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<!-- To obtain a blank version of this page, type subst:chembox supplement inside of double curly braces, {{}}, and save the page -->
 
This page provides supplementary chemical data on [[carbon tetrachloride]]. <!-- replace with proper wikilink -->
 
== Material Safety Data Sheet == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
 
The handling of this chemical may incur notable safety precautions. It is highly recommend that you seek the Material Safety Datasheet ([[Material safety data sheet|MSDS]]) for this chemical from a reliable source  such as [http://www2.siri.org/msds/index.php SIRI], and follow its directions. MSDS for carbon tetrachloride is available at [https://fscimage.fishersci.com/msds/90116.htm Fisher Scientific].
 
== Structure and properties == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
 
{| border="1" cellspacing="0" cellpadding="3" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
! {{chembox header}} | Structure and properties
|-
| [[Index of refraction]], ''n''<sub>D</sub>
| 1.460 <!-- Please omit if not applicable -->
|-
| [[Abbe number]]
|? <!-- Please omit if not applicable -->
|-
| [[Dielectric constant]], ε<sub>r</sub>
| 2.2379 ε<sub>0</sub> at 20 °C <!-- Please omit if not applicable -->
|-
| [[Bond strength]]
| ? <!-- Specify which bond. Please omit if not applicable -->
|-
| [[Bond length]]
| 175pm
|-
| [[Bond angle]]
| 109.5° Cl–C–Cl <!-- Specify which angle, e.g. Cl-P-O. Please omit if not applicable -->
|-
| [[Magnetic susceptibility]]
| ? <!-- Please omit if not applicable -->
|-
| [[Surface tension]]
| 28.0 dyn/cm at 10°C<br>26.8 dyn/cm at 20°C<br>22.2 dyn/cm at 75°C
|-
| [[Viscosity]]<ref name="lange1669">''Lange's Handbook of Chemistry'', 10th ed. pp 1669-1674</ref>
| 0.9578 mPa·s at 21°C<br>0.901 mPa·s at 25 °C<br>0.7928 mPa·s at 35°C<br>0.4056 mPa·s at 99°C
|-
|}
 
== Thermodynamic properties == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
 
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
! {{chembox header}} | Phase behavior
|-
| [[Triple point]]
| 249 K (–24 °C), ? Pa
|-
| [[Critical point (chemistry)|Critical point]]
| 556.4 K (283.3 °C), 4493 kPa, 3.625&nbsp;mol.dm<sup>−3</sup>
|-
| [[Standard enthalpy change of fusion|Std enthalpy change<br/>of fusion]], Δ<sub>fus</sub>''H''<sup><s>o</s></sup>
| 2.52 kJ/mol
|-
| [[Standard entropy change of fusion|Std entropy change<br/>of fusion]], Δ<sub>fus</sub>''S''<sup><s>o</s></sup>
| 10.1 J/(mol·K)
|-
| [[Standard enthalpy change of vaporization|Std enthalpy change<br/>of vaporization]], Δ<sub>vap</sub>''H''<sup><s>o</s></sup>
| 32.54 kJ/mol
|-
| [[Standard entropy change of vaporization|Std entropy change<br/>of vaporization]], Δ<sub>vap</sub>''S''<sup><s>o</s></sup>
| 92.82 J/(mol·K) at 76°C
|-
! {{chembox header}} | Solid properties
|-
| [[Standard enthalpy change of formation|Std enthalpy change<br/>of formation]], Δ<sub>f</sub>''H''<sup><s>o</s></sup><sub>solid</sub>
| ? kJ/mol
|-
| [[Standard molar entropy]],<br/>''S''<sup><s>o</s></sup><sub>solid</sub>
| ? J/(mol K)
|-
| [[Heat capacity]], ''c<sub>p</sub>''
| 44.22 J/(mol K) at -227 °C (46 K)
|-
! {{chembox header}} | Liquid properties
|-
| [[Standard enthalpy change of formation|Std enthalpy change<br/>of formation]], Δ<sub>f</sub>''H''<sup><s>o</s></sup><sub>liquid</sub>
| –128.4 kJ/mol
|-
| [[Standard molar entropy]],<br/>''S''<sup><s>o</s></sup><sub>liquid</sub>
| 214.39 J/(mol K)
|-
| [[Enthalpy of combustion]], Δ<sub>c</sub>''H''<sup><s>o</s></sup>
| –359.9 kJ/mol
|-
| [[Heat capacity]], ''c<sub>p</sub>''
| 131.3 J/(mol K)
|-
! {{chembox header}} | Gas properties
|-
| [[Standard enthalpy change of formation|Std enthalpy change<br/>of formation]], Δ<sub>f</sub>''H''<sup><s>o</s></sup><sub>gas</sub>
| –95.98 kJ/mol
|-
| [[Standard molar entropy]],<br/>''S''<sup><s>o</s></sup><sub>gas</sub>
| 309.65 J/(mol K)
|-
| [[Heat capacity]], ''c<sub>p</sub>''
| 82.65 J/(mol K)
|-
| [[van der Waals equation|van der Waals' constants]]<ref name="crcD104">''CRC Handbook of Chemistry and Physics'' 47th ed, p D-104</ref>
| a = 2066 L<sup>2</sup> kPa/mol<sup>2</sup><br> b = 0.1383 liter per mole
|-
|}
 
==Vapor pressure of liquid==
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|-
| {{chembox header}} | '''P in mm Hg''' || 1 || 10 || 40 || 100 || 400 || 760 || 1520 || 3800 || 7600 || 15200 || 30400 || 45600
|-
| {{chembox header}} | '''T in °C''' || –50.0<sub>(s)</sub> || –19.6 || 4.3 || 23.0 || 57.8 || 76.7 || 102.0 || 141.7 || 178.0 || 222.0 || 276.0 || &nbsp; —
|}
Table data obtained from ''CRC Handbook of Chemistry and Physics'' 47th ed. Note that "(s)" annotation indicates equilibrium temperature of vapor over solid. Otherwise the temperature is equilibrium of vapor over liquid.
 
[[Image:LogCarbontetrachlorideVaporPressure.png|thumb|821px|left|'''log<sub>10</sub> of Carbon tetrachloride vapor pressure.''' Uses formula: <math>\scriptstyle \log_e P_{mmHg} =</math><math>\scriptstyle \log_e (\frac{760}{101.325}) - 9.113968 \log_e(T+273.15) - \frac {6263.383}{T+273.15} + 74.99482 + 7.411446 \times 10^{-06} (T+273.15)^2</math> obtained from CHERIC<ref name="cheric_p">{{Cite web|url=http://www.cheric.org/research/kdb/hcprop/cmpsrch.php|title=Pure Component Properties|format=Queriable database|publisher=Chemical Engineering Research Information Center|accessdate=17 May 2007}}</ref>]]{{Clear}}
 
==Distillation data==
{|
|- valign="top"
|
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|-
| bgcolor="#D0D0D0" align="center" colspan="3" | '''Vapor-liquid Equilibrium<br>for Carbon tetrachloride/[[hexane|''n''-hexane]]'''<ref name="cheric_b">{{Cite web|url=http://www.cheric.org/research/kdb/hcvle/hcvle.php|title=Binary Vapor-Liquid Equilibrium Data|publisher=Chemical Engineering Research Information Center|format=Queriable database|accessdate=17 May 2007}}</ref><br>''P'' = 760 mmHg
|- {{chembox header}}
! rowspan="2" | BP<br>Temp.<br>°C
! colspan="2" | % by mole CCl<sub>4</sub>
|- {{chembox header}}
! liquid !! vapor
|-
| 68.8 || 2.6 || 2.3
|-
| 68.9 || 8.1 || 7.1
|-
| 69.0 || 14.0 || 12.5
|-
| 69.2 || 20.3 || 17.9
|-
| 69.4 || 26.4 || 23.3
|-
| 69.6 || 32.5 || 28.6
|-
| 69.9 || 38.5 || 33.8
|-
| 70.3 || 44.8 || 39.4
|-
| 70.7 || 50.9 || 44.8
|-
| 70.7 || 51.6 || 45.5
|-
| 71.1 || 57.0 || 50.5
|-
| 71.6 || 63.1 || 56.2
|-
| 72.2 || 69.1 || 62.2
|-
| 72.9 || 74.8 || 68.1
|-
| 73.6 || 80.7 || 74.5
|-
| 74.4 || 86.5 || 81.2
|-
| 75.4 || 92.5 || 88.8
|-
| 76.4 || 98.2 || 97.2
|-
|}
| &nbsp; &nbsp;
|
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|-
| bgcolor="#D0D0D0" align="center" colspan="3" | '''Vapor-liquid Equilibrium<br>for Carbon tetrachloride/[[benzene]]'''<ref name="cheric_b"/><br>''P'' = 760 mmHg
|- {{chembox header}}
! rowspan="2" | BP<br>Temp.<br>°C
! colspan="2" | % by mole CCl<sub>4</sub>
|- {{chembox header}}
! liquid !! vapor
|-
| 79.9 || 2.1 || 2.5
|-
| 79.7 || 6.1 || 7.2
|-
| 79.2 || 12.4 || 14.4
|-
| 78.8 || 18.8 || 21.3
|-
| 78.5 || 25.1 || 28.1
|-
| 78.1 || 31.3 || 34.4
|-
| 77.8 || 37.6 || 40.7
|-
| 77.6 || 43.9 || 46.7
|-
| 77.3 || 49.5 || 52.0
|-
| 77.3 || 50.1 || 52.5
|-
| 77.1 || 55.9 || 58.2
|-
| 77.0 || 62.2 || 64.1
|-
| 76.8 || 68.6 || 70.1
|-
| 76.7 || 75.1 || 76.0
|-
| 76.7 || 81.5 || 82.0
|-
| 76.7 || 87.8 || 88.1
|-
| 76.7 || 93.9 || 94.1
|-
| 76.7 || 97.8 || 97.9
|-
|}
| &nbsp; &nbsp;
|
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|-
| bgcolor="#D0D0D0" align="center" colspan="3" | '''Vapor-liquid Equilibrium<br>for Carbon tetrachloride/[[acetone]]'''<ref name="cheric_b"/><br>''P'' = 760 mmHg
|- {{chembox header}}
! rowspan="2" | BP<br>Temp.<br>°C
! colspan="2" | % by mole acetone
|- {{chembox header}}
! liquid !! vapor
|-
| 76.74 || 0.00 || 0.00
|-
| 70.80 || 5.90 || 20.25
|-
| 68.74 || 8.70 || 27.10
|-
| 64.45 || 17.90 || 40.75
|-
| 61.91 || 26.40 || 48.95
|-
| 59.83 || 37.40 || 56.55
|-
| 58.74 || 45.10 || 61.25
|-
| 57.94 || 52.55 || 65.50
|-
| 57.18 || 61.65 || 70.65
|-
| 56.67 || 69.60 || 75.60
|-
| 56.36 || 76.20 || 79.85
|-
| 56.15 || 82.95 || 84.60
|-
| 56.01 || 89.50 || 89.80
|-
| 56.02 || 91.40 || 91.50
|-
| 55.99 || 95.30 || 95.20
|-
| 56.08 || 100.00 || 100.00
|-
|}
|}
 
== Spectral data == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
 
{| border="1" cellspacing="0" cellpadding="3" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
! {{chembox header}} | [[UV/VIS spectroscopy|UV-Vis]]
|-
| [[Lambda-max|λ<sub>max</sub>]]
| ? [[Nanometre|nm]]
|-
| [[molar absorptivity|Extinction coefficient]], ε
| ?
|-
! {{chembox header}} | [[Infrared|IR]]
|-
| Major absorption bands
| ? cm<sup>&minus;1</sup>
|-
! {{chembox header}} | [[NMR Spectroscopy|NMR]]
|-
| [[Proton NMR]] <!-- Link to image of spectrum -->
| &nbsp;
|-
| [[Carbon-13 NMR]] <!-- Link to image of spectrum -->
| &nbsp;
|-
| Other NMR data <!-- Insert special data e.g. <sup>19</sup>F chem. shifts, omit if not used -->
| &nbsp;
|-
! {{chembox header}} | [[Mass Spectrometry|MS]]
|-
| Masses of <br>main fragments
| &nbsp; <!-- Give list of major fragments -->
|-
|}
 
==References==
<references/>
* {{Cite web|url=http://webbook.nist.gov/chemistry/|title=NIST Standard Reference Database|accessdate= 17 May 2007}}
 
Except where noted otherwise, data relate to [[standard ambient temperature and pressure]].
 
[[wikipedia:Chemical infobox|Disclaimer]] applies.
 
{{DEFAULTSORT:Carbon Tetrachloride (Data Page)}}
[[Category:Chemical data pages]]

Revision as of 03:09, 17 March 2013

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This page provides supplementary chemical data on carbon tetrachloride.

Material Safety Data Sheet

The handling of this chemical may incur notable safety precautions. It is highly recommend that you seek the Material Safety Datasheet (MSDS) for this chemical from a reliable source such as SIRI, and follow its directions. MSDS for carbon tetrachloride is available at Fisher Scientific.

Structure and properties

Structure and properties
Index of refraction, nD 1.460
Abbe number ?
Dielectric constant, εr 2.2379 ε0 at 20 °C
Bond strength ?
Bond length 175pm
Bond angle 109.5° Cl–C–Cl
Magnetic susceptibility ?
Surface tension 28.0 dyn/cm at 10°C
26.8 dyn/cm at 20°C
22.2 dyn/cm at 75°C
Viscosity[1] 0.9578 mPa·s at 21°C
0.901 mPa·s at 25 °C
0.7928 mPa·s at 35°C
0.4056 mPa·s at 99°C

Thermodynamic properties

Phase behavior
Triple point 249 K (–24 °C), ? Pa
Critical point 556.4 K (283.3 °C), 4493 kPa, 3.625 mol.dm−3
Std enthalpy change
of fusion, ΔfusHo 		2.52 kJ/mol
Std entropy change
of fusion, ΔfusSo 		10.1 J/(mol·K)
Std enthalpy change
of vaporization, ΔvapHo 		32.54 kJ/mol
Std entropy change
of vaporization, ΔvapSo 		92.82 J/(mol·K) at 76°C
Solid properties
Std enthalpy change
of formation, ΔfHosolid 		? kJ/mol
Standard molar entropy,
Sosolid 		? J/(mol K)
Heat capacity, cp 44.22 J/(mol K) at -227 °C (46 K)
Liquid properties
Std enthalpy change
of formation, ΔfHoliquid 		–128.4 kJ/mol
Standard molar entropy,
Soliquid 		214.39 J/(mol K)
Enthalpy of combustion, ΔcHo –359.9 kJ/mol
Heat capacity, cp 131.3 J/(mol K)
Gas properties
Std enthalpy change
of formation, ΔfHogas 		–95.98 kJ/mol
Standard molar entropy,
Sogas 		309.65 J/(mol K)
Heat capacity, cp 82.65 J/(mol K)
van der Waals' constants[2] a = 2066 L2 kPa/mol2
b = 0.1383 liter per mole

Vapor pressure of liquid

P in mm Hg 1 10 40 100 400 760 1520 3800 7600 15200 30400 45600
T in °C –50.0(s) –19.6 4.3 23.0 57.8 76.7 102.0 141.7 178.0 222.0 276.0   —

Table data obtained from CRC Handbook of Chemistry and Physics 47th ed. Note that "(s)" annotation indicates equilibrium temperature of vapor over solid. Otherwise the temperature is equilibrium of vapor over liquid.

log10 of Carbon tetrachloride vapor pressure. Uses formula: obtained from CHERIC[3]

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Distillation data

Vapor-liquid Equilibrium
for Carbon tetrachloride/n-hexane[4]
P = 760 mmHg
BP
Temp.
°C 		% by mole CCl4
liquid vapor
68.8 2.6 2.3
68.9 8.1 7.1
69.0 14.0 12.5
69.2 20.3 17.9
69.4 26.4 23.3
69.6 32.5 28.6
69.9 38.5 33.8
70.3 44.8 39.4
70.7 50.9 44.8
70.7 51.6 45.5
71.1 57.0 50.5
71.6 63.1 56.2
72.2 69.1 62.2
72.9 74.8 68.1
73.6 80.7 74.5
74.4 86.5 81.2
75.4 92.5 88.8
76.4 98.2 97.2
   
Vapor-liquid Equilibrium
for Carbon tetrachloride/benzene[4]
P = 760 mmHg
BP
Temp.
°C 		% by mole CCl4
liquid vapor
79.9 2.1 2.5
79.7 6.1 7.2
79.2 12.4 14.4
78.8 18.8 21.3
78.5 25.1 28.1
78.1 31.3 34.4
77.8 37.6 40.7
77.6 43.9 46.7
77.3 49.5 52.0
77.3 50.1 52.5
77.1 55.9 58.2
77.0 62.2 64.1
76.8 68.6 70.1
76.7 75.1 76.0
76.7 81.5 82.0
76.7 87.8 88.1
76.7 93.9 94.1
76.7 97.8 97.9
   
Vapor-liquid Equilibrium
for Carbon tetrachloride/acetone[4]
P = 760 mmHg
BP
Temp.
°C 		% by mole acetone
liquid vapor
76.74 0.00 0.00
70.80 5.90 20.25
68.74 8.70 27.10
64.45 17.90 40.75
61.91 26.40 48.95
59.83 37.40 56.55
58.74 45.10 61.25
57.94 52.55 65.50
57.18 61.65 70.65
56.67 69.60 75.60
56.36 76.20 79.85
56.15 82.95 84.60
56.01 89.50 89.80
56.02 91.40 91.50
55.99 95.30 95.20
56.08 100.00 100.00

Spectral data

UV-Vis
λmax ? nm
Extinction coefficient, ε ?
IR
Major absorption bands ? cm−1
NMR
Proton NMR  
Carbon-13 NMR  
Other NMR data  
MS
Masses of
main fragments 		 

References

  1. ↑ Lange's Handbook of Chemistry, 10th ed. pp 1669-1674
  2. ↑ CRC Handbook of Chemistry and Physics 47th ed, p D-104
  3. ↑ Template:Cite web
  4. ↑ 4.0 4.1 4.2 Template:Cite web

Except where noted otherwise, data relate to standard ambient temperature and pressure.

Disclaimer applies.

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