Dimethyl sulfoxide (data page): Difference between revisions

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<!-- To obtain a blank version of this page, type subst:chembox supplement inside of double curly braces, {{}}, and save the page -->
Hi there. Allow me start by introducing the author, her title is Sophia Boon but she never truly favored that name. She works as  psychic solutions by lynne ([http://modenpeople.co.kr/modn/qna/292291 http://modenpeople.co.kr]) a travel agent but quickly she'll be on her personal. For many years he's been residing in Mississippi and he doesn't strategy on changing it. What me and my family adore is bungee leaping but I've been using on new things recently.<br><br>my web page; [http://www.taehyuna.net/xe/?document_srl=78721 love psychic] readers ([http://jplusfn.gaplus.kr/xe/qna/78647 gaplus.kr])
This page provides supplementary chemical data on [[m-Xylene|''m''-Xylene]]. <!-- replace with proper wikilink -->
 
== Material Safety Data Sheet == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
 
The handling of this chemical may incur notable safety precautions. It is highly recommend that you seek the Material Safety Datasheet ([[Material safety data sheet|MSDS]]) for this chemical from a reliable source  such as [http://www2.siri.org/msds/index.php SIRI], and follow its directions. MSDS is available at [https://fscimage.fishersci.com/msds/13240.htm Fisher Scientific].
 
== Structure and properties == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
 
{| border="1" cellspacing="0" cellpadding="3" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
! {{chembox header}} | Structure and properties
|-
| [[Index of refraction]], ''n''<sub>D</sub>
| 1.49722 at 20°C <!-- Please omit if not applicable -->
|-
| [[Abbe number]]
|? <!-- Please omit if not applicable -->
|-
| [[Dielectric constant]],<ref>''CRC Handbook of Chemistry and Physics'', 44th ed. pp 2611-2620</ref> ε<sub>r</sub>
| 2.374 ε<sub>0</sub> at 20°C <!-- Please omit if not applicable -->
|-
| [[Bond strength]]
| ? <!-- Specify which bond. Please omit if not applicable -->
|-
| [[Bond length]]
| ? <!-- Specify which bond. Please omit if not applicable -->
|-
| [[Bond angle]]
| ? <!-- Specify which angle, e.g. Cl-P-O. Please omit if not applicable -->
|-
| [[Magnetic susceptibility]]
| ? <!-- Please omit if not applicable -->
|-
| [[Surface tension]]<ref>''Lange's Handbook of Chemistry'', 10th ed. pp 1661-1663</ref>
| 31.15 dyn/cm at 0°C<br>28.90 dyn/cm at 20°C<br>20.46 dyn/cm at 100°C
|-
| [[Viscosity]]<ref>''Lange's Handbook of Chemistry'', 10th ed. pp 1669-1674</ref>
| 0.8059 mPa·s at 0°C<br>0.6200 mPa·s at 20°C<br>0.4970 mPa·s at 40°C<br>0.3455 mPa·s at 80°C<br>0.2418 mPa·s at 130°C
|-
| [[Solubility]]<ref>''CRC Handbook of Chemistry and Physics'', 85th ed. p 8-111</ref>
| 0.203 g/L at 0°C<br> 0.161 g/L at 25°C<br> 0.22 g/L at 40°C<br>
|-
|}
 
== Thermodynamic properties == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
 
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
! {{chembox header}} | Phase behavior
|-
| [[Triple point]]
| 219.6 K (–53.5 °C), ? Pa
|-
| [[Critical point (chemistry)|Critical point]]
| 618 K (345 °C), ? Pa
|-
| [[Standard enthalpy change of fusion|Std enthalpy change<br/>of fusion]], Δ<sub>fus</sub>''H''<sup><s>o</s></sup>
| 11.57 kJ/mol
|-
| [[Standard entropy change of fusion|Std entropy change<br/>of fusion]], Δ<sub>fus</sub>''S''<sup><s>o</s></sup>
| 51.36 J/(mol·K) at –47.88°C
|-
| [[Standard enthalpy change of vaporization|Std enthalpy change<br/>of vaporization]], Δ<sub>vap</sub>''H''<sup><s>o</s></sup>
| 35.66 kJ/mol at 139.2°C
|-
| [[Standard entropy change of vaporization|Std entropy change<br/>of vaporization]], Δ<sub>vap</sub>''S''<sup><s>o</s></sup>
| ? J/(mol·K)
|-
! {{chembox header}} | Solid properties
|-
| [[Standard enthalpy change of formation|Std enthalpy change<br/>of formation]], Δ<sub>f</sub>''H''<sup><s>o</s></sup><sub>solid</sub>
| ? kJ/mol
|-
| [[Standard molar entropy]],<br/>''S''<sup><s>o</s></sup><sub>solid</sub>
| ? J/(mol K)
|-
| [[Heat capacity]], ''c<sub>p</sub>''
| ? J/(mol K)
|-
! {{chembox header}} | Liquid properties
|-
| [[Standard enthalpy change of formation|Std enthalpy change<br/>of formation]], Δ<sub>f</sub>''H''<sup><s>o</s></sup><sub>liquid</sub>
| –25.4 kJ/mol
|-
| [[Standard molar entropy]],<br/>''S''<sup><s>o</s></sup><sub>liquid</sub>
| 253.80 J/(mol K)
|-
| [[Enthalpy of combustion]], Δ<sub>c</sub>''H''<sup><s>o</s></sup>
| –4549 kJ/mol
|-
| [[Heat capacity]], ''c<sub>p</sub>''
| 184.5 J/(mol K) at 25°C
|-
! {{chembox header}} | Gas properties
|-
| [[Standard enthalpy change of formation|Std enthalpy change<br/>of formation]], Δ<sub>f</sub>''H''<sup><s>o</s></sup><sub>gas</sub>
| 17.2 kJ/mol
|-
| [[Standard molar entropy]],<br/>''S''<sup><s>o</s></sup><sub>gas</sub>
| 358.2 J/(mol K)
|-
| [[Heat capacity]], ''c<sub>p</sub>''
| 125.8 J/(mol K)
|-
| [[van der Waals equation|van der Waals' constants]]<ref name="lange1522">''Lange's Handbook of Chemistry'', 10th ed, pp 1522-1524</ref>
| a = 3076 L<sup>2</sup> kPa/mol<sup>2</sup><br> b = 0.1772 liter per mole
|-
|}
 
==Vapor pressure of liquid==
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|-
| {{chembox header}} | '''P in mm Hg''' || 1 || 10 || 40 || 100 || 400 || 760
|-
| {{chembox header}} | '''T in °C''' || –6.9 || 28.3 || 55.3 || 76.8 || 116.7 || 139.1
|}
Table data obtained from ''CRC Handbook of Chemistry and Physics'' 44th ed.
 
[[Image:LogMXyleneVaporPressure.png|thumb|left|840px|left|'''log<sub>10</sub> of ''m''-Xylene vapor pressure.''' Uses formula: <math>\scriptstyle \log_e P_{mmHg} =</math><math>\scriptstyle \log_e (\frac {760} {101.325}) - 9.106679\log_e(T+273.15) - \frac {7556.611} {T+273.15} + 76.86698 + 5.403634 \times 10^{-6} (T+273.15)^2</math> obtained from CHERIC<ref name="cheric_p">{{Cite web|url=http://www.cheric.org/research/kdb/hcprop/cmpsrch.php|title=Pure Component Properties|format=Queriable Database|accessdate=28 May 2007|publisher=Chemical Engineering Research Information Center}}</ref>]]{{Clear}}
 
==Distillation data==
See also:
*[[p-Xylene (data page)#Distillation data|''p''-xylene (data page)]]
*[[o-xylene (data page)#Distillation data|''o''-xylene (data page)]]
 
{|
|- valign="top"
|
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|-
| bgcolor="#D0D0D0" align="center" colspan="3"| '''Vapor-liquid Equilibrium<br>for ''m''-Xylene/[[Carbon tetrachloride]]'''<ref name="cheric_b">{{Cite web|url=http://www.cheric.org/research/kdb/hcvle/hcvle.php|title=Binary Vapor-Liquid Equilibrium Data|publisher=Chemical Engineering Research Information Center|format=Queriable database|accessdate=28 May 2007}}</ref><br>''P'' = 760&nbsp;mm Hg
|- {{chembox header}}
! rowspan="2" | BP<br>Temp.<br>°C
! colspan="2" | % by mole carbon tetrachloride
|- {{chembox header}}
! liquid !! vapor
|-
| 137.0 || 1.8 || 5.8
|-
| 131.9 || 6.5 || 21.9
|-
| 126.8 || 11.4 || 35.6
|-
| 122.0 || 16.4 || 46.5
|-
| 118.1 || 20.8 || 55.2
|-
| 113.9 || 25.8 || 62.6
|-
| 110.2 || 30.6 || 68.7
|-
| 106.4 || 35.7 || 73.9
|-
| 102.8 || 41.2 || 78.8
|-
| 102.3 || 41.9 || 79.6
|-
| 98.1 || 48.8 || 84.3
|-
| 94.1 || 56.2 || 88.0
|-
| 90.6 || 63.5 || 91.1
|-
| 87.5 || 70.4 || 93.5
|-
| 84.6 || 77.5 || 95.5
|-
| 82.1 || 84.3 || 97.1
|-
| 79.7 || 91.1 || 98.4
|-
| 77.5 || 97.7 || 99.6
|-
|}
| &nbsp; &nbsp;
|
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|-
| bgcolor="#D0D0D0" align="center" colspan="3"| '''Vapor-liquid Equilibrium<br>for ''m''-Xylene/[[Toluene]]'''<ref name="cheric_b"/><br>''P'' = 760&nbsp;mm Hg
|- {{chembox header}}
! rowspan="2" | BP<br>Temp.<br>°C
! colspan="2" | % by mole toluene
|- {{chembox header}}
! liquid !! vapor
|-
| 133.20 || 11.1 || 35.8
|-
| 129.87 || 18.6 || 46.2
|-
| 119.68 || 52.3 || 71.8
|-
| 118.56 || 56.1 || 74.1
|-
| 117.91 || 59.3 || 76.0
|-
| 117.37 || 62.5 || 77.9
|-
| 116.32 || 67.7 || 80.2
|-
| 116.36 || 68.8 || 81.6
|-
| 115.97 || 69.8 || 82.2
|-
| 115.30 || 73.6 || 84.4
|-
|}
| &nbsp; &nbsp;
|
{|
|-
|
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|-
| bgcolor="#D0D0D0" align="center" colspan="3"| '''Vapor-liquid Equilibrium<br>for ''m''-Xylene/[[Benzene]]'''<ref name="cheric_b"/><br>''P'' = 760&nbsp;mm Hg
|- {{chembox header}}
! rowspan="2" | BP<br>Temp.<br>°C
! colspan="2" | % by mole benzene
|- {{chembox header}}
! liquid !! vapor
|-
| 124.80 || 10.2 || 44.7
|-
| 118.94 || 17.5 || 59.8
|-
| 115.40 || 21.4 || 65.5
|-
| 112.30 || 28.4 || 73.2
|-
| 106.35 || 34.0 || 78.0
|-
| 102.08 || 42.7 || 83.3
|-
| 99.15 || 49.4 || 86.5
|-
| 96.70 || 59.5 || 90.3
|-
| 90.89 || 68.1 || 93.0
|-
|}
|-
| &nbsp;
|-
|
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|-
| bgcolor="#D0D0D0" align="center" colspan="3"| '''Vapor-liquid Equilibrium<br>for ''m''-Xylene/[[Aniline]]'''<ref name="cheric_b"/><br>''P'' = 745&nbsp;mm Hg
|- {{chembox header}}
! rowspan="2" | BP<br>Temp.<br>°C
! colspan="2" | % by mole ''m''-xylene
|- {{chembox header}}
! liquid !! vapor
|-
| 167 || 10.0 || 45.5
|-
| 160 || 19.5 || 58.0
|-
| 153 || 34.0 || 71.5
|-
| 146 || 53.0 || 83.0
|-
| 143 || 71.5 || 89.0
|-
| 141 || 82.0 || 93.0
|-
|}
|}
|}
{{Clear}}
 
== Spectral data == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
 
{| border="1" cellspacing="0" cellpadding="3" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
! {{chembox header}} | [[UV/VIS spectroscopy|UV-Vis]]
|-
| [[Lambda-max|λ<sub>max</sub>]]
| ? [[Nanometre|nm]]
|-
| [[molar absorptivity|Extinction coefficient]], ε
| ?
|-
! {{chembox header}} | [[Infrared|IR]]
|-
| Major absorption bands
| ? cm<sup>&minus;1</sup>
|-
! {{chembox header}} | [[NMR Spectroscopy|NMR]]
|-
| [[Proton NMR]] <!-- Link to image of spectrum -->
| &nbsp;
|-
| [[Carbon-13 NMR]] <!-- Link to image of spectrum -->
| &nbsp;
|-
| Other NMR data <!-- Insert special data e.g. <sup>19</sup>F chem. shifts, omit if not used -->
| &nbsp;
|-
! {{chembox header}} | [[Mass Spectrometry|MS]]
|-
| Masses of <br>main fragments
| &nbsp; <!-- Give list of major fragments -->
|-
|}
 
==References==
<references/>
{{Cite web|url=http://webbook.nist.gov/chemistry|title=NIST Standard Reference Database}}
 
Except where noted otherwise, data relate to [[standard ambient temperature and pressure]].
 
[[wikipedia:Chemical infobox|Disclaimer]] applies.
{{Use dmy dates|date=September 2010}}
 
{{DEFAULTSORT:M-Xylene (Data Page)}}
[[Category:Chemical data pages|Xylene]]

Latest revision as of 11:49, 28 July 2014

Hi there. Allow me start by introducing the author, her title is Sophia Boon but she never truly favored that name. She works as psychic solutions by lynne (http://modenpeople.co.kr) a travel agent but quickly she'll be on her personal. For many years he's been residing in Mississippi and he doesn't strategy on changing it. What me and my family adore is bungee leaping but I've been using on new things recently.

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