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{{ref improve|date=January 2013}}
A '''Maxwell material''' is a [[viscoelastic]] material having the properties both of [[Elasticity (physics)|elasticity]] and [[viscosity]].<ref name=roylance_EV>{{cite book|last=Roylance|first=David|title=Engineering Viscoelasticity|year=2001|publisher=Massachusetts Institute of Technology|location=Cambridge, MA 02139|pages=8-11|url=http://web.mit.edu/course/3/3.11/www/modules/visco.pdf}}</ref>  It is named for [[James Clerk Maxwell]] who proposed the model in 1867.  It is also known as a Maxwell fluid.


== Definition ==


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The Maxwell model can be represented by a purely viscous damper and a purely elastic spring connected in series, as shown in the diagram.  In this configuration, under an applied axial stress, the total stress, <math>\sigma_\mathrm{Total}</math> and the total strain, <math>\epsilon_\mathrm{Total}</math> can be defined as follows:<ref name=roylance_EV />
 
:<math>\sigma_\mathrm{Total}=\sigma_D = \sigma_S</math>
:<math>\epsilon_\mathrm{Total}=\epsilon_D+\epsilon_S</math>
 
where the subscript D indicates the stress/strain in the damper and the subscript S indicates the stress/strain in the spring.  Taking the derivative of strain with respect to time, we obtain:
 
:<math>\frac {d\epsilon_\mathrm{Total}} {dt} = \frac {d\epsilon_D} {dt} + \frac {d\epsilon_S} {dt} = \frac {\sigma} {\eta} + \frac {1} {E} \frac {d\sigma} {dt}</math>
 
where ''E'' is the elastic modulus and ''η'' is the material coefficient of viscosity. This model describes the damper as a [[Newtonian fluid]] and models the spring with [[Hooke's law]].
 
[[Image:Maxwell diagram.svg|right]]
 
If we connect these two elements in parallel, we get a model of [[Kelvin–Voigt material]].
 
In a Maxwell material, [[Stress (physics)|stress]] σ, [[Strain (materials science)|strain]] ε and their rates of change with respect to time t are governed by equations of the form:<ref name=roylance_EV />
 
:<math>\frac {1} {E} \frac {d\sigma} {dt} + \frac {\sigma} {\eta} = \frac {d\epsilon} {dt}</math>
 
or, in dot notation:
 
:<math>\frac {\dot {\sigma}} {E} + \frac {\sigma} {\eta}= \dot {\epsilon}</math>
 
The equation can be applied either to the [[shear stress]] or to the uniform tension in a material. In the former case, the viscosity corresponds to that for a [[Newtonian fluid]]. In the latter case, it has a slightly different meaning relating stress and rate of strain.
 
The model is usually applied to the case of small deformations. For the large deformations we should include some geometrical non-linearity. For the simplest way of generalizing the Maxwell model, refer to the [[upper-convected Maxwell model]].
 
== Effect of a sudden deformation ==
 
If a Maxwell material is suddenly deformed and held to a [[Strain (materials science)|strain]] of <math>\epsilon_0</math>, then the stress decays with a characteristic time of <math>\frac{\eta}{E}</math>.
 
The picture shows dependence of dimensionless stress <math>\frac {\sigma(t)} {E\epsilon_0} </math>
upon dimensionless time <math>\frac{E}{\eta} t</math>:
[[Image:Maxwell deformation.PNG|right|thumb|400px|Dependence of dimensionless stress upon dimensionless time under constant strain|Dependence of dimensionless stress
upon dimensionless time under constant strain]]
 
If we free the material at time <math>t_1</math>, then the elastic element will spring back by the value of
 
:<math>\epsilon_\mathrm{back} = -\frac {\sigma(t_1)} E = \epsilon_0 \exp \left(-\frac{E}{\eta} t_1\right). </math>
 
Since the viscous element would not return to its original length, the irreversible component of deformation can be simplified to the expression below:
 
:<math>\epsilon_\mathrm{irreversible} =  \epsilon_0 \left(1- \exp \left(-\frac{E}{\eta} t_1\right)\right). </math>
 
==Effect of a sudden stress ==
 
If a Maxwell material is suddenly subjected to a stress <math>\sigma_0</math>, then the elastic element would suddenly deform and the viscous element would deform with a constant rate:
 
:<math>\epsilon(t) = \frac {\sigma_0} E + t \frac{\sigma_0} \eta </math>
 
If at some time <math>t_1</math> we would release the material, then the deformation of the elastic element would be the spring-back deformation and the deformation of the viscous element would not change:
 
:<math>\epsilon_\mathrm{reversible} = \frac {\sigma_0} E,  </math>
 
:<math>\epsilon_\mathrm{irreversible} =  t_1 \frac{\sigma_0} \eta. </math>
 
The Maxwell Model does not exhibit [[Creep (deformation)|creep]] since it models strain as linear function of time.
 
If a small stress is applied for a sufficiently long time, then the irreversible strains become large. Thus, Maxwell material is a type of [[liquid]].
 
== Dynamic modulus ==
 
The complex [[dynamic modulus]] of a Maxwell material would be:
 
:<math>E^*(\omega) = \frac 1 {1/E - i/(\omega \eta) } = \frac {E\eta^2 \omega^2 +i \omega E^2\eta} {\eta^2 \omega^2 + E^2} </math>
 
Thus, the components of the dynamic modulus are :
 
:<math>E_1(\omega) = \frac {E\eta^2 \omega^2 } {\eta^2 \omega^2 + E^2} </math>
 
and
 
:<math>E_2(\omega) =  \frac {\omega E^2\eta} {\eta^2 \omega^2 + E^2} </math>
 
[[Image:Maxwell relax spectra.PNG|thumb|right|400px|Relaxational spectrum for Maxwell material]]
The picture shows relaxational spectrum for Maxwell material. The relaxation time constant is <math> \lambda \equiv \eta / E </math>.
{| border="1" cellspacing="0"
| Blue curve || dimensionless elastic modulus <math>\frac {E_1} {E}</math>
|-
| Pink curve || dimensionless modulus of losses <math>\frac {E_2} {E}</math>
|-
| Yellow curve || dimensionless apparent viscosity <math>\frac {E_2} {\omega \eta}</math>
|-
| X-axis || dimensionless frequency <math> \omega\lambda</math>.
|}
 
== References ==
{{reflist}}
== See also ==
 
*[[Generalized Maxwell material]]
*[[Kelvin–Voigt material]]
*[[Oldroyd material]]
*[[Standard Linear Solid Material]]
*[[Upper-convected Maxwell model]]
 
{{DEFAULTSORT:Maxwell Material}}
[[Category:Non-Newtonian fluids]]
[[Category:Materials science]]
[[Category:James Clerk Maxwell]]

Revision as of 02:59, 29 December 2013

Template:Ref improve A Maxwell material is a viscoelastic material having the properties both of elasticity and viscosity.[1] It is named for James Clerk Maxwell who proposed the model in 1867. It is also known as a Maxwell fluid.

Definition

The Maxwell model can be represented by a purely viscous damper and a purely elastic spring connected in series, as shown in the diagram. In this configuration, under an applied axial stress, the total stress, σTotal and the total strain, ϵTotal can be defined as follows:[1]

σTotal=σD=σS
ϵTotal=ϵD+ϵS

where the subscript D indicates the stress/strain in the damper and the subscript S indicates the stress/strain in the spring. Taking the derivative of strain with respect to time, we obtain:

dϵTotaldt=dϵDdt+dϵSdt=ση+1Edσdt

where E is the elastic modulus and η is the material coefficient of viscosity. This model describes the damper as a Newtonian fluid and models the spring with Hooke's law.

If we connect these two elements in parallel, we get a model of Kelvin–Voigt material.

In a Maxwell material, stress σ, strain ε and their rates of change with respect to time t are governed by equations of the form:[1]

1Edσdt+ση=dϵdt

or, in dot notation:

σ˙E+ση=ϵ˙

The equation can be applied either to the shear stress or to the uniform tension in a material. In the former case, the viscosity corresponds to that for a Newtonian fluid. In the latter case, it has a slightly different meaning relating stress and rate of strain.

The model is usually applied to the case of small deformations. For the large deformations we should include some geometrical non-linearity. For the simplest way of generalizing the Maxwell model, refer to the upper-convected Maxwell model.

Effect of a sudden deformation

If a Maxwell material is suddenly deformed and held to a strain of ϵ0, then the stress decays with a characteristic time of ηE.

The picture shows dependence of dimensionless stress σ(t)Eϵ0 upon dimensionless time Eηt:

File:Maxwell deformation.PNG
Dependence of dimensionless stress upon dimensionless time under constant strain

If we free the material at time t1, then the elastic element will spring back by the value of

ϵback=σ(t1)E=ϵ0exp(Eηt1).

Since the viscous element would not return to its original length, the irreversible component of deformation can be simplified to the expression below:

ϵirreversible=ϵ0(1exp(Eηt1)).

Effect of a sudden stress

If a Maxwell material is suddenly subjected to a stress σ0, then the elastic element would suddenly deform and the viscous element would deform with a constant rate:

ϵ(t)=σ0E+tσ0η

If at some time t1 we would release the material, then the deformation of the elastic element would be the spring-back deformation and the deformation of the viscous element would not change:

ϵreversible=σ0E,
ϵirreversible=t1σ0η.

The Maxwell Model does not exhibit creep since it models strain as linear function of time.

If a small stress is applied for a sufficiently long time, then the irreversible strains become large. Thus, Maxwell material is a type of liquid.

Dynamic modulus

The complex dynamic modulus of a Maxwell material would be:

E(ω)=11/Ei/(ωη)=Eη2ω2+iωE2ηη2ω2+E2

Thus, the components of the dynamic modulus are :

E1(ω)=Eη2ω2η2ω2+E2

and

E2(ω)=ωE2ηη2ω2+E2
File:Maxwell relax spectra.PNG
Relaxational spectrum for Maxwell material

The picture shows relaxational spectrum for Maxwell material. The relaxation time constant is λη/E.

Blue curve dimensionless elastic modulus E1E
Pink curve dimensionless modulus of losses E2E
Yellow curve dimensionless apparent viscosity E2ωη
X-axis dimensionless frequency ωλ.

References

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