into 3 classes numbered 1, 2, and 3, given by the 3 different ways to fill space with hard hexagons. There are 3 local densities ρ1, ρ2, ρ3, corresponding to the 3 classes of sites. When the activity is large the system approximates one of these 3 packings, so the local densities differ, but when the activity is below a critical point the three local densities are the same. The critical point separating the low-activity homogeneous phase from the high-activity ordered phase is zc = (11 + 53/2)/2 = 11.0917.... Above the critical point the local densities differ and in the phase where most hexagons are on sites of type 1 can be expanded as

ρ1=1z15z234z3267z42037z5
ρ2=ρ3=z2+9z3+80z4+965z5.

Solution

The solution is given for small values of z < zc by

z=xH(x)5G(x)5
κ=H(x)3Q(x5)2G(x)2n1(1x6n4)(1x6n3)2(1x6n2)(1x6n5)(1x6n1)(1x6n)2
ρ=ρ1=ρ2=ρ3=xG(x)H(x6)P(x3)P(x)

where

G(x)=n11(1x5n4)(1x5n1)
H(x)=n11(1x5n3)(1x5n2)
P(x)=n1(1x2n1)=Q(x)/Q(x2)
Q(x)=n1(1xn).

For large z > zc the solution (in the phase where most occupied sites have type 1) is given by

z=G(x)5xH(x)5
κ=G(x)3Q(x5)2H(x)2n1(1x3n2)(1x3n1)(1x3n)2
ρ1=H(x)Q(x)(G(x)Q(x)+x2H(x9)Q(x9))Q(x3)2
ρ2=ρ3=x2H(x)Q(x)H(x9)Q(x9)Q(x3)2
R=ρ1ρ2=Q(x)Q(x5)Q(x3)2.

The functions G and H turn up in the Rogers-Ramanujan identities, and the function Q is closely related to the Dedekind eta function. If x = e2πiτ, then q−1/60G(x), x11/60H(x), x−1/24P(x), z, κ, ρ, ρ1, ρ2, and ρ3 are modular functions of τ, while x1/24Q(x) is a modular form of weight 1/2. Since any two modular functions are related by an algebraic relation, this implies that the functions κ, z, R, ρ are all algebraic functions of each other (of quite high degree) Template:Harv.

References

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    In case you are in search of an actual estate or Singapore property agent on-line, you simply should belief your intuition. It's because you do not know which agent is nice and which agent will not be. Carry out research on several brokers by looking out the internet. As soon as if you end up positive that a selected agent is dependable and reliable, you can choose to utilize his partnerise in finding you a home in Singapore. Most of the time, a property agent is taken into account to be good if he or she locations the contact data on his website. This may mean that the agent does not mind you calling them and asking them any questions relating to new properties in singapore in Singapore. After chatting with them you too can see them in their office after taking an appointment.

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    Once you place down the one per cent choice price to carry down a non-public property, it's important to accept its situation as it is whenever you move in – faulty air-con, choked rest room and all. Get round this by asking your agent to incorporate a ultimate inspection clause within the possibility-to-buy letter. HDB flat patrons routinely take pleasure in this security net. "There's a ultimate inspection of the property two days before the completion of all HDB transactions. If the air-con is defective, you can request the seller to repair it," says Kelvin.

    15.6.1 As the agent is an intermediary, generally, as soon as the principal and third party are introduced right into a contractual relationship, the agent drops out of the image, subject to any problems with remuneration or indemnification that he could have against the principal, and extra exceptionally, against the third occasion. Generally, agents are entitled to be indemnified for all liabilities reasonably incurred within the execution of the brokers´ authority.

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