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'''Percobaltates''' are chemical compounds where the [[oxidation state]] of [[cobalt]] is +5, which is highest known oxidation state of cobalt. Its general formula is {{chem|M|3|CoO|4}}. Impure '''sodium percobaltate''' can be produced by the reaction of [[cobalt(II,III) oxide]] and [[sodium oxide]]; the oxidant is dioxygen:
 
:<math>\rm \ 4Co_3O_4 + 18Na_2O + 7O_2 \rightarrow 12Na_3CoO_4</math>
 
The [[potassium]] salt can be synthesized similarly. Its [[magnetic moment]] has indicated the existence of cobalt(V).<ref>{{zh icon}} {{cite book|title=《无机化学丛书》第九卷:锰分族、铁系、铂系|page=333|author=张青莲|isbn=7-03-002238-6|location=北京|publisher=科学出版社}}</ref>{{better source|date=December 2013}}
 
== See also ==
* [[Caesium hexafluorocobaltate(IV)]]
 
== References ==
{{reflist}}
 
{{Inorganic-compound-stub}}
 
[[Category:Salts]]
[[Category:Cobalt compounds]]

Latest revision as of 04:56, 30 November 2013

Percobaltates are chemical compounds where the oxidation state of cobalt is +5, which is highest known oxidation state of cobalt. Its general formula is Template:Chem. Impure sodium percobaltate can be produced by the reaction of cobalt(II,III) oxide and sodium oxide; the oxidant is dioxygen:

4Co3O4+18Na2O+7O212Na3CoO4

The potassium salt can be synthesized similarly. Its magnetic moment has indicated the existence of cobalt(V).[1]Template:Better source

See also

References

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