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| | {{Chembox |
| | | ImageFile = |
| | | ImageSize = |
| | | SystematicName = Silver(I) cyanate |
| | | OtherNames = |
| | | Section1 = {{Chembox Identifiers |
| | | CASNo = 3315-16-0 |
| | | CASNo_Ref = {{cascite|correct|}} |
| | | PubChem = 76827 |
| | | ChemSpiderID = 69282 |
| | | SMILES = [Ag+].[O-]C#N |
| | | InChI = 1/CHNO.Ag/c2-1-3;/h3H;/q;+1/p-1 |
| | | InChIKey = DWBPIWPCOSHWCK-REWHXWOFAQ |
| | | StdInChI = 1S/CHNO.Ag/c2-1-3;/h3H;/q;+1/p-1 |
| | | StdInChIKey = DWBPIWPCOSHWCK-UHFFFAOYSA-M |
| | }} |
| | | Section2 = {{Chembox Properties |
| | | Formula = AgOCN |
| | | MolarMass = 149.885 g/mol |
| | | Appearance = |
| | | Density = |
| | | MeltingPt = |
| | | BoilingPt = |
| | | Solubility = |
| | }} |
| | | Section3 = {{Chembox Hazards |
| | | MainHazards = |
| | | FlashPt = |
| | | Autoignition = |
| | }} |
| | }} |
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| | '''Silver cyanate''' is a [[chemical compound]] and the [[cyanate]] [[salt]] of [[silver]]. |
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| | It can be prepared by reaction of [[potassium cyanate]] or [[urea]] with [[silver nitrate]].<ref name="buch">{{Literatur | Autor = Willy Kühne | Titel = Lehrbuch der physiologischen Chemie | Verlag = | ISBN = | Jahr = 1868 | Online = {{Google Buch | BuchID = q8U9AAAAYAAJ | Linktext = Seite 470 | Seite = 470 }} }}</ref> |
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| | :<math>\mathrm{AgNO_3 + KOCN \longrightarrow AgOCN \downarrow +\ KNO_3}</math> |
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| | :<math>\mathrm{AgNO_3 + H_2N\text{-}C(O)\text{-}NH_2 \longrightarrow}</math> <math>\mathrm{AgOCN \downarrow +\ NH_4NO_3}</math> |
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| | Silver cyanate is a beige to gray powder. It crystallises in the [[monoclinic crystal system]] in [[space group]] ''P''2<sub>1</sub>/''m'' with parameters a = 547.3 [[Picometer|pm]], b = 637.2 pm, c = 341.6 pm und β = 91°.<ref>[http://scripts.iucr.org/cgi-bin/paper?a04540 D. Britton, J. D. Dunitz: ''The crystal structure of silver cyanate''], Acta Cryst. (1965). 18, 424-428, {{DOI|10.1107/S0365110X65000944}}</ref> |
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| | With [[nitric acid]] silver cyanate reacts to form [[carbon dioxide]] and [[ammonium nitrate]].<ref name="Milbauer">J. Milbauer: ''Bestimmung und Trennung der Cyanate, Cyanide, Rhodanide und Sulfide'' in [[Fresenius' Journal of Analytical Chemistry]] 42 (1903) 77-95, {{DOI|10.1007/BF01302741}}.</ref> |
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| | :<math>\mathrm{AgOCN + 2HNO_3 + H_2O \longrightarrow}</math> |
| | :<math>\mathrm{AgNO_3 + CO_2 \uparrow +\ NH_4NO_3}</math> |
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| | == See also == |
| | * [[Justus Von Liebig]] |
| | * [[Friedrich Woehler]] |
| | * [[Silver fulminate]] |
| | * [[Isomerism]] |
| | |
| | ==References== |
| | {{Reflist}} |
| | |
| | [[Category:Silver compounds]] |
| | [[Category:Cyanates]] |
Template:Chembox
Silver cyanate is a chemical compound and the cyanate salt of silver.
It can be prepared by reaction of potassium cyanate or urea with silver nitrate.[1]
Silver cyanate is a beige to gray powder. It crystallises in the monoclinic crystal system in space group P21/m with parameters a = 547.3 pm, b = 637.2 pm, c = 341.6 pm und β = 91°.[2]
With nitric acid silver cyanate reacts to form carbon dioxide and ammonium nitrate.[3]
See also
References
43 year old Petroleum Engineer Harry from Deep River, usually spends time with hobbies and interests like renting movies, property developers in singapore new condominium and vehicle racing. Constantly enjoys going to destinations like Camino Real de Tierra Adentro.
- ↑ Template:Literatur
- ↑ D. Britton, J. D. Dunitz: The crystal structure of silver cyanate, Acta Cryst. (1965). 18, 424-428, Electronic Instrument Positions Staff (Standard ) Cameron from Clarence Creek, usually spends time with hobbies and interests which include knotting, property developers in singapore apartment For sale and boomerangs. Has enrolled in a world contiki journey. Is extremely thrilled specifically about visiting .
- ↑ J. Milbauer: Bestimmung und Trennung der Cyanate, Cyanide, Rhodanide und Sulfide in Fresenius' Journal of Analytical Chemistry 42 (1903) 77-95, Electronic Instrument Positions Staff (Standard ) Cameron from Clarence Creek, usually spends time with hobbies and interests which include knotting, property developers in singapore apartment For sale and boomerangs. Has enrolled in a world contiki journey. Is extremely thrilled specifically about visiting ..