Secondary polynomials

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This page provides supplementary chemical data on trichloroethylene.

Material Safety Data Sheet

The handling of this chemical may incur notable safety precautions. It is highly recommend that you seek the Material Safety Datasheet (MSDS) for this chemical from a reliable source such as SIRI, and follow its directions. MSDS for trichloroethylene is available at Mallinckrodt Baker.

Structure and properties

Structure and properties
Index of refraction,[1]nD 1.4777 at 19.8°C
Abbe number ?
Dielectric constant,[2] εr 3.4 ε0 at 16 °C
Bond strength ?
Bond length ?
Bond angle ?
Magnetic susceptibility ?
Surface tension[3] 28.7 dyn/cm
Viscosity[4] 0.53 mPa·s at 25°C

Thermodynamic properties

Phase behavior
Triple point[5] 188.4 K (–84.7 °C), ? Pa
Critical point[5] 571 K (298 °C), 5016 kPa
Std enthalpy change
of fusion, ΔfusHo 		8.45 kJ/mol
Std entropy change
of fusion, ΔfusSo 		44.8 J/(mol·K)
Std enthalpy change
of vaporization, ΔvapHo 		31.4 kJ/mol
Std entropy change
of vaporization, ΔvapSo 		? J/(mol·K)
Solid properties
Std enthalpy change
of formation, ΔfHosolid 		? kJ/mol
Standard molar entropy,
Sosolid 		? J/(mol K)
Heat capacity, cp ? J/(mol K)
Liquid properties
Std enthalpy change
of formation, ΔfHoliquid 		–53.1 kJ/mol
Standard molar entropy,
Soliquid 		? J/(mol K)
Enthalpy of combustion, ΔcHoliquid –947.7 kJ/mol
Heat capacity, cp 120.1 J/(mol K)
Gas properties
Std enthalpy change
of formation, ΔfHogas 		–19.1 kJ/mol
Standard molar entropy,
Sogas 		? J/(mol K)
Heat capacity,[6] cp 80.7 J/(mol K) at 25°C

Vapor pressure of liquid

P in mm Hg 1 10 40 100 400 760
T in °C –43.8 –12.4 11.9 31.4 67.0 86.7

Table data obtained from CRC Handbook of Chemistry and Physics 44th ed.

log10 of Trichloroethylene vapor pressure. Uses formula: logePmmHg=loge(760101.325)−3.586434loge(T+273.15)−5142.974T+273.15+39.83149+1.342324×10−6(T+273.15)2 obtained from CHERIC[6]

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Distillation data

Vapor-liquid Equilibrium
for Trichlorethylene/Carbon tetrachloride[7]
P = 760 mmHg
BP
Temp.
°C 		% by mole CCl4
liquid vapor
86.0 6.0 7.5
85.1 14.7 17.6
84.4 20.2 25.0
84.2 22.4 27.8
83.5 27.4 34.4
83.1 31.5 38.0
82.5 37.6 44.5
81.3 49.0 56.5
81.0 52.5 58.9
80.5 58.0 65.0
80.0 62.7 70.0
79.1 70.6 78.0
78.5 76.7 82.9
78.1 80.4 86.6
77.3 91.8 95.0
76.9 96.5 98.0
   
Vapor-liquid Equilibrium
for Trichlorethylene/Tetrachloroethylene[7]
P = 760 mmHg
BP
Temp.
°C 		% by mole trichloroethylene
liquid vapor
117.0 7.5 17.8
115.7 10.0 22.8
112.8 16.2 33.8
110.5 21.7 42.0
109.1 25.0 46.8
106.9 30.8 53.7
105.7 33.6 57.2
103.4 39.4 62.7
101.0 46.2 69.8
100.0 49.3 71.8
98.4 55.0 75.6
96.3 61.4 80.0
94.4 68.5 84.3
93.4 72.3 87.2
92.1 76.9 88.8
89.5 87.5 95.0
   
Vapor-liquid Equilibrium
for Trichlorethylene/Isopropanol[7]
P = 100 kPa
BP
Temp.
°C 		% by mole trichloroethylene
liquid vapor
81.7 0.0 0.0
81.4 0.8 2.1
80.4 3.2 8.0
79.3 6.8 14.7
78.3 10.6 20.9
77.2 15.6 27.3
76.3 21.8 33.7
75.6 29.0 39.4
75.2 35.7 43.7
74.9 43.3 47.7
74.8 50.9 50.8
74.8 57.3 53.9
75.0 63.2 56.2
75.3 69.5 58.7
75.7 75.2 61.1
76.2 79.8 64.1
77.4 86.2 68.8
78.9 90.8 74.5
80.5 94.1 80.1
81.3 94.9 83.0
82.5 96.7 87.1
83.5 97.9 90.7
84.2 98.5 92.9
85.0 99.1 95.1
86.4 100.0 100.0

Spectral data

UV-Vis
λmax ? nm
Extinction coefficient, ε ?
IR
Major absorption bands ? cm−1
NMR
Proton NMR  
Carbon-13 NMR  
Other NMR data  
MS
Masses of
main fragments 		 

References

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Except where noted otherwise, data relate to standard ambient temperature and pressure.

Disclaimer applies. 30 year-old Entertainer or Range Artist Wesley from Drumheller, really loves vehicle, property developers properties for sale in singapore singapore and horse racing. Finds inspiration by traveling to Works of Antoni Gaudí.

  1. ↑ Lange's Handbook of Chemistry, 10th ed. pp 1289-1376
  2. ↑ CRC Handbook of Chemistry and Physics, 44th ed. pp 2613-2620
  3. ↑ Template:Cite web
  4. ↑ Template:Cite web
  5. ↑ 5.0 5.1 Template:Cite web Template:Dead link
  6. ↑ 6.0 6.1 Template:Cite web
  7. ↑ 7.0 7.1 7.2 Template:Cite web
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