Extended Kalman filter
Cobalt(II,III) oxide is inorganic compound with the formula Co3O4. It is one of two well characterized cobalt oxides. It is a black antiferromagnetic solid. As a mixed valence compound, its formula is sometimes written as CoIICoIII2O4 and sometimes as CoO.Co2O3.[1]
Structure
Co3O4 adopts the normal spinel structure, with Co2+ ions in tetrahedral interstices and Co3+ ions in the octahedral interstices of the cubic close-packed lattice of oxide anions.[1]
-oxide-xtal-2006-Co(II)-coord-CM-3D-balls.png) |
-oxide-xtal-2006-Co(III)-coord-CM-3D-balls.png) |
-oxide-xtal-2006-O-coord-CM-3D-balls.png) |
| tetrahedral coordination geometry of Co(II) | distorted octahedral coordination geometry of Co(III) | distorted tetrahedral coordination geometry of O |
Synthesis
Cobalt(II) oxide, CoO, converts to Co3O4 if heated to around 600-700 °C in air. Above 900 °C, CoO is stable.[2] These reaction are described by the following equilibrium:
- 2 Co3O4 6 CoO + O2
Research
This inorganic compound is currently utilized in the process of artificial photosynthesis.Template:Cn
Safety
Cobalt compounds are potentially poisonous in large amounts.[3]
References
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Template:Cobalt compounds Template:Oxides
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- ↑ MSDS