Fumonisin B1 esterase

Many quantum mechanical Hamiltonians are time dependent. How to solve problems where there is an explicit time dependence is an open subject nowadays. For these kind of problems it is of importance to look for constants of motion or invariants. For the (time dependent) harmonic oscillator it is possible to write several invariants, among them, the Ermakov–Lewis invariant which is developed below.

The time dependent harmonic oscillator Hamiltonian reads

$\hat{H}=\frac{1}{2}[{\hat{p}}^2+{\mathrm{\Omega }}^2(t){\hat{q}}^2].$

It is well known that an invariant for this type of interaction has the form

$\hat{I}=\frac{1}{2}[{\left(\frac{\hat{q}}{\rho }\right)}^2+(\rho \hat{p}-\dot{\rho }\hat{q}{)}^2],$

where $\rho$ obeys the Ermakov equation

$\ddot{\rho }+{\mathrm{\Omega }}^2\rho ={\rho }^{-3}.$

The above invariant is the so-called Ermakov-Lewis invariant. It is easy to show that $\hat{I}$ may be related to the time independent harmonic oscillator Hamiltonian via a unitary transformation of the form

$\hat{T}=e^{i\frac{\ln \rho }{2}(\hat{q}\hat{p}+\hat{p}\hat{q})}{e}^{-i\frac{\dot{\rho }}{2\rho }{\hat{q}}^2}=e^{i\frac{\ln \rho }{2}\frac{d{\hat{q}}^2}{dt}}{e}^{-i\frac{{\hat{q}}^2}{2}\frac{d\ln \rho }{dt}},$

as

$\frac{1}{2}[{\hat{p}}^2+{\hat{q}}^2]=\hat{T}\hat{I}{\hat{T}}^{†}.$

This allows an easy form to express the solution of the Schrödinger equation for the time dependent Hamiltonian.

The first exponential in the transformation is the so-called squeeze operator.

This approach may allow to simplify problems such as the Quadrupole ion trap, where an ion is trapped in a harmonic potential with time dependent frequency. The transformation presented here is then useful to take into account such effects.

References

43 year old Petroleum Engineer Harry from Deep River, usually spends time with hobbies and interests like renting movies, property developers in singapore new condominium and vehicle racing. Constantly enjoys going to destinations like Camino Real de Tierra Adentro.