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The '''Kramers-Heisenberg dispersion formula''' is an expression for the [[cross section (physics)|cross section]] for [[scattering]] of a [[photon]] by an [[atom]]ic [[electron]]. It was derived before the advent of [[quantum mechanics]] by [[Hendrik Anthony Kramers|Hendrik Kramers]] and [[Werner Heisenberg]] in 1925,<ref name=KH>{{cite journal
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  | last = Kramers
  | first = H. A.
  | authorlink = Hendrik Anthony Kramers
  | last2 = Heisenberg
  | first2 = W.
  | author2-link = Werner Heisenberg
  | title = Über die Streuung von Strahlung durch Atome
  | journal = Z. Phys.
  | volume = 31
  | issue = 1
  | pages = 681–708
  | date = Feb 1925
  | url = http://www.springerlink.com/content/x2x7220805540747
  | doi = 10.1007/BF02980624
|bibcode = 1925ZPhy...31..681K }}</ref> based on the [[correspondence principle]] applied to the classical dispersion formula for light. The quantum mechanical derivation was given by [[Paul Dirac]] in 1927.<ref>{{cite journal
  | last = Dirac.
  | first = P. A. M.
  | authorlink = Paul Dirac
  | title = The Quantum Theory of the Emission and Absorption of Radiation
  | journal = Proc. Roy. Soc. Lond. A
  | volume = 114
  | issue = 769
  | pages = 243–265
  | year = 1927
  | doi = 10.1098/rspa.1927.0039
|bibcode = 1927RSPSA.114..243D }}</ref><ref>{{cite journal
  | last = Dirac.
  | first = P. A. M.
  | authorlink = Paul Dirac
  | title = The Quantum Theory of Dispersion
  | journal = Proc. Roy. Soc. Lond. A
  | volume = 114
  | issue = 769
  | pages = 710–728
  | year = 1927
  | doi = 10.1098/rspa.1927.0071
|bibcode = 1927RSPSA.114..710D }}</ref>
 
The Kramers–Heisenberg formula was an important achievement when it was published, explaining the notion of "negative absorption" ([[stimulated emission]]), the Thomas-Reiche-Kuhn sum rule, and [[inelastic scattering]] - where the [[energy]] of the scattered photon may be larger or smaller than that of the incident photon - thereby anticipating the [[Raman effect]].<ref>{{Cite journal
  | last = Breit
  | first = G.
  | title = Quantum Theory of Dispersion
  | journal = Rev. Mod. Phys.
  | volume = 4
  | issue = 3
  | pages = 504–576
  | year = 1932
  | url = http://link.aps.org/doi/10.1103/RevModPhys.4.504
  | doi = 10.1103/RevModPhys.4.504
|bibcode = 1932RvMP....4..504B }}</ref>
 
== Equation ==
The Kramers-Heisenberg (KH) formula for second order processes is <ref name=KH/><ref>J.J. Sakurai, Advanced Quantum Mechanics, Addison-Wesley (1967), page
56.</ref><BR>
<math> \frac{d^2 \sigma}{d\Omega_{k^\prime}d(\hbar \omega_k^\prime)}=\frac{\omega_k^\prime}{\omega_k}\sum_{|f\rangle}\left | \sum_{|n\rangle} \frac{\langle f | T^\dagger | n \rangle \langle n | T | i \rangle}{E_i - E_n + \hbar \omega_k + i \frac{\Gamma_n}{2}}\right |^2 \delta (E_i - E_f + \hbar \omega_k - \hbar \omega_k^\prime)</math>
 
It represents the probability of the emission of photons of energy <math> \hbar \omega_k^\prime </math> in the
solid angle <math>d\Omega_{k^\prime}</math> (centred in the <math>k^\prime</math> direction), after the excitation of the system with photons of energy <math> \hbar \omega_k</math>. <math>|i\rangle, |n\rangle, |f\rangle</math> are the initial, intermediate
and final states of the system with energy <math>E_i , E_n , E_f</math> respectively; the delta
function ensures the energy conservation during the whole process. <math>T</math> is the relevant
transition operator. <math>\Gamma_n </math> is the instrinsic linewidth of the intermediate state.
 
== References ==
<references />
 
{{DEFAULTSORT:Kramers-Heisenberg formula}}
[[Category:Particle physics]]
 
 
{{physics-stub}}

Latest revision as of 10:40, 7 February 2014

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