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In [[quantum mechanics]] ([[physics]]), the '''canonical commutation relation''' is the fundamental relation between [[canonical conjugate]] quantities (quantities which are related by definition such that one is the [[Fourier transform]] of another). For example,
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:<math>[x,p_x] = i\hbar</math>
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between the position {{mvar|x}} and momentum {{mvar|p<sub>x</sub>}} in the  {{mvar|x}}  direction of a point particle in one dimension, where {{math| [''x'' , ''p''<sub>''x''</sub>] {{=}} ''x'' ''p''<sub>''x''</sub> − ''p''<sub>''x''</sub> ''x''}}  is the [[commutator]] of {{mvar|x}} and  {{mvar|p<sub>x</sub> }}, {{mvar|i}} is the [[imaginary unit]], and {{math|ℏ}} is the reduced [[Planck's constant]] {{math|{{sfrac|''h''|2&pi;}}}}  . 
 
This relation is attributed to [[Max Born]] (1925),<ref>{{cite doi|10.1007/BF01328531|noedit}}</ref> who called it a "quantum condition" serving as a postulate of the theory;  it was noted by [[Earle Hesse Kennard|E. Kennard]] (1927)<ref>{{cite doi|10.1007/BF01391200|noedit}}</ref> to imply the [[Werner Heisenberg|Heisenberg]] [[uncertainty principle]].
 
== Relation to classical mechanics ==
By contrast, in [[classical physics]], all observables commute and the [[commutator]] would be zero. However, an analogous relation exists, which is obtained by replacing the commutator with the [[Poisson bracket]] multiplied by {{math|''i''ℏ}}:
 
:<math>\{x,p\} = 1 \, .</math>
 
This observation led [[Paul Dirac|Dirac]] to propose that the quantum counterparts  {{mvar|f&#770;}},  {{mvar|g&#770;}} of classical observables {{mvar|f}}, {{mvar|g}} satisfy
 
:<math>[\hat f,\hat g]= i\hbar\widehat{\{f,g\}} \, .</math>
 
In 1946, [[Hilbrand J. Groenewold|Hip Groenewold]] demonstrated that a ''general systematic correspondence''  between  quantum commutators and Poisson brackets could not hold consistently. <ref name="groenewold">{{cite doi|10.1016/S0031-8914(46)80059-4|noedit}}</ref> However, he did appreciate that such a systematic correspondence does, in fact, exist between the quantum commutator and a ''deformation'' of the Poisson bracket, the [[Moyal bracket]], and, in general, quantum operators and  classical observables and distributions in [[phase space]]. He thus finally elucidated the correspondence mechanism, [[Weyl quantization]], that underlies an alternate equivalent mathematical approach to quantization known as [[deformation quantization]].<ref name="groenewold"/>
 
== Representations ==
The [[Lie group|group]] {{math|''H''<sub>3</sub>(ℝ)}} generated by [[exponential map|exponentiation]] of the [[Lie algebra]] specified by these commutation relations, {{math|1=['''x''', '''p'''] = ''i''ℏ}}, is called the [[Heisenberg group]].
 
According to the standard [[mathematical formulation of quantum mechanics]], quantum observables such as {{math|'''x'''}}  and {{math|'''p'''}} should be represented as [[self-adjoint operator]]s on some [[Hilbert space]]. It is relatively easy to see that two [[operator (mathematics)|operator]]s satisfying the above canonical commutation relations cannot both be [[bounded operator|bounded]]—try taking the [[trace (linear algebra)|Trace]] of both sides of the relations and use the relation {{math|1=Trace(''A B '') = Trace(''B A '')}}; one gets a finite number on the right and zero on the left.<ref>More directly, note {{math|1=[''x<sup>n</sup>'', ''p''] = ''i'' ℏ ''n x''<sup>''n'' − 1</sup>}}, hence {{math|<big>2 ‖ ''p'' ‖ ‖ ''x'' ‖<sup>''n''</sup> ≥ ''n'' ℏ ‖ ''x'' ‖<sup>''n'' − 1</sup></big>}}, so that, {{math|∀''n'': 2 ‖ ''p'' ‖ ‖ ''x'' ‖ ≥ ''n'' ℏ}}. However, {{mvar|n}}  can be arbitrarily large. Utilizing the Weyl relations, below, it can actually be shown that ''both'' operators are unbounded.</ref> 
 
These canonical commutation relations can be rendered somewhat "tamer" by writing them in terms of the (bounded) [[unitary operator]]s {{math|exp(''i t'' '''x''')}} and {{math|exp(''i s'' '''p''')}}, which do admit finite-dimensional representations. The resulting braiding relations for these are the so-called [[Stone–von Neumann theorem|Weyl relations]]
:{{math|size=120%|1=exp(''i t'' '''x''') exp(''i s'' '''p''') = exp(−''i''ℏ ''s t'') exp(''i s'' '''p''') exp(''i t'' '''x''')}}. 
The corresponding group [[commutator]] is then
:{{math|size=120%|1=exp(''i t'' '''x''') exp(''i s'' '''p''') exp(−''i t'' '''x''') exp(−''i s'' '''p''') = exp(−''i''ℏ ''s t'')}}. 
The uniqueness of the canonical commutation relations between position and momentum is then guaranteed by the [[Stone–von Neumann theorem]].
 
== Generalizations ==
The simple formula
 
:<math>[x,p] = i\hbar, \, </math>
 
valid for the [[Canonical quantization|quantization]] of the simplest classical system, can be generalized to the case of an arbitrary [[Lagrangian]] <math>{\mathcal L}</math>.<ref name="town">{{cite book |first=J. S. |last=Townsend |title=A Modern Approach to Quantum Mechanics |publisher=University Science Books |location=Sausalito, CA |year=2000 |isbn=1-891389-13-0 }}</ref> We identify '''canonical coordinates''' (such as {{mvar|x}} in the example above, or a field {{math|&phi;(''x'')}} in the case of [[quantum field theory]]) and '''canonical momenta''' {{math|&pi;<sub>''x''</sub>}}  (in the example above it is {{mvar|p}}, or more generally, some functions involving the [[derivative]]s of the canonical coordinates with respect to time):
 
:<math>\pi_i \ \stackrel{\mathrm{def}}{=}\  \frac{\partial {\mathcal L}}{\partial(\partial x_i / \partial t)}.</math>
 
This definition of the canonical momentum ensures that one of the [[Euler–Lagrange equation]]s has the form
 
:<math>\frac{\partial}{\partial t} \pi_i = \frac{\partial {\mathcal L}}{\partial x_i}.</math>
 
The canonical commutation relations then amount to
 
:<math>[x_i,\pi_j] = i\hbar\delta_{ij}, \, </math>
 
where {{math|''&delta;''<sub>''ij''</sub>}} is the [[Kronecker delta]].
 
Further, it can be easily shown that
 
:<math>[p_i,F(\vec{x})] = -i\hbar\frac{\partial F(\vec{x})}{\partial x_i}; \qquad [x_i, F(\vec{p})] = i\hbar\frac{\partial F(\vec{p})}{\partial p_i}.</math>
 
==Gauge invariance==
Canonical quantization is applied, by definition, on [[canonical coordinates]].  However, in the presence of an [[electromagnetic field]], the canonical momentum {{mvar|p}} is not [[gauge invariant]]. The correct gauge-invariant momentum (or "kinetic momentum") is
 
:<math>p_\textrm{kin} = p - qA  \,\!</math> &nbsp; ([[SI units]]) &nbsp;&nbsp;&nbsp;&nbsp; <math>p_\textrm{kin} = p - \frac{qA}{c} \,\!</math> &nbsp; ([[Gaussian units|cgs units]]),
 
where {{mvar|q}} is the particle's [[electric charge]], {{mvar|A}} is the [[magnetic potential|vector potential]], and {{math|''c''}} is the [[speed of light]]. Although the quantity {{math|''p''<sub>kin</sub>}} is the "physical momentum", in that it is the quantity to be identified with momentum in laboratory experiments, it ''does not'' satisfy the canonical commutation relations; only the canonical momentum does that. This can be seen as follows.
 
The non-relativistic [[Hamiltonian (quantum mechanics)|Hamiltonian]] for a quantized charged particle of mass {{mvar|m}} in a classical electromagnetic field is (in cgs units)
 
:<math>H=\frac{1}{2m} \left(p-\frac{qA}{c}\right)^2 +q\phi</math>
 
where {{mvar|A}} is the three-vector potential and <math>\phi</math> is the [[scalar potential]]. This form of the Hamiltonian, as well as the [[Schrödinger equation]] <math>H\psi=i\hbar \partial\psi/\partial t</math>, the [[Maxwell equation]]s and the [[Lorentz force law]] are invariant under the gauge transformation
 
:<math>A\to A^\prime=A+\nabla \Lambda</math>
:<math>\phi\to \phi^\prime=\phi-\frac{1}{c} \frac{\partial \Lambda}{\partial t}</math>
:<math>\psi\to\psi^\prime=U\psi</math>
:<math>H\to H^\prime= U HU^\dagger,</math>
 
where
 
:<math>U=\exp \left( \frac{iq\Lambda}{\hbar c}\right)</math>
 
and <math>\Lambda=\Lambda(x,t)</math> is the gauge function.
 
The [[angular momentum operator]] is
:<math>L=r \times p \,\!</math>
and obeys the canonical quantization relations
:<math>[L_i, L_j]= i\hbar {\epsilon_{ijk}} L_k</math>
defining the [[Lie algebra]] for [[so(3)]], where <math>\epsilon_{ijk}</math> is the [[Levi-Civita symbol]]Under gauge transformations, the angular momentum transforms as
 
:<math> \langle \psi \vert L \vert \psi \rangle \to  
\langle \psi^\prime \vert L^\prime \vert \psi^\prime \rangle =
\langle \psi \vert L \vert \psi \rangle +
\frac {q}{\hbar c}  \langle \psi \vert r \times \nabla \Lambda \vert \psi \rangle \, .
</math>
 
The gauge-invariant angular momentum (or "kinetic angular momentum") is given by
 
:<math>K=r \times \left(p-\frac{qA}{c}\right),</math>
 
which has the commutation relations
 
:<math>[K_i,K_j]=i\hbar {\epsilon_{ij}}^{\,k}
\left(K_k+\frac{q\hbar}{c} x_k
\left(x \cdot B\right)\right)</math>
 
where
 
:<math>B=\nabla \times A</math>
 
is the [[magnetic field]]. The inequivalence of these two formulations shows up in the [[Zeeman effect]] and the [[Aharonov–Bohm effect]].
 
==Angular momentum operators==
From {{math|1=''L''<sub>''x''</sub> = ''y p<sub>z</sub>'' − ''z p<sub>y</sub>''}}, etc, it follows directly from the above that
:<math> [{L_x}, {L_y}] = i \hbar \epsilon_{xyz} {L_z}, </math>
where <math>\epsilon_{xyz}</math> is the [[Levi-Civita symbol]] and simply reverses the sign of the answer under pairwise interchange of the indices. An analogous relation holds for the [[spin (physics)|spin]] operators.
 
All such nontrivial commutation relations for pairs of operators lead to corresponding [[uncertainty principle|uncertainty relations]],<ref name="robertson">{{cite journal |first=H. P. |last=Robertson |title=The Uncertainty Principle |journal=[[Physical Review]] |volume=34 |issue=1 |year=1929 |pages=163–164 |doi=10.1103/PhysRev.34.163 |bibcode = 1929PhRv...34..163R }}</ref> involving positive semi-definite expectation contributions by their respective commutators and anticommutators.  In general, for two [[Self-adjoint operator|Hermitian operators]] {{mvar|A}} and {{mvar|B}}, consider expectation values in a system in the state {{mvar|ψ}}, the variances around the corresponding expectation values being {{math|1=(Δ''A'')<sup>2</sub> &equiv; {{langle}}(''A'' − {{langle}}''A''{{rangle}})<sup>2</sup>{{rangle}}}}, etc.
 
Then
:<math> \Delta  A \, \Delta  B \geq  \frac{1}{2} \sqrt{ \left|\left\langle\left[{A},{B}\right]\right\rangle \right|^2 + \left|\left\langle\left\{ A-\langle A\rangle ,B-\langle B\rangle  \right\} \right\rangle \right|^2} ,</math>
where {{math|1=[''A'', ''B''] &equiv; ''A B'' &minus; ''B A''}} is the [[Commutator#Ring theory|commutator]] of {{mvar|A}} and {{mvar|B}}, and {{math|1={''A'', ''B''} &equiv; ''A B'' + ''B A''}} is the [[anticommutator]].
 
This follows through use of the [[Cauchy–Schwarz inequality]], since
{{math|{{!}}{{langle}}''A''<sup>2</sup>{{rangle}}{{!}} {{!}}{{langle}}''B''<sup>2</sup>{{rangle}}{{!}} &ge; {{!}}{{langle}}''A B''{{rangle}}{{!}}<sup>2</sup>}}, and {{math|1=''A B'' = ([''A'', ''B''] + {''A'', ''B''})/2 }}; and similarly for the shifted operators {{math|''A'' − {{langle}}''A''{{rangle}}}} and  {{math|''B'' − {{langle}}''B''{{rangle}}}}. (cf. [[Uncertainty principle derivations]].)
 
Judicious choices for {{mvar|A}} and {{mvar|B}} yield Heisenberg's familiar uncertainty relation for {{mvar|x}} and {{mvar|p}}, as usual. 
 
Here, for {{mvar|L<sub>x</sub>}} and {{mvar|L<sub>y</sub> }},<ref name="robertson" /> in angular momentum multiplets {{math|1=''ψ'' = {{!}}''{{ell}}'',''m''{{rangle}}}}, one has {{math|1={{langle}}''L<sub>x</sub>''<sup>2</sup>{{rangle}} = {{langle}}''L<sub>y</sub>''<sup>2</sup>{{rangle}} = (''{{ell}}'' (''{{ell}}'' + 1) − ''m''<sup>2</sup>) ℏ<sup>2</sup>/2 }}, so the above inequality yields useful constraints such as a lower bound on the [[Casimir invariant]] {{math|''{{ell}}'' (''{{ell}}'' + 1) &ge; ''m'' (''m'' + 1)}}, and hence {{math|''{{ell}}'' &ge; ''m''}}, among others.
 
== See also ==
*[[Canonical quantization]]
*[[CCR algebra]]
*[[Lie derivative]]
*[[Moyal bracket]]
 
==References==
{{Reflist}}
 
[[Category:Quantum mechanics]]
[[Category:Mathematical physics]]
 
[[zh:對易關係]]<!-- in Chinese wikipedia 對易關係 is redirected to 交換子; once the redirect is canceled, 對易關係 should be added to wikidata. -->

Latest revision as of 04:42, 15 October 2014

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