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In [[quantum mechanics]], '''Kossakowski–Lindblad equation''' (after Andrzej Kossakowski and Göran Lindblad) or '''master equation in ''Lindblad form''''' is the most general type of [[Markov process|Markovian]] and [[time-homogeneous]] [[master equation]] describing non-unitary evolution of the [[density matrix]] <math>\rho</math> that is [[completely positive trace-preserving|trace-preserving and completely positive]] for any initial condition.


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Lindblad master equation for an <math>N</math>-dimensional system's reduced density matrix <math>\ \rho</math> can be written:
 
:<math>\dot\rho=-{i\over\hbar}[H,\rho]+\sum_{n,m = 1}^{N^2-1} h_{n,m}\big(L_n\rho L_m^\dagger-\frac{1}{2}\left(\rho L_m^\dagger L_n + L_m^\dagger L_n\rho\right)\big)</math>
 
where <math>\ H</math> is a ([[Hermitian]]) [[Hamiltonian (quantum mechanics)|Hamiltonian]] part, the <math>\ L_m</math> are an arbitrary [[orthonormal basis]] of the operators on the system's Hilbert space, and the <math>\ h_{n,m}</math> are constants which determine the dynamics. The coefficient matrix <math>\ h = (h_{n,m})</math> must be [[Positive-definite matrix|positive]] to ensure that the equation is trace-preserving and completely positive. The summation only runs to <math>\ N^2-1</math> because we have taken <math>\ L_{N^2}</math> to be proportional to the identity operator, in which case the [[Addition#Notation and terminology|summand]] vanishes.  Our convention implies that the <math>\ L_m</math> are traceless for <math>\ m<N^2</math>. The terms in the summation where <math>m=n</math> can be described in terms of the [[Lindblad superoperator]], <math> L(C)\rho=C\rho C^\dagger -\frac{1}{2}\left(C^\dagger C \rho +\rho C^\dagger C\right) </math>.
 
If the <math>\ L_m</math> terms are all zero, then this is [[Liouville's theorem (Hamiltonian)#Quantum_Liouville_equation|quantum Liouville equation]] (for a closed system), which is the quantum analog of the classical [[Liouville equation]]. A related equation describes the time evolution of the expectation values of observables, it is given by the [[Ehrenfest theorem]].
 
Note that <math>\ H</math> is ''not'' necessarily equal to the self-Hamiltonian of the system. It may also incorporate effective unitary dynamics arising from the system-environment interaction.
 
==Diagonalization==
Since the matrix <math>\ h = (h_{n,m})</math> is positive, it can be [[Diagonalizable matrix|diagonalized]] with a [[Unitary transformation|unitary]] transformation u:
 
:<math>u^\dagger h u =
\begin{bmatrix}
\gamma_1 & 0        & \cdots & 0 \\
0        & \gamma_2 & \cdots & 0 \\
\vdots  & \vdots  & \ddots & \vdots \\
0        & 0        & \cdots & \gamma_{N^2-1}
\end{bmatrix}
</math>
 
where the eigenvalues <math>\ \gamma_i</math> are non-negativeIf we define another orthonormal operator basis
 
:<math> A_i = \sum_{j = 1}^{N^2-1} u_{j,i} L_j </math>
 
we can rewrite Lindblad equation in ''diagonal'' form
 
:<math>\dot\rho=-{i\over\hbar}[H,\rho]+\sum_{i = 1}^{N^2-1} \gamma_{i}\big(A_i\rho A_i^\dagger -\frac{1}{2} \rho A_i^\dagger A_i -\frac{1}{2} A_i^\dagger A_i \rho \big) .</math>
 
This equation is invariant under a unitary transformation of Lindblad operators and constants,
 
:<math> \sqrt{\gamma_i} A_i \to \sqrt{\gamma_i'} A_i' = \sum_{j = 1}^{N^2-1} v_{j,i} \sqrt{\delta_i} A_j ,</math>
 
and also under the inhomogenous transformation
 
:<math> A_i \to A_i' =  A_i + a_i ,</math>
:<math> H \to  H' =  H + \frac{1}{2i} \sum_{j=1}^{N^2-1} \gamma_j (a_j^* A_j - a_j A_J^\dagger) .</math>
 
However, the first transformation destroys the orthonormality of the operators <math>\ A_i</math> (unless all the <math>\ \gamma_i</math> are equal) and the second transformation destroys the tracelessness.  Therefore, up to degeneracies among the <math>\ \gamma_i</math>, the <math>\ A_i</math> of the diagonal form of the Lindblad equation are uniquely determined by the dynamics so long as we require them to be orthonormal and traceless.
 
==Harmonic oscillator example==
The most common Lindblad equation is that describing the damping of a  [[quantum harmonic oscillator]], it has <math>\ L_0=a</math>, <math>\ L_1=a^{\dagger}</math>, <math>\ h_{0,1}=-(\gamma/2)(\bar n+1)</math>, <math>\ h_{1,0}=-(\gamma/2)\bar n</math> with all others <math>\ h_{n,m}=0</math>. Here <math>\bar n</math> is the mean number of excitations in the reservoir damping the oscillator and <math>\ \gamma</math> is the decay rate. Additional Lindblad operators can be included to model various forms of dephasing and vibrational relaxation.  These methods have been incorporated into grid-based [[density matrix]] propagation methods.
 
==See also==
* [[Open quantum system]]
* [[Quantum jump method]]
 
==References==
* {{cite journal | last=Kossakowski | first=A. | title=On quantum statistical mechanics of non-Hamiltonian systems | journal=Rep. Math. Phys. | volume=3 | pages=247 | year=1972 | bibcode=1972RpMP....3..247K | doi=10.1016/0034-4877(72)90010-9 | issue=4}}
* {{cite journal | last=Lindblad | first=G. | title=On the generators of quantum dynamical semigroups | journal=Commun. Math. Phys. | volume=48 | pages=119 | year=1976 | doi=10.1007/BF01608499 | issue=2}}
* {{cite journal | last1=Gorini | first1=V. | last2=Kossakowski | first2=A. | last3=Sudarshan | first3=E.C.G. | title=Completely positive semigroups of N-level systems | journal=J. Math. Phys. | volume=17 | pages=821 | year=1976 | doi=10.1063/1.522979 | issue=5}}
* {{cite journal | last1=Banks | first1=T. | last2=Susskind | first2=L. | last3=Peskin | first3=M.E. | title=Difficulties for the evolution of pure states into mixed states | journal=Nuclear Physics B | volume=244 | pages=125–134 | year=1984 | bibcode=1984NuPhB.244..125B | doi=10.1016/0550-3213(84)90184-6}}
* {{cite book | last1=Accardi | first1=Luigi | last2=Lu | first2=Yun Gang | last3=Volovich | first3=I.V. | title=Quantum Theory and Its Stochastic Limit | publisher=Springer Verlag | location=New York | year=2002 | isbn=978-3-5404-1928-0}}
* {{cite book | last1=Alicki | first1=Robert | last2=Lendi | first2=Karl | title=Quantum Dynamical Semigroups and Applications | publisher=Springer Verlag | location=Berlin | year=1987 | isbn=978-0-3871-8276-6}}
* {{cite book | last1=Attal | first1=Stéphane | last2=Joye | first2=Alain | last3=Pillet | first3=Claude-Alain | title=Open Quantum Systems II: The Markovian Approach | publisher=Springer | year=2006 | isbn=978-3-5403-0992-5}}
* {{cite book | first1=Heinz-Peter | last1=Breuer | first2=F. | last2=Petruccione | title=The Theory of Open Quantum Systems | publisher=Oxford University Press | year=2002 | isbn=978-0-1985-2063-4}}
* {{cite book | last = Gardiner | first = C.W. | last2 = Zoller | first2 = Peter | author2-link = Peter Zoller | title = Quantum Noise | place = Berlin Heidelberg | publisher = Springer-Verlag | series = Springer Series in Synergetics | date = 2010 | edition = 3rd | isbn = 978-3-642-06094-6}}
* {{cite book | last1=Ingarden | first1=Roman S. | last2=Kossakowski | first2=A. | last3=Ohya | first3=M. | title=Information Dynamics and Open Systems: Classical and Quantum Approach | publisher=Springer Verlag | location=New York | year=1997 | isbn=978-0-7923-4473-5}}
* {{cite book | last=Lindblad | first=G. | title=Non-Equilibrium Entropy and Irreversibility | url=http://www.google.com/books?id=tvMcxdPNmRAC&dq=.+Non-Equilibrium+Entropy+and+Irreversibility | publisher=Delta Reidel | location=Dordrecht | year=1983 | isbn=1-4020-0320-X}}
* {{cite book | last=Tarasov | first=Vasily E. | title=Quantum Mechanics of Non-Hamiltonian and Dissipative Systems | publisher=Elsevier Science | location=Amsterdam, Boston, London, New York | year=2008 | isbn=978-0-0805-5971-1}}
 
==External links==
* [http://www.cmmp.ucl.ac.uk/~ajf/course_notes/node36.html The Lindblad master equation]
 
[[Category:Quantum mechanics]]
[[Category:Equations]]

Revision as of 19:05, 27 December 2013

Template:No footnotes In quantum mechanics, Kossakowski–Lindblad equation (after Andrzej Kossakowski and Göran Lindblad) or master equation in Lindblad form is the most general type of Markovian and time-homogeneous master equation describing non-unitary evolution of the density matrix that is trace-preserving and completely positive for any initial condition.

Lindblad master equation for an -dimensional system's reduced density matrix can be written:

where is a (Hermitian) Hamiltonian part, the are an arbitrary orthonormal basis of the operators on the system's Hilbert space, and the are constants which determine the dynamics. The coefficient matrix must be positive to ensure that the equation is trace-preserving and completely positive. The summation only runs to because we have taken to be proportional to the identity operator, in which case the summand vanishes. Our convention implies that the are traceless for . The terms in the summation where can be described in terms of the Lindblad superoperator, .

If the terms are all zero, then this is quantum Liouville equation (for a closed system), which is the quantum analog of the classical Liouville equation. A related equation describes the time evolution of the expectation values of observables, it is given by the Ehrenfest theorem.

Note that is not necessarily equal to the self-Hamiltonian of the system. It may also incorporate effective unitary dynamics arising from the system-environment interaction.

Diagonalization

Since the matrix is positive, it can be diagonalized with a unitary transformation u:

where the eigenvalues are non-negative. If we define another orthonormal operator basis

we can rewrite Lindblad equation in diagonal form

This equation is invariant under a unitary transformation of Lindblad operators and constants,

and also under the inhomogenous transformation

However, the first transformation destroys the orthonormality of the operators (unless all the are equal) and the second transformation destroys the tracelessness. Therefore, up to degeneracies among the , the of the diagonal form of the Lindblad equation are uniquely determined by the dynamics so long as we require them to be orthonormal and traceless.

Harmonic oscillator example

The most common Lindblad equation is that describing the damping of a quantum harmonic oscillator, it has , , , with all others . Here is the mean number of excitations in the reservoir damping the oscillator and is the decay rate. Additional Lindblad operators can be included to model various forms of dephasing and vibrational relaxation. These methods have been incorporated into grid-based density matrix propagation methods.

See also

References

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  • 20 year-old Real Estate Agent Rusty from Saint-Paul, has hobbies and interests which includes monopoly, property developers in singapore and poker. Will soon undertake a contiki trip that may include going to the Lower Valley of the Omo.

    My blog: http://www.primaboinca.com/view_profile.php?userid=5889534
  • 20 year-old Real Estate Agent Rusty from Saint-Paul, has hobbies and interests which includes monopoly, property developers in singapore and poker. Will soon undertake a contiki trip that may include going to the Lower Valley of the Omo.

    My blog: http://www.primaboinca.com/view_profile.php?userid=5889534
  • 20 year-old Real Estate Agent Rusty from Saint-Paul, has hobbies and interests which includes monopoly, property developers in singapore and poker. Will soon undertake a contiki trip that may include going to the Lower Valley of the Omo.

    My blog: http://www.primaboinca.com/view_profile.php?userid=5889534
  • 20 year-old Real Estate Agent Rusty from Saint-Paul, has hobbies and interests which includes monopoly, property developers in singapore and poker. Will soon undertake a contiki trip that may include going to the Lower Valley of the Omo.

    My blog: http://www.primaboinca.com/view_profile.php?userid=5889534
  • 20 year-old Real Estate Agent Rusty from Saint-Paul, has hobbies and interests which includes monopoly, property developers in singapore and poker. Will soon undertake a contiki trip that may include going to the Lower Valley of the Omo.

    My blog: http://www.primaboinca.com/view_profile.php?userid=5889534
  • 20 year-old Real Estate Agent Rusty from Saint-Paul, has hobbies and interests which includes monopoly, property developers in singapore and poker. Will soon undertake a contiki trip that may include going to the Lower Valley of the Omo.

    My blog: http://www.primaboinca.com/view_profile.php?userid=5889534
  • 20 year-old Real Estate Agent Rusty from Saint-Paul, has hobbies and interests which includes monopoly, property developers in singapore and poker. Will soon undertake a contiki trip that may include going to the Lower Valley of the Omo.

    My blog: http://www.primaboinca.com/view_profile.php?userid=5889534

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