Problem of points: Difference between revisions

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<!-- To obtain a blank version of this page, type subst:chembox supplement inside of double curly braces, {{}}, and save the page -->
The author's title is Christy Brookins. Office supervising is exactly where her primary earnings comes from but she's already applied for an additional one. Mississippi is where her home is but her spouse desires them to transfer. What me and my family members love is to climb but I'm considering on starting something new.<br><br>Also visit my blog post [http://formalarmour.com/index.php?do=/profile-26947/info/ are psychics real]
 
This page provides supplementary chemical data on [[propan-1-ol|''n''-propanol]]. <!-- replace with proper wikilink -->
 
== Material Safety Data Sheet == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
 
The handling of this chemical may incur notable safety precautions. It is highly recommended that you seek the Material Safety Datasheet ([[Material safety data sheet|MSDS]]) for this chemical from a reliable source  such as [http://www2.siri.org/msds/index.php SIRI], and follow its directions. MSDS for '''propan-1-ol''' is available from [http://hazard.com/msds/mf/baker/baker/files/p6390.htm Mallinckrodt Baker].
 
== Structure and properties == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
 
{| border="1" cellspacing="0" cellpadding="3" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
! {{chembox header}} | Structure and properties
|-
| [[Index of refraction]], ''n''<sub>D</sub>
| 1.383 at 25°C <!-- Please omit if not applicable -->
|-
| [[Abbe number]]
|? <!-- Please omit if not applicable -->
|-
| [[Dielectric constant]], ε<sub>r</sub>
| 20.1 ε<sub>0</sub> at 25 °C <!-- Please omit if not applicable -->
|-
| [[Bond strength]]
| ? <!-- Specify which bond. Please omit if not applicable -->
|-
| [[Bond length]]
| ? <!-- Specify which bond. Please omit if not applicable -->
|-
| [[Bond angle]]
| ? <!-- Specify which angle, e.g. Cl-P-O. Please omit if not applicable -->
|-
| [[Magnetic susceptibility]]
| ? <!-- Please omit if not applicable -->
|-
| [[Surface tension]]
| 23.78 dyn/cm at 20°C
|-
| [[Viscosity]]<ref name="crcF31">''CRC Handbook of Chemistry and Physics'', 47th ed. p F-31 - F-42</ref>
|
{|
|-
| 3.893 mPa·s || at 0°C
|-
| 2.52 mPa·s || at 15°C
|-
| 2.256 mPa·s || at 20°C
|-
| 1.72 mPa·s || at 30°C
|-
| 1.405 mPa·s || at 40°C
|-
| 1.130 mPa·s || at 50°C
|-
| 0.760 mPa·s || at 70°C
|-
|}
|-
|}
 
== Thermodynamic properties == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
 
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
! {{chembox header}} | Phase behavior
|-
| [[Triple point]]
| 148.75 K (–124.4 °C), ? Pa
|-
| [[Critical point (chemistry)|Critical point]]
| 536.9 K (263.8 °C), 5200 kPa
|-
| [[Standard enthalpy change of fusion|Std enthalpy change<br/>of fusion]], Δ<sub>fus</sub>''H''<sup><s>o</s></sup>
| 5.37 kJ/mol
|-
| [[Standard entropy change of fusion|Std entropy change<br/>of fusion]], Δ<sub>fus</sub>''S''<sup><s>o</s></sup>
| 36 J/(mol·K)
|-
| [[Standard enthalpy change of vaporization|Std enthalpy change<br/>of vaporization]], Δ<sub>vap</sub>''H''<sup><s>o</s></sup>
| 47.5 kJ/mol
|-
| [[Standard entropy change of vaporization|Std entropy change<br/>of vaporization]], Δ<sub>vap</sub>''S''<sup><s>o</s></sup>
| ? J/(mol·K)
|-
! {{chembox header}} | Solid properties
|-
| [[Standard enthalpy change of formation|Std enthalpy change<br/>of formation]], Δ<sub>f</sub>''H''<sup><s>o</s></sup><sub>solid</sub>
| ? kJ/mol
|-
| [[Standard molar entropy]],<br/>''S''<sup><s>o</s></sup><sub>solid</sub>
| 112.7 J/(mol K)
|-
| [[Heat capacity]], ''c<sub>p</sub>''
| 106.3 J/(mol K) at –123°C
|-
! {{chembox header}} | Liquid properties
|-
| [[Standard enthalpy change of formation|Std enthalpy change<br/>of formation]], Δ<sub>f</sub>''H''<sup><s>o</s></sup><sub>liquid</sub>
| –303.0 kJ/mol
|-
| [[Standard molar entropy]],<br/>''S''<sup><s>o</s></sup><sub>liquid</sub>
| 192.8 J/(mol K)
|-
| [[Enthalpy of combustion]], Δ<sub>c</sub>''H''<sup><s>o</s></sup>
| –2021 kJ/mol
|-
| [[Heat capacity]], ''c<sub>p</sub>''
| 144.4 J/(mol K)
|-
! {{chembox header}} | Gas properties
|-
| [[Standard enthalpy change of formation|Std enthalpy change<br/>of formation]], Δ<sub>f</sub>''H''<sup><s>o</s></sup><sub>gas</sub>
| –255 kJ/mol
|-
| [[Standard molar entropy]],<br/>''S''<sup><s>o</s></sup><sub>gas</sub>
| 322.49 J/(mol K)
|-
| [[Heat capacity]], ''c<sub>p</sub>''
| 85.56 J/(mol K) at 25°
|-
| [[van der Waals equation|van der Waals' constants]]<ref name="crcD104">''CRC Handbook of Chemistry and Physics'' 47th ed, p D-104</ref>
| a = 1512 L<sup>2</sup> kPa/mol<sup>2</sup><br> b = 0.1029 liter per mole
|-
|}
 
==Vapor pressure of liquid==
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|-
| {{chembox header}} | '''P in mm Hg''' || 1 || 10 || 40 || 100 || 400 || 760 || 1520 || 3800 || 7600 || 15200 || 30400 || 45600
|-
| {{chembox header}} | '''T in °C''' || –15.0 || 14.7 || 36.4 || 52.8 || 82.0 || 97.8 || 117.0 || 149.0 || 177.0 || 210.8 || 250.0 || &nbsp;—
|}
Table data obtained from ''CRC Handbook of Chemistry and Physics'' 44th ed.
 
[[Image:logNpropanolVaporPressure.png|thumb|713px|left|'''log<sub>10</sub> of ''n''-propanol vapor pressure.''' Uses formula: <math>\scriptstyle \log_e P_{mmHg} =</math><math>\scriptstyle \log_e (\frac {760} {101.325}) - 7.702226 \log_e(T+273.15) - \frac {8002.693} {T+273.15} + 71.71697 + 3.950448 \times 10^{-07} (T+273.15)^2</math> obtained from CHERIC<ref name="cheric_p">{{Cite web|url=http://www.cheric.org/research/kdb/hcprop/cmpsrch.php|title=Pure Component Properties|publisher=Chemical Engineering Research Information Center|accessdate=19 May 2007|format=Queriable database}}</ref>]]{{Clear}}
 
==Distillation data==
{|
|- valign="top"
|
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|-
| bgcolor="#D0D0D0" align="center" colspan="3"| '''Vapor-liquid Equilibrium<br>for ''n''-propanol/Water'''<ref name="cheric_b">{{Cite web|url=http://www.cheric.org/research/kdb/hcvle/hcvle.php|title=Binary Vapor-Liquid Equilibrium Data|publisher=Chemical Engineering Research Information Center|format=Queriable database|accessdate=19 May 2007}}</ref><br>''P'' = 100 kPa
|- {{chembox header}}
! rowspan="2" | BP<br>Temp.<br>°C
! colspan="2" | % by mole water
|- {{chembox header}}
! liquid !! vapor
|-
| 96.60 || 0.00 || 0.00
|-
| 96.25 || 1.3 || 2.5
|-
| 94.69 || 3.8 || 9.7
|-
| 92.92 || 8.3 || 19.4
|-
| 90.64 || 16.0 || 31.7
|-
| 89.31 || 22.6 || 39.0
|-
| 88.48 || 28.3 || 43.7
|-
| 87.67 || 35.6 || 48.7
|-
| 87.32 || 42.6 || 52.2
|-
| 87.18 || 50.0 || 55.0
|-
| 87.13 || 58.3 || 57.2
|-
| 87.12 || 64.8 || 58.5
|-
| 87.17 || 70.8 || 59.5
|-
| 87.29 || 76.3 || 60.3
|-
| 87.47 || 81.7 || 60.8
|-
| 87.63 || 85.3 || 61.3
|-
| 87.78 || 88.3 || 61.9
|-
| 87.97 || 91.1 || 62.7
|-
| 88.28 || 92.6 || 63.2
|-
| 88.62 || 94.5 || 64.3
|-
| 89.26 || 95.7 || 66.3
|-
| 90.15 || 96.7 || 68.3
|-
| 91.91 || 97.8 || 73.9
|-
| 93.72 || 98.5 || 79.4
|-
| 95.56 || 99.1 || 85.4
|-
| 97.08 || 99.6 || 90.5
|-
| 98.80 || 99.9 || 98.4
|-
| 99.63 || 100.0 || 100.0
|-
|}
| &nbsp; &nbsp;
|
{|
|-
|
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|-
| bgcolor="#D0D0D0" align="center" colspan="3"| '''Vapor-liquid Equilibrium<br>for ''n''-propanol/[[Methanol]]'''<ref name="cheric_b"/><br>''P'' = 760&nbsp;mm Hg
|- {{chembox header}}
! rowspan="2" | BP<br>Temp.<br>°C
! colspan="2" | % by mole methanol
|- {{chembox header}}
! liquid !! vapor
|-
| 92.30 || 9.2 || 23.5
|-
| 88.88 || 18.0 || 41.2
|-
| 83.90 || 28.0 || 56.2
|-
| 82.53 || 32.0 || 61.0
|-
| 80.25 || 38.0 || 67.5
|-
| 78.15 || 45.9 || 75.3
|-
| 74.46 || 58.1 || 83.2
|-
| 74.42 || 58.3 || 83.5
|-
| 71.28 || 68.0 || 88.8
|-
| 69.40 || 76.4 || 92.8
|-
| 68.30 || 82.2 || 94.0
|-
| 67.08 || 86.2 || 95.5
|-
|}
|-
| &nbsp;
|-
|
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|-
| bgcolor="#D0D0D0" align="center" colspan="3"| '''Vapor-liquid Equilibrium<br>for ''n''-propanol/[[Butanone]]'''<ref name="cheric_b"/><br>''P'' = 760&nbsp;mm Hg
|- {{chembox header}}
! rowspan="2" | BP<br>Temp.<br>°C
! colspan="2" | % by mole butanone
|- {{chembox header}}
! liquid !! vapor
|-
| 94.8 || 5.4 || 12.5
|-
| 93.0 || 9.3 || 20.6
|-
| 91.8 || 12.8 || 27.1
|-
| 90.3 || 17.1 || 33.7
|-
| 88.9 || 23.5 || 41.3
|-
| 87.7 || 28.4 || 46.9
|-
| 86.1 || 36.6 || 54.7
|-
| 84.9 || 44.0 || 60.5
|-
| 83.8 || 53.3 || 67.7
|-
| 83.5 || 57.2 || 70.1
|-
| 82.5 || 64.1 || 74.8
|-
| 81.6 || 73.0 || 81.0
|-
| 81.0 || 80.4 || 85.9
|-
| 80.4 || 87.9 || 90.9
|-
| 79.9 || 94.3 || 95.7
|-
|}
|}
| &nbsp; &nbsp;
|
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|-
| bgcolor="#D0D0D0" align="center" colspan="3"| '''Vapor-liquid Equilibrium<br>for ''n''-propanol/[[Cyclohexane]]'''<ref name="cheric_b"/><br>''P'' = 101.325 kPa
|- {{chembox header}}
! rowspan="2" | BP<br>Temp.<br>°C
! colspan="2" | % by mole cyclohexane
|- {{chembox header}}
! liquid !! vapor
|-
| 80.42 || 100 || 100
|-
| 77.42 || 96.46 || 88.36
|-
| 76.40 || 95.27 || 85.29
|-
| 75.71 || 93.97 || 83.35
|-
| 75.18 || 91.59 || 80.91
|-
| 74.92 || 89.52 || 79.43
|-
| 74.59 || 86.19 || 77.89
|-
| 74.40 || 80.52 || 76.29
|-
| 74.33 || 78.11 || 75.69
|-
| 74.29 || 75.91 || 75.13
|-
| 74.27 || 74.19 || 74.75
|-
| 74.28 || 71.43 || 74.30
|-
| 74.33 || 68.00 || 73.70
|-
| 74.43 || 64.26 || 72.87
|-
| 74.49 || 61.21 || 72.20
|-
| 74.77 || 54.09 || 70.71
|-
| 75.23 || 48.00 || 69.53
|-
| 75.59 || 41.10 || 67.48
|-
| 76.78 || 33.29 || 64.73
|-
| 77.72 || 28.53 || 62.71
|-
| 79.12 || 23.01 || 59.03
|-
| 81.11 || 17.35 || 53.39
|-
| 82.69 || 14.44 || 49.70
|-
| 84.90 || 10.73 || 42.87
|-
| 86.64 || 8.44 || 38.28
|-
| 89.34 || 4.75 || 28.90
|-
| 90.65 || 3.60 || 24.39
|-
| 91.88 || 2.70 || 19.94
|-
| 92.85 || 2.13 || 16.06
|-
| 93.44 || 1.64 || 13.64
|-
| 97.0  || 0.0 || 0.0
|-
|}
| &nbsp; &nbsp;
|
{|
|-
|
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|-
| bgcolor="#D0D0D0" align="center" colspan="3"| '''Vapor-liquid Equilibrium<br>for ''n''-propanol/[[hexane|''n''-Hexane]]'''<ref name="cheric_b"/><br>''P'' = 760&nbsp;mm Hg
|- {{chembox header}}
! rowspan="2" | BP<br>Temp.<br>°C
! colspan="2" | % by mole ''n''-propanol
|- {{chembox header}}
! liquid !! vapor
|-
| 77.70 || 2.3 || 13.6
|-
| 70.05 || 6.0 || 25.7
|-
| 68.25 || 11.7 || 42.4
|-
| 64.70 || 21.0 || 55.8
|-
| 64.10 || 24.6 || 60.0
|-
| 63.90 || 28.6 || 63.7
|-
| 62.25 || 39.8 || 67.2
|-
| 62.20 || 41.7 || 67.2
|-
| 61.90 || 49.3 || 69.1
|-
| 61.55 || 59.3 || 70.6
|-
| 61.60 || 65.7 || 72.0
|-
| 61.65 || 67.3 || 72.5
|-
| 61.60 || 72.8 || 72.7
|-
| 61.80 || 87.2 || 75.8
|-
| 62.50 || 92.3 || 79.9
|-
| 63.90 || 97.5 || 85.6
|-
|}
|-
| &nbsp;
|-
|
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|-
| bgcolor="#D0D0D0" align="center" colspan="3"| '''Vapor-liquid Equilibrium<br>for ''n''-propanol/[[Acetone]]'''<ref name="cheric_b"/><br>''P'' = 760&nbsp;mm Hg
|- {{chembox header}}
! rowspan="2" | BP<br>Temp.<br>°C
! colspan="2" | % by mole acetone
|- {{chembox header}}
! liquid !! vapor
|-
| 86.55 || 10.80 || 40.31
|-
| 78.35 || 24.17 || 63.36
|-
| 72.65 || 35.55 || 74.32
|-
| 68.50 || 47.42 || 81.76
|-
|-
| 65.00 || 60.74 || 87.74
|-
| 62.85 || 71.29 || 91.51
|-
|}
|}
|}
 
== Spectral data == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
 
{| border="1" cellspacing="0" cellpadding="3" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
! {{chembox header}} | [[UV/VIS spectroscopy|UV-Vis]]
|-
| [[Lambda-max|λ<sub>max</sub>]]
| ? [[Nanometre|nm]]
|-
| [[molar absorptivity|Extinction coefficient]], ε
| ?
|-
! {{chembox header}} | [[Infrared|IR]]
|-
| Major absorption bands
| ? [[Centimetre|cm]]<sup>&minus;1</sup>
|-
! {{chembox header}} | [[NMR Spectroscopy|NMR]]
|-
| [[Proton NMR]] <!-- Link to image of spectrum -->
| &nbsp;
|-
| [[Carbon-13 NMR]] <!-- Link to image of spectrum -->
| &nbsp;
|-
| Other NMR data <!-- Insert special data e.g. <sup>19</sup>F chem. shifts, omit if not used -->
| &nbsp;
|-
! {{chembox header}} | [[Mass Spectrometry|MS]]
|-
| Masses of <br>main fragments
| &nbsp; <!-- Give list of major fragments -->
|-
|}
 
==References==
<references/>
* {{Cite web|url=http://webbook.nist.gov/chemistry/|title=NIST Standard Reference Database}}
 
Except where noted otherwise, data relate to [[standard ambient temperature and pressure]].
 
[[wikipedia:Chemical infobox|Disclaimer]] applies.
{{Use dmy dates|date=September 2010}}
 
{{DEFAULTSORT:Propan-1-Ol (Data Page)}}
[[Category:Chemical data pages]]

Revision as of 03:18, 5 March 2014

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