Kolmogorov equations (Markov jump process): Difference between revisions

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[[File:Quaternary ammonium cation.svg|upright|thumb|[[Quaternary ammonium cation]]. The R's may be the same or different groups. They may also be connected ([[Heterocyclic compound|cyclic]]).]]
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In [[chemistry]], a '''quaternary compound''' is a [[cation]] consisting of a central positively charged [[nitrogen group]] atom with four substituents, especially [[organic compound|organic]] ([[alkyl]] and [[aryl]]) groups, discounting [[hydrogen]] atoms.<ref>{{GoldBookRef|title=Onium compounds|file=O04291}}</ref>
 
The best known quaternary compounds are [[quaternary ammonium cation]]s, having a [[nitrogen]] atom at the centre.<ref>{{GoldBookRef | file = Q05003 | title = quaternary ammonium compounds }}</ref> For example, in the following reaction, the [[nitrogen]] atom is said to be '''quaternized''' as it has gone from 3 to 4 substituents:
 
:<math>\mathrm{R_3N + RCl \longrightarrow R_4N^+ \ Cl^-}</math>
 
Other examples include substituted [[phosphonium salt]]s (R<sub>4</sub>[[Phosphorus|P]]<sup>+</sup>), substituted [[arsonium salt]]s (R<sub>4</sub>[[Arsenic|As]]<sup>+</sup>) like [[arsenobetaine]], as well as some [[arsenic]] containing [[superconductor]]s.<ref>{{cite doi|10.1209/0295-5075/82/57002}}</ref> Substituted [[stibonium salt|stibonium]] (R<sub>4</sub>[[Antimony|Sb]]<sup>+</sup>)<ref>{{cite doi|10.1002/zaac.19774350124}}</ref> and [[bismuthonium salt]]s (R<sub>4</sub>[[Bismuth|Bi]]<sup>+</sup>) have also been described.<ref>{{cite book|title=Chemistry of arsenic, antimony, and bismuth|author=Nicholas C. Norman|publisher=Springer Netherlands|year=1997|page=316|isbn=0-7514-0389-X|url=http://books.google.at/books?id=vVhpurkfeN4C&pg=PA316&lpg=PA316&dq=tetramethyl+bismuthonium&source=bl&ots=sHfnfzzxWm&sig=e5_UI0j8Ff_W0UDelpUp1zIWsKc&hl=de&ei=FQS3Tp_1DYul-gbqoZWFBg&sa=X&oi=book_result&ct=result&resnum=1&ved=0CB4Q6AEwAA#v=onepage&q=tetramethyl%20bismuthonium&f=false}}</ref>
 
==See also==
* [[Onium compounds]]
 
==References==
{{reflist}}
 
[[Category:Quaternary compounds]]
 
 
{{chemistry-stub}}

Latest revision as of 09:45, 5 September 2014

Bone Handle Pocket Knife is an amazing selection when looking to purchase a great Pocket Knife to carry about for your day-to-day use. This is often known as the old timer pocket knife. People today have been working with bone to make pocket knifes for hundreds of years and are nonetheless just as preferred now as they have been hundreds of years ago. But When it comes time to make a choice on what bone manage pocket knife you are thinking of buying

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